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Assi, H. (author), Pardo Pérez, Laura C. (author), Mouchaham, Georges (author), Ragon, Florence (author), Nasalevich, M. (author), Guillou, Nathalie (author), Martineau, Charlotte (author), Chevreau, Hubert (author), Kapteijn, F. (author), Gascon, Jorge (author), Fertey, Pierre (author), Elkaim, Erik (author), Serre, Christian (author), Devic, Thomas (author)
The reactivity of 2,5-dihydroxyterephthalic acid (H<sub>4</sub>DOBDC) with titanium(IV) precursors was thoroughly investigated for the synthesis of metal-organic frameworks under solvothermal conditions. Four crystalline phases were isolated whose structures were studied by a combination of single-crystal or powder X-ray diffraction and solid...
journal article 2016
document
Juan-Alcaniz, J. (author), Gielisse, R. (author), Lago, A.B. (author), Ramos-Fernandez, E.V. (author), Serra-Crespo, P. (author), Devic, T. (author), Guillou, N. (author), Serre, C. (author), Kapteijn, F. (author), Gascon, J. (author)
In this work, the inclusion of free sulfonic acid groups in highly stable MOFs is explored. The synthesized catalysts have been applied in a model esterification reaction. Two metal organic frameworks bearing sulfonic acid moieties are investigated: HSO3-MIL-101(Cr) synthesized following different approaches and a new structure based on HSO3-bdc...
journal article 2013