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Sun, X. (author), Olivos Suarez, A.I. (author), Oar-Arteta Gonzalez, L. (author), Rozhko, E. (author), Osadchii, D. (author), Bavykina, A.V. (author), Kapteijn, F. (author), Gascon, Jorge (author)A Co@N-doped carbon (Co@ NC) hybrid was synthesized by thermal decomposition of the metal–organic framework (MOF) ZIF-67 under N2 atmosphere. These hybrid materials exhibit outstanding catalytic activity and chemoselectivity for the conversion of a wide range of substituted nitroarenes to their corresponding anilines under relatively mild...journal article 2017
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Bavykina, A.V. (author), Mautscke, H.H. (author), Makkee, M. (author), Kapteijn, F. (author), Gascon, Jorge (author), Llabres i Xamena, FX (author)Isomerisation of allylic alcohols to saturated ketones can be efficiently catalysed by a heterogeneous molecular system resulting from IrIIICp* anchoring to a covalent triazine framework. The obtained catalysts are active, selective, and fully recyclable.journal article 2017
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Garcia Santaclara, J. (author), Olivos Suarez, A.I. (author), du Fossé, Indy (author), Houtepen, A.J. (author), Hunger, J (author), Kapteijn, F. (author), Gascon, Jorge (author), van der Veen, M.A. (author)The highly porous titanium based metal–organic framework NH2-MIL-125(Ti) has recently attracted significant attention in the field of photocatalysis as a promising material for H+ reduction. This work reveals charge transfer upon visible light illumination from this MOF to two different charge acceptors, as an alternative to sacrificial electron...journal article 2017
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Rogge, S.M.J. (author), Bavykina, A.V. (author), Hajek, Julianna (author), Garcia, H (author), Olivos Suarez, A.I. (author), Sepúlveda-Escribano, A. (author), Vimont, A. (author), Clet, G (author), Bazin, P. (author), Kapteijn, F. (author), Daturi, Marco (author), Ramos-Fernandez, E.V. (author), Llabres i Xamena, FX (author), Van Speybroeck, V (author), Gascon, Jorge (author)Heterogeneous single-site catalysts consist of isolated, well-defined, active sites that are spatially separated in a given solid and, ideally, structurally identical. In this review, the potential of metal–organic frameworks (MOFs) and covalent organic frameworks (COFs) as platforms for the development of heterogeneous single-site catalysts is...journal article 2017
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Oar-Arteta Gonzalez, L. (author), Wezendonk, T.A. (author), Sun, X. (author), Kapteijn, F. (author), Gascon, Jorge (author)The use of metal organic frameworks as hard templates for the preparation of heterogeneous catalysts is thoroughly reviewed. In this critical article, the main factors to consider when using a MOF as a sacrificial template are first discussed. Then, the existing literature on the topic is reviewed, classifying the different examples according to...journal article 2017
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Garcia Santaclara, J. (author), Kapteijn, F. (author), Gascon, Jorge (author), van der Veen, M.A. (author)The fascinating chemical and physical properties of MOFs have recently stimulated exploration of their application for photocatalysis. Despite the intense research effort, the efficiency of most photocatalytic MOFs for solar fuel generation is still very modest. In this highlight we analyse the current status of the field and stress the...journal article 2017
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Álvarez, Andrea (author), Bansode, Atul (author), Urakawa, Atsushi (author), Bavykina, A.V. (author), Wezendonk, T.A. (author), Makkee, M. (author), Gascon, Jorge (author), Kapteijn, F. (author)The recent advances in the development of heterogeneous catalysts and processes for the direct hydrogenation of CO2 to formate/formic acid, methanol, and dimethyl ether are thoroughly reviewed, with special emphasis on thermodynamics and catalyst design considerations. After introducing the main motivation for the development of such processes,...journal article 2017
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Wezendonk, T.A. (author), Warringa, Quirinus S E (author), Santos, Vera P. (author), Chojecki, Adam (author), Ruitenbeek, Matthijs (author), Meima, Garry (author), Makkee, M. (author), Kapteijn, F. (author), Gascon, Jorge (author)The structure and elementary composition of various commercial Fe-based MOFs used as precursors for Fischer-Tropsch synthesis (FTS) catalysts have a large influence on the high-temperature FTS activity and selectivity of the resulting Fe on carbon composites. The selected Fe-MOF topologies (MIL-68, MIL-88A, MIL-100, MIL-101, MIL-127, and Fe...journal article 2017
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Schäfer, P. (author), Kapteijn, F. (author), van der Veen, M.A. (author), Domke, Katrin F. (author)The room temperature growth kinetics of the commonly studied metal-organic framework CuBTC (HKUST-1) is investigated with UV/vis absorption spectroscopy. Contrary to chemical intuition, increased concentrations of the BTC ligand slows down the formation of CuBTC. Based on the time-resolved experimental data, a kinetic model is proposed for...journal article 2017
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Santos, Vera P. (author), Borgers, Liam (author), Sartipi, Sina (author), van der Linden, B. (author), Dugulan, A.I. (author), Chojecki, A (author), Davidian, T (author), Ruitenbeek, M (author), Meima, GR (author), Kapteijn, F. (author), Makkee, M. (author), Gascon, Jorge (author)tA series of Fe-Ti mixed oxide model catalysts containing different Ti/Fe ratios were synthesized andapplied as catalysts for the High Temperature Fischer-Tropsch reaction (HTFTS). XRD, H2-TPR and in situMössbauer and XAFS spectroscopy were applied to evaluate the role of Ti on the physical and chemicalproperties of Fe within the mixed metal...journal article 2017
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Yarulina, I. (author), Dikhtiarenko, A. (author), Kapteijn, F. (author), Gascon, Jorge (author)Zeolites with DDR (Sigma-1 and ZSM-58) and CHA (SSZ-13) topology were synthesized by seed assisted and direct hydrothermal synthesis in order to investigate the effects of fast crystal growth on catalytic performance. Application of small amount of seeds (0.1% wt) significantly reduced synthesis time of all the studied zeolites. XRD and NH...journal article 2017
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ten Dam, J. (author), Ramanathan, A. (author), Djanashvili, K. (author), Kapteijn, F. (author), Hanefeld, U. (author)The synthesis of a series of bifunctional catalysts (1 wt% Pt/W-TUD-1 (Technische Universiteit Delft-1) and 1 wt% Pt/WO<sub>3</sub>/TUD-1) with different tungsten loadings (5-30 wt% WO<sub>3</sub>) is described. They were characterized using ICP-OES, INAA, N<sub>2</sub> physisorption, XRD and TEM. Their catalytic performance (activity and...journal article 2017
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Eslava, José L. (author), Sun, X. (author), Gascon, Jorge (author), Kapteijn, F. (author), Rodríguez-Ramos, Inmaculada (author)The effect of ruthenium particle size on Fischer-Tropsch synthesis (FTS) has been studied at 513 K, H<sub>2</sub>/CO = 2 and 15 bar. Supported Ru catalysts with particle sizes ranging from 1.7 to 12 nm were prepared by using different Ru loadings and two different high surface area graphite (HSAG) supports to minimize the metal-support...journal article 2017
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Kosinov, Nikolay (author), Coumans, Ferdy J A G (author), Uslamin, Evgeny (author), Kapteijn, F. (author), Hensen, Emiel J M (author)Non-oxidative methane dehydroaromatization is a promising reaction to directly convert natural gas into aromatic hydrocarbons and hydrogen. Commercialization of this technology is hampered by rapid catalyst deactivation because of coking. A novel approach is presented involving selective oxidation of coke during methane dehydroaromatization...journal article 2016
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Puspitasari, I. (author), Skupien, E. (author), Kapteijn, F. (author), Kooyman, P.J. (author)To prevent sintering, ozone treatment at mild temperature is used to remove the capping agent from supported Au nanoparticles. The Au nanoparticles are first synthesized as a colloidal solution and then supported on alumina. Fourier Transform Infra Red (FTIR) shows the capping agent is removed completely. Transmission Electron Microscopy (TEM...journal article 2016
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Assi, H. (author), Pardo Pérez, Laura C. (author), Mouchaham, Georges (author), Ragon, Florence (author), Nasalevich, M. (author), Guillou, Nathalie (author), Martineau, Charlotte (author), Chevreau, Hubert (author), Kapteijn, F. (author), Gascon, Jorge (author), Fertey, Pierre (author), Elkaim, Erik (author), Serre, Christian (author), Devic, Thomas (author)The reactivity of 2,5-dihydroxyterephthalic acid (H<sub>4</sub>DOBDC) with titanium(IV) precursors was thoroughly investigated for the synthesis of metal-organic frameworks under solvothermal conditions. Four crystalline phases were isolated whose structures were studied by a combination of single-crystal or powder X-ray diffraction and solid...journal article 2016
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Hakeem, A. (author), Rajendran, Jaikishen (author), Kapteijn, F. (author), Makkee, M. (author)Sulfur addition is used to probe the role of gold in Au/Fe<sub>2</sub>O<sub>3</sub>/ZrO<sub>2</sub> catalyst in the water-gas shift (WGS) at high temperature (623-773 K) and pressure (21 bar). Sulfur poisoning unravels the WGS activity contribution by gold nano-particles and gold promotion of iron oxide in Au/Fe<sub>2</sub>O<sub>3</sub>/ZrO...journal article 2016
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Bavykina, A.V. (author), Rozhko, E. (author), Goesten, M.G. (author), Wezendonk, T.A. (author), Seoane, Beatriz (author), Kapteijn, F. (author), Makkee, M. (author), Gascon, Jorge (author)A facile one-step method to shape covalent triazine frameworks (CTFs) for catalytic applications is reported. Phase inversion of the CTF powder by using a polyimide as a binder in a microfluidic device results in the formation of composite spheres with accessible CTF porosity and a high mechanical and thermal stability. The fabricated spheres...journal article 2016
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Wang, Y. (author), Posthuma De Boer, J (author), Kapteijn, F. (author), Makkee, M. (author)Temporal analysis of product (TAP) is used to investigate the effectiveness of CO, C<sub>3</sub>H<sub>6</sub>, and C<sub>3</sub>H<sub>8</sub> in the reduction of a La–Zr doped ceria catalyst and NO reduction into N<sub>2</sub> over this pre-reduced catalyst. Hydrocarbons are found to be substantially more effective in the reduction of this...journal article 2016
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Goesten, M.G. (author), de Lange, M.F. (author), Olivos Suarez, A.I. (author), Bavykina, A.V. (author), Serra Crespo, P. (author), Krywka, C. (author), Bickelhaupt, F. M. (author), Kapteijn, F. (author), Gascon, Jorge (author)Chemical clocks are often used as exciting classroom experiments, where an induction time is followed by rapidly changing colours that expose oscillating concentration patterns. This type of reaction belongs to a class of nonlinear chemical kinetics also linked to chaos, wave propagation and Turing patterns. Despite its vastness in occurrence...journal article 2016