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Visser, P. (author), Marcoen, K. (author), Trindade, G. F. (author), Abel, M. L. (author), Watts, J. F. (author), Hauffman, T. (author), Mol, J.M.C. (author), Terryn, H.A. (author)Chemical throwing power, being the distance over which an inhibitor is able to protect a defect effectively, is an important parameter for active protective coatings. This study investigates the chemical throwing power of lithium-based leachable corrosion inhibitors exhibiting different leaching kinetics, from coatings at different inhibitor...journal article 2019
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van der Hoek, J.P. (author), Mol, Stefan (author), Giorgi, Sara (author), Ahmad, J.I. (author), Liu, G. (author), Medema, G.J. (author)Greenhouse gas (GHG) emissions contribute to climate change. The public water utility of Amsterdam wants to operate climate neutrally in 2020 to reduce its GHG emissions. Energy recovery from the water cycle has a large potential to contribute to this goal: the recovered energy is an alternative for fossil fuel and thus contributes to the...journal article 2018
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Naddaf Dezfuli, S. (author), Brouwer, J.C. (author), Mol, J.M.C. (author), van der Helm, F.C.T. (author), Zhou, J. (author)Recent studies have shown great potential of Mg matrix composites for biodegradable orthopedic devices. However, the poor structural integrity of these composites, which results in excessive localized corrosion and premature mechanical failure, has hindered their widespread applications. In this research, an in-situ Powder Metallurgy (PM)...journal article 2018
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Harzheim, Achim (author), Spiece, Jean (author), Evangeli, Charalambos (author), McCann, Edward (author), Falko, Vladimir (author), Sheng, Yuewen (author), Warner, Jamie H. (author), Briggs, G. Andrew D. (author), Mol, Jan A. (author), Gehring, P. (author), Kolosov, Oleg V. (author)The influence of nanostructuring and quantum confinement on the thermoelectric properties of materials has been extensively studied. While this has made possible multiple breakthroughs in the achievable figure of merit, classical confinement, and its effect on the local Seebeck coefficient has mostly been neglected, as has the Peltier effect...journal article 2018
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Li, Y. (author), Jahr, H. (author), Lietaert, K. (author), Pavanram, P. (author), Yilmaz, A. (author), Fockaert, L.I. (author), Leeflang, M.A. (author), Pouran, B. (author), Gonzalez Garcia, Y. (author), Weinans, Harrie (author), Mol, J.M.C. (author), Zhou, J. (author), Zadpoor, A.A. (author)Additively manufactured (AM) topologically ordered porous metallic biomaterials with the proper biodegradation profile offer a unique combination of properties ideal for bone regeneration. These include a fully interconnected porous structure, bone-mimicking mechanical properties, and the possibility of fully regenerating bony defects. Most...journal article 2018
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Visser, P. (author), Terryn, H.A. (author), Mol, J.M.C. (author)Inhibitor leaching, fast, effective and irreversible passivation are essential for active protective coatings to protect aluminium alloys. This study presents the comparison of the active protective properties of lithium carbonate and two organic corrosion inhibitors, benzotriazole and 2-mercaptobenzothiazole, on aluminium alloy 2024-T3 with...journal article 2018
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Mirzakhanzadeh, Z. (author), Kosari, A. (author), Moayed, M. H. (author), Naderi, R. (author), Taheri, P. (author), Mol, J.M.C. (author)This work investigates the synergetic effect of zinc aluminum polyphosphate (ZAPP) and 2-mercaptobenzimidazole (MBI) on the corrosion protection of mild steel coated with a solvent-borne epoxy-polyamide layer. The magnitude and trend of electrochemical impedance spectroscopy data over 70-d immersion in 3.5 wt.% NaCl solution indicate superior...journal article 2018
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Marcoen, Kristof (author), Visser, P (author), Trindade, G. F. (author), Abel, M. L. (author), Watts, J. F. (author), Mol, J.M.C. (author), Terryn, H.A. (author), Hauffman, T. (author)Organic primer coatings loaded with environmentally harmful Cr(VI) corrosion inhibitive pigments still play an important role in corrosion protection of aluminium alloys for the aerospace industry. A potential “green” alternative coating system has recently been developed, loaded with lithium salt corrosion inhibitors. Under exposure to...journal article 2018
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Meeusen, M. (author), Visser, P. (author), Fernández Macía, L. (author), Hubin, A. (author), Terryn, H.A. (author), Mol, J.M.C. (author)In this work, the study of the time-dependent behaviour of lithium carbonate based inhibitor technology for the active corrosion protection of aluminium alloy 2024-T3 is presented. Odd random phase electrochemical impedance spectroscopy (ORP-EIS) is selected as the electrochemical tool to study the corrosion protective properties of a model...journal article 2018
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Huang, Yao (author), Deng, Leping (author), Ju, Pengfei (author), Huang, Luyao (author), Qian, H. (author), Zhang, Dawei (author), Li, Xiaogang (author), Terryn, H.A. (author), Mol, J.M.C. (author)In this study, a new self-healing shape memory polymer (SMP) coating was prepared to protect the aluminum alloy 2024-T3 from corrosion by the incorporation of dual-function microspheres containing polycaprolactone and the corrosion inhibitor 8-hydroxyquinoline (8HQ). The self-healing properties of the coatings were investigated via scanning...journal article 2018
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Visser, P. (author), Gonzalez Garcia, Y. (author), Mol, J.M.C. (author), Terryn, H.A. (author)This study focuses on the elucidation of the formation mechanism of passive layers on AA2024-T3 during the exposure to alkaline lithium carbonate solutions in the presence of sodium chloride. Under controlled conditions, in an electrochemical cell, a protective layer was generated comprising an amorphous inner layer and a crystalline outer...journal article 2018
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Haddadi, S. (author), Ramazani, S. A.A. (author), Mahdavian, M. (author), Taheri, P. (author), Mol, J.M.C. (author)In this work, we synthesized carbon hollow spheres (CHSs) using the silica templating method, encapsulated 2-mercaptobenzimidazole (MBI) inhibitor in the CHSs and evaluated their corrosion inhibition performance upon exposure of mild steel to a saline solution containing the released inhibitor. The effects of silica template surface...journal article 2018
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Pletincx, Sven (author), Fockaert, L.I. (author), Meeusen, M. (author), Mol, J.M.C. (author), Terryn, H.A. (author), Hauffman, Tom (author)A common approach to investigate chemical interactions at the polymer/metal oxide interface is by monitoring ultrathin polymer films onto a metal oxide substrate by a variety of surface analysis techniques. The deposition of this nanometer-thin overlayer is frequently carried out by reactive adsorption from dilute polymer solutions. However,...journal article 2018
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Homborg, A.M. (author), Oonincx, P.J. (author), Mol, J.M.C. (author)A potentially powerful tool to detect and classify corrosion mechanisms is the analysis of electrochemical noise (EN). Data analysis in the time-frequency domain using, e.g., continuous wavelet transform (CWT) allows the extraction of localized frequency information, providing information on the type of corrosion, i.e., uniform or localized...journal article 2018
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Stepniowski, W.J. (author), Moneta, Marcin (author), Karczewski, Krzysztof (author), Michalska-Domanska, Marta (author), Czujko, Tomasz (author), Mol, J.M.C. (author), Buijnsters, J.G. (author)Anodic aluminum oxide was formed by employing mild and hard anodizing in sulfuric acid followed by mild anodizing in oxalic acid without oxide removal in-between at 40 and 45 V. Such multi-step anodizing, combining hard anodizing in sulfuric acid with mild anodizing in oxalic acid allowed to form a highly-ordered nanoporous template with a...journal article 2018
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Abrahami, S.T. (author), de Kok, J.M.M. (author), Gudla, V.C. (author), Marcoen, Kristof (author), Hauffman, T. (author), Ambat, R. (author), Mol, J.M.C. (author), Terryn, H.A. (author)Nanoporous anodic aluminum oxides (AAOs) are used as templates in various technological applications, including load-bearing aircraft structures. But in spite of their popularity, the important aspects that control their (dis-)bonding to an organic coating are not fully understood. To study the mechanisms behind the negative effect of fluorides...journal article 2018
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Pletincx, S. (author), Trotochaud, L. (author), Fockaert, L.I. (author), Mol, J.M.C. (author), Head, A.R. (author), Karslıoğlu, O. (author), Bluhm, H. (author), Terryn, H.A. (author), Hauffman, T. (author)Probing initial interactions at the interface of hybrid systems under humid conditions has the potential to reveal the local chemical environment at solid/solid interfaces under real-world, technologically relevant conditions. Here, we show that ambient pressure X-ray photoelectron spectroscopy (APXPS) with a conventional X-ray source can be...journal article 2017
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Martinez Lombardia, Esther (author), Lapeire, Linsey (author), Maurice, Vincent (author), De Graeve, Iris (author), Klein, Lorena (author), Marcus, Philippe (author), Verbeken, Kim (author), Kestens, L.A.I. (author), Gonzalez Garcia, Y. (author), Mol, J.M.C. (author), Terryn, H.A. (author)When aiming for an increased and more sustainable use of metals a thorough knowledge of the corrosion phenomenon as function of the local metal microstructure is of crucial importance. In this work, we summarize the information presented in our previous publications[1-3] and present an overview of the different local (electrochemical) techniques...journal article 2017
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Li, Y. (author), Zhou, J. (author), Pavanram, P. (author), Leeflang, M.A. (author), Fockaert, L.I. (author), Pouran, B. (author), Tümer, N. (author), Schröder, K. U. (author), Mol, J.M.C. (author), Weinans, Harrie (author), Jahr, H. (author), Zadpoor, A.A. (author)An ideal bone substituting material should be bone-mimicking in terms of mechanical properties, present a precisely controlled and fully interconnected porous structure, and degrade in the human body to allow for full regeneration of large bony defects. However, simultaneously satisfying all these three requirements has so far been highly...journal article 2017
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Abrahami, S.T. (author), de Kok, John M.M. (author), Terryn, H.A. (author), Mol, J.M.C. (author)For more than six decades, chromic acid anodizing (CAA) has been the central process in the surface pre-treatment of aluminum for adhesively bonded aircraft structures. Unfortunately, this electrolyte contains hexavalent chromium (Cr(VI)), a compound known for its toxicity and carcinogenic properties. To comply with the new strict...journal article 2017