Signal-dependent reactivity of host-guest complexes controls supramolecular aggregate formation

Living systems can respond to their environment through signal transduction cascades. In these cascades, original stimuli are amplified and translated into reaction or assembly events. In an effort to instill synthetic materials with biomimetic responsivity, we report an aggregation process forming a supramolecular network held together by...

Chemical signal regulated injectable coacervate hydrogels

In the quest for stimuli-responsive materials with specific, controllable functions, coacervate hydrogels have become a promising candidate, featuring sensitive responsiveness to environmental signals enabling control over sol-gel transitions. However, conventional coacervation-based materials are regulated by relatively non-specific signals,...

A fuel-driven chemical reaction network based on conjugate addition and elimination chemistry

Fuel-driven chemical reaction networks provide an opportunity to develop chemical systems that operate out-ofequilibrium. There remains a need to design and develop new fueldriven chemical reaction networks capable of repeated operation using simple and benign chemistry. Here, we propose a new chemical reaction network for fuel-driven transient...