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Rauch, M.C.R. (author), Tieves, F. (author), Paul, C.E. (author), Arends, I.W.C.E. (author), Alcalde, Miguel (author), Hollmann, F. (author)
Biocatalytic oxyfunctionalisation reactions are traditionally conducted in aqueous media limiting their production yield. Here we report the application of a peroxygenase in neat reaction conditions reaching product concentrations of up to 360 mM.
journal article 2019
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Ma, Yunjian (author), Li, Yongru (author), Ali, Shahid (author), Li, Peilin (author), Zhang, W. (author), Rauch, M.C.R. (author), Willot, S.J. (author), Ribitsch, Doris (author), Hollmann, F. (author)
Natural deep eutectic solvents (NADES) are proposed as alternative solvents for peroxygenase-catalysed oxyfunctionalization reactions. Choline chloride-based NADES are of particular interest as they can serve as solvent, enzyme-stabiliser and sacrificial electron donor for the in situ H<sub>2</sub>O<sub>2</sub> generation. This report...
journal article 2019