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Dai, Jiaxin (author), Fu, Dongmei (author), Song, Guangxuan (author), Ma, Lingwei (author), Guo, Xin (author), Mol, J.M.C. (author), Cole, Ivan (author), Zhang, Dawei (author)
Current experimental verification, computational modeling, and machine learning methods for predicting corrosion inhibition efficiency (IE) are limited to specific inhibitor categories with high cost and poor generalization. In this study, a cross-category corrosion inhibitor dataset is constructed and a three-level direct message passing...
journal article 2022
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Bender, Roman (author), Féron, Damien (author), Mills, Douglas (author), Ritter, Stefan (author), Bäßler, Ralph (author), Bettge, Dirk (author), Mol, J.M.C. (author), Terryn, H.A. (author), Wilms, M.E. (author)
A global transition towards more sustainable, affordable and reliable energy systems is being stimulated by the Paris Agreement and the United Nation's 2030 Agenda for Sustainable Development. This poses a challenge for the corrosion industry, as building climate-resilient energy systems and infrastructures brings with it a long-term...
journal article 2022
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Rahimi, E. (author), Imani, Amin (author), Lekka, Maria (author), Andreatta, Francesco (author), Gonzalez Garcia, Y. (author), Mol, J.M.C. (author), Asselin, Edouard (author), Fedrizzi, Lorenzo (author)
The formation of a protein nanobiofilm on the surface of degradable biomaterials such as magnesium (Mg) and its alloys influences metal ion release, cell adhesion/spreading, and biocompatibility. During the early stage of human body implantation, competition and interaction between inorganic species and protein molecules result in a complex...
journal article 2022
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Liu, Tong (author), Zhang, Dawei (author), Ma, Lingwei (author), Huang, Yao (author), Hao, Xiangping (author), Terryn, H.A. (author), Mol, J.M.C. (author), Li, Xiaogang (author)
Herein, we report the development of a self-sensing and active corrosion protection coating which incorporates pH-sensitive multilayer chitosan/alginate-covered CaCO<sub>3</sub> microcontainers containing 1,10-phenanthrolin-5-amine (APhen). The microcontainers can respond to pH variation to release APhen which serves not only as a corrosion...
review 2022
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Bakhit, Babak (author), Dorri, Samira (author), Kosari, A. (author), Mol, J.M.C. (author), Petrov, Ivan (author), Birch, Jens (author), Hultman, Lars (author), Greczynski, Grzegorz (author)
We study microstructure, mechanical, and corrosion properties of Zr<sub>1-x</sub>Cr<sub>x</sub>B<sub>y</sub> coatings deposited by hybrid high-power impulse/DC magnetron co-sputtering (CrB<sub>2</sub>-HiPIMS/ZrB<sub>2</sub>-DCMS). Cr/(Zr + Cr) ratio, x, increases from 0.13 to 0.9, while B/(Zr + Cr) ratio, y, decreases from 2.92 to 1.81. As...
journal article 2022
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Van den Steen, N. (author), Gonzalez Garcia, Y. (author), Mol, J.M.C. (author), Terryn, H.A. (author), Van Ingelgem, Y. (author)
A new approach is proposed to numerically predict and study atmospheric corrosion for ranging droplet size distributions and the influence of the droplet geometry. The proposed methodology allows for a corrosion prediction based on observed droplet size distributions and droplet contact angles. A mechanistic finite element model, including...
journal article 2022
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Herrmann, A. (author), Erich, S. J.F. (author), van der Ven, L. G.J. (author), Huinink, H. P. (author), van Driel, W.D. (author), van Soestbergen, M. (author), Mavinkurve, A. (author), De Buyl, F. (author), Fischer, H. R. (author), Mol, J.M.C. (author), Adan, O. C.G. (author)
Epoxy Mold Compounds (EMC) are used to protect integrated circuits (IC) from environmental influences, with one of these influences being moisture ingress, causing corrosion. To obtain the needed thermal and mechanical properties EMCs require a high loading of (silica) fillers, introducing a large amount of interface. While silane coupling...
journal article 2022
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Putra, N.E. (author), Borg, K. G.N. (author), Diaz Payno, P.J. (author), Leeflang, M.A. (author), Klimopoulou, M. (author), Taheri, P. (author), Mol, J.M.C. (author), Fratila-Apachitei, E.L. (author), Zhou, J. (author), Zadpoor, A.A. (author)
Advanced additive manufacturing techniques have been recently used to tackle the two fundamental challenges of biodegradable Fe-based bone-substituting materials, namely low rate of biodegradation and insufficient bioactivity. While additively manufactured porous iron has been somewhat successful in addressing the first challenge, the limited...
journal article 2022
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Aghaeian, S. (author), Sloof, W.G. (author), Mol, J.M.C. (author), Bottger, A.J. (author)
High-temperature oxidation of steels can be relatively fast when exposed to air. Consequently, elucidating the effect of different parameters on the oxidation mechanism and kinetics is challenging. In this study, short-time oxidation was investigated to determine the oxidation mechanism, the affecting parameters, and the linear-to-parabolic...
journal article 2022
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Mol, Merel O. (author), van der Lee, S.J. (author), Hulsman, M. (author), Pijnenburg, Yolande A.L. (author), Scheltens, Phillip (author), Seelaar, Harro (author), van Swieten, John C. (author), Kaat, Laura Donker (author), Holstege, H. (author), van Rooij, Jeroen G.J. (author)
Background: Many families with clinical early-onset Alzheimer’s disease (EOAD) remain genetically unexplained. A combination of genetic factors is not standardly investigated. In addition to monogenic causes, we evaluated the possible polygenic architecture in a large series of families, to assess if genetic testing of familial EOAD could be...
journal article 2022
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Huang, Luyao (author), Chang, Weiwei (author), Zhang, Dawei (author), Huang, Ye (author), Li, Z. (author), Lou, Yuntian (author), Qian, Hongchang (author), Jiang, Chengying (author), Li, Xiaogang (author), Mol, J.M.C. (author)
The influence of outward extracellular electron transfer (EET) of Pseudomonas aeruginosa in accelerating corrosion of 304 stainless steel was investigated. With less NO<sub>3</sub><sup>−</sup> available as electron acceptor, P. aeruginosa biofilm accelerated the pitting corrosion. The ICP-MS and XPS results indicated that P. aeruginosa...
journal article 2022
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Suresh Babu, Diwakar (author), Mol, J.M.C. (author), Buijnsters, J.G. (author)
GenX is the trade name of the ammonium salt of hexafluoropropylene oxide dimer acid (HFPO-DA) and is used as a replacement for the banned perfluorooctanoic acid (PFOA). However, recent studies have found GenX to be more toxic than PFOA. This work deals with the electrochemical degradation of HFPO-DA using boron-doped diamond anodes. For the...
journal article 2022
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Putra, N.E. (author), Tigrine, A. (author), Aksakal, S. (author), de la Rosa, V. R. (author), Taheri, P. (author), Fratila-Apachitei, E.L. (author), Mol, J.M.C. (author), Zhou, J. (author), Zadpoor, A.A. (author)
Additively manufacturing of porous iron offers a unique opportunity to increase its biodegradation rate by taking advantage of arbitrarily complex porous structures. Nevertheless, achieving the required biodegradation profile remains challenging due to the natural passivation of iron that decrease the biodegradation rate. Moreover, the...
journal article 2022
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Dong, J. (author), Tümer, N. (author), Leeflang, M.A. (author), Taheri, P. (author), Fratila-Apachitei, E.L. (author), Mol, J.M.C. (author), Zadpoor, A.A. (author), Zhou, J. (author)
Porous biodegradable Mg and its alloys are considered to have a great potential to serve as ideal bone substitutes. The recent progress in additive manufacturing (AM) has prompted its application to fabricate Mg scaffolds with geometrically ordered porous structures. Extrusion-based AM, followed by debinding and sintering, has been recently...
journal article 2022
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Neupane, Shova (author), Losada-Pérez, Patricia (author), Tiringer, U. (author), Taheri, P. (author), Desta, Derese (author), Xie, Chenyang (author), Crespo, Daniel (author), Mol, J.M.C. (author), Milošev, Ingrid (author), Kokalj, Anton (author), Renner, Frank Uwe (author)
The initiation of corrosion can be triggered by defects in the adsorbed layer of organic inhibitors. A detailed knowledge of the intermolecular forces between the inhibitor molecules and the interfacial bonding will be decisive to unravel the mechanisms driving the corrosion initiation. In this work, adsorbed organic layers of 2-mercapto-5...
journal article 2021
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Cutz, L. (author), Tiringer, U. (author), Gilvari, H. (author), Schott, D.L. (author), Mol, J.M.C. (author), de Jong, W. (author)
The use of biomass pellets as a source of renewable energy has increased in recent times. However, pellet storage during transportation can compromise their properties, due to fluctuating temperature and humid environments. Here, we show that extended storage of one month at 40 °C and 85% relative humidity causes significant biomass pellet...
journal article 2021
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Putra, N.E. (author), Leeflang, M.A. (author), Minneboo, M.B. (author), Taheri, P. (author), Fratila-Apachitei, E.L. (author), Mol, J.M.C. (author), Zhou, J. (author), Zadpoor, A.A. (author)
Extrusion-based 3D printing followed by debinding and sintering is a powerful approach that allows for the fabrication of porous scaffolds from materials (or material combinations) that are otherwise very challenging to process using other additive manufacturing techniques. Iron is one of the materials that have been recently shown to be...
journal article 2021
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Kokalj, Anton (author), Lozinšek, Matic (author), Kapun, Barbara (author), Taheri, P. (author), Neupane, Shova (author), Losada-Pérez, Patricia (author), Xie, Chenyang (author), Stavber, Stojan (author), Crespo, Daniel (author), Renner, Frank U. (author), Mol, J.M.C. (author), Milošev, Ingrid (author)
The often used simplistic correlations between molecular electronic parameters and experimentally determined corrosion inhibition efficiencies are critically evaluated for a set of 24 heterocyclic organic compounds, tested as corrosion inhibitors for copper in 3 wt.% NaCl aqueous solution. Twelve different molecular electronic descriptors...
journal article 2021
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Laucht, Arne (author), Hohls, Frank (author), Ubbelohde, Niels (author), Gonzalez-Zalba, M. Fernando (author), Scarlino, Pasquale (author), Koski, J.V. (author), Yang, Chih Hwan (author), Geresdi, A. (author), Mol, Jan A. (author)
Quantum phenomena are typically observable at length and time scales smaller than those of our everyday experience, often involving individual particles or excitations. The past few decades have seen a revolution in the ability to structure matter at the nanoscale, and experiments at the single particle level have become commonplace. This has...
review 2021
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Li, Z. (author), Chang, Weiwei (author), Cui, Tianyu (author), Xu, Dake (author), Zhang, Dawei (author), Lou, Yuntian (author), Qian, Hongchang (author), Song, Hao (author), Mol, J.M.C. (author), Cao, Fahe (author), Gu, Tingyue (author), Li, Xiaogang (author)
Microbiologically influenced corrosion of metals is prevalent in both natural and industrial environments, causing enormous structural damage and economic loss. Exactly how microbes influence corrosion remains controversial. Here, we show that the pitting corrosion of stainless steel is accelerated in the presence of Shewanella oneidensis MR...
journal article 2021
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