Tunable visible emission and persistent luminescence of BaGa₂O₄:Cu²⁺

In the field of solid-state luminescence, Cu²⁺ has long been widely acknowledged for its capacity to emit infrared light. However, the occurrence of visible emission from Cu²⁺ ions had been infrequently observed and reported. In this study, we made an intriguing discovery by examining the behavior of Cu²⁺...

Structures, activities, and mechanisms under the spectroscopes: the quest for unveiling the nature of active sites for highly selective CO2 hydrogenation to methanol

Since the industrial revolution in the 1760s, the CO2 concentration in the atmosphere has been rising incessantly driving global warming closer to the point of no return. The world requires urgent actions to not only reduce CO2 emissions but also capture the CO2 for utilization to mitigate the future environmental crisis. CO2 hydrogenation to...

Autogenous shrinkage of alkali-activated slag: A critical review

This paper provides a critical review on autogenous shrinkage of alkali-activated slag (AAS). It is reported that AAS paste, mortar, and concrete generally show larger autogenous shrinkage than Portland cement (PC) counterparts. Self-desiccation is the main driving force of the autogenous shrinkage of hardened AAS, but other mechanisms also...

Analytical and numerical models of debris flow impact

A full understanding of the interaction mechanisms among flow-like landslides and impacted protection structures is still an open issue. Although several approaches, from experimental to numerical, have been used so far, a thoroughly assessment of the hydromechanical behaviour of the landslide body is achievable only through a multiphase and...

Mechanistic insight into the improved photocatalytic degradation of dyes for an ultrathin coating of SiO₂ on TiO₂ (P25) nanoparticles

The photocatalytic mechanism of TiO₂ (P25) nanoparticles coated with SiO₂ (SiO₂:TiO₂) by atomic layer deposition was investigated. The deposition of SiO₂ on TiO₂ not only gives a photocatalytic improvement for the degradation of both Rhodamine B (3.6–fold) and Acid Blue 9 (3...

Initial High-Temperature Oxidation Behavior of Fe–Mn Binaries in Air: The Kinetics and Mechanism of Oxidation

High-temperature oxidation of steels can be relatively fast when exposed to air. Consequently, elucidating the effect of different parameters on the oxidation mechanism and kinetics is challenging. In this study, short-time oxidation was investigated to determine the oxidation mechanism, the affecting parameters, and the linear-to-parabolic...

The role of H₂ in Fe carburization by CO in Fischer-Tropsch catalysts

The formation of Fe-carbide phases is relevant to the synthesis of Fischer-Tropsch synthesis catalysts. We investigated the carburization of Raney Fe as a model catalyst using spectroscopic and temperature-programmed techniques. IR spectroscopy shows that CO dissociation already occurs at −150 °C, while C diffusion into metallic Fe requires...

Review of strain rate effects of fiber-reinforced polymer composites

The application of fiber-reinforced polymer (FRP) composites is gaining increasing popu-larity in impact-resistant devices, automotives, biomedical devices and aircraft structures due to their high strength-to-weight ratios and their potential for impact energy absorption. Impact-induced high loading rates can result in significant changes of...

Synergy of Ni micro-alloying and thermomechanical processing in Al–Mg–Si–Cu–Zn–Fe–Mn alloys with enhanced bendability

Synergy of Ni micro-alloying and thermomechanical processing on the phase distribution, formability and bendability of Al–Mg–Si–Cu–Zn–Fe–Mn alloys was systematically studied in this paper. With the addition of micro-alloying Ni, the Ni-containing Fe-rich phase can be formed, which not only serves as nucleation sites of Mg–Si precipitates ...

Mechanisms of autogenous shrinkage of alkali-activated slag and fly ash pastes

This study aims to provide a better understanding of the autogenous shrinkage of slag and fly ash-based alkali-activated materials (AAMs) cured at ambient temperature. The main reaction products in AAMs pastes are C-A-S-H type gel and the reaction rate decreases when slag is partially replaced by fly ash. Due to the chemical shrinkage and the...