A novel lattice model to predict chloride diffusion coefficient of unsaturated cementitious materials based on multi-typed pore structure characteristics

This paper develops a novel lattice diffusive model to quantitatively study the chloride diffusion coefficient in unsaturated cementitious materials, in which the pore voxels are redistributed to make a better representation of a real microstructure of hardened cement paste. Considering the hierarchical microstructure and different drying...

Towards understanding deformation and fracture in cementitious lattice materials: Insights from multiscale experiments and simulations

Tailoring lattice structures is a commonly used method to develop lattice materials with desired mechanical properties. However, for cementitious lattice materials, besides the macroscopic lattice structure, the multi-phase microstructure of cement paste may have substantial impact on the mechanical responses. Therefore, this work proposes a...

Architected Cementitious Cellular Materials: Peculiarities and opportunities

Conventionally, the properties of cementitious materials are tailored by a simple but efficient method: mixture proportion design. For a given cementitious mixture, the chemical and physical properties of cementitious materials have already been determined. Consequently, the mechanical performance of the hardened cementitious material is...

Freeze-thaw resistance and air-void analysis of concrete with recycled glass-pozzolan using X-ray micro-tomography

Recent studies have shown promising potential for using Glass Pozzolan (GP) as an alternative supplementary cementitious material (SCM) due to the scarcity of fly ash and slag in the United States. However, comprehensive studies on the freeze-thaw (FT) resistance and air void system of mixtures containing GP are lacking. Therefore, this study...

Engineering of green cementitious composites modified with siliceous fly ash: Understanding the importance of curing conditions

Siliceous fly ash can be applied as a cement replacement material for mortars used in cement-based floor overlays. At present, there is no knowledge of the appropriate curing conditions that need to be applied on concrete floors. Moreover, previous research related to curing conditions has left research gaps related to the conditions in which...

Reactions of self-healing agents and the chemical binding of aggressive ions in sea water: Thermodynamics and kinetics

New self-healing agents that can chemically bind seawater ions invading cracked cementitious materials were proposed. The potential of self-healing and binding of seawater ions were investigated by thermodynamic modeling. It was found that CaO-NaAlO₂ and CaO-metakaolin agents can have Cl⁻, SO₄²⁻ and...

Sodium silicate/polyurethane microcapsules synthesized for enhancing self-healing ability of cementitious materials: Optimization of stirring speeds and evaluation of self-healing efficiency

In this study, stirring speeds during the synthesizing process of the sodium silicate/polyurethane microcapsules were optimized. The yield values of microcapsules at different stirring rates were evaluated. Based on the yield values and shape of microcapsules, optimized microcapsules were obtained. The measurements of the shell thickness of...

An Improved Test for Generating Rapid, Accurate, and Reliable Crack Permeability Data for Cementitious Materials

Presented is a modified test for generating crack permeability data for cementitious materials. Single-parallel cracks were generated in mortar specimens. The width of the cracks was analysed through stereomicroscope and computer tomography, and the water permeability of the cracks was determined. Reduction factors and crack flow models were...

Self-sealing cementitious materials by using water-swelling rubber particles

Water ingress into cracked concrete structures is a serious problem, as it can cause leakage and reinforcement corrosion and thus reduce functionality and safety of the structures. In this study, the application of water-swelling rubber particles for providing the cracked concrete a self-sealing function was developed. The feasibility of...