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Tiihonen, L.V. (author), Bernardo, Gabriel (author), Dalgliesh, Robert M. (author), Mendes, Adélio (author), Parnell, S.R. (author)
Cellulose membranes were prepared from an EMIMAc ionic liquid solution by nonsolvent-induced phase separation (NIPS) in coagulation baths of water–acetone mixtures, ethanol–water mixtures and water at different temperatures. High water volume fractions in the coagulation bath result in a highly reproducible gel-like structure with...
journal article 2024
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Zhang, M. (author), Arunachalam, Abinaya (author), Perrin, H.R.L. (author), Polat, S. (author), Groenewold, Jan (author), Mendes, E. (author), Eral, H.B. (author)
Elevated humidity levels in medical, food, and pharmaceutical products may reduce the products' shelf life, trigger bacterial growth, and even lead to complete spoilage. In this study, we report a humidity indicator that mechanically bends and rolls itself irreversibly upon exposure to high humidity conditions. The indicator is made of two...
journal article 2023
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Cardoso, Rafaela (author), Ramon-Tarragona, Anna (author), Lourenço, Sérgio (author), Mendes, João (author), Caruso, Marco (author), Jommi, C. (author)
Monitoring structural behavior of earth structures during construction and in service is a common practice done for safety reasons, consolidation control and maintenance needs. Several are the techniques available for measuring displacements, water pressures and total stresses, not only in these geotechnical structures but also at their...
book chapter 2023
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Lakshminarayanan, Vasudevan (author), Chockalingam, Cindhuja (author), Mendes, E. (author), van Esch, J.H. (author)
Properties such as shear modulus, gelation time, structure of supramolecular hydrogels are strongly dependent on self-assembly, gelation triggering mechanism and processes used to form the gel. In our work we extend reported rheology analysis methodologies to pH-triggered supramolecular gels to understand structural insight using a model...
journal article 2021
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Wang, Yiming (author), Piskorz, T.K. (author), Lovrak, M. (author), Mendes, E. (author), Guo, Xuhong (author), Eelkema, R. (author), van Esch, J.H. (author)
Here, transient supramolecular hydrogels that are formed through simple aging-induced seeded self-assembly of molecular gelators are reported. In the involved molecular self-assembly system, multicomponent gelators are formed from a mixture of precursor molecules and, typically, can spontaneously self-assemble into thermodynamically more...
journal article 2020
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El Asjadi, S. (author), Lakshminarayanan, V. (author), Besseling, N.A.M. (author), Picken, S.J. (author), Mendes, E. (author)
This study investigates the stabilization of oil/water emulsions as a function of addition of a biopolymer (scleroglucan) which acts as an emulsion stabilizer. Rheological characterization in the form of controlled stress creep measurements has been carried out and it reveals the colloidal gel exhibiting a delayed yielding in a certain...
journal article 2020
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van der Helm, M. (author), Wang, Chang Lin (author), Fan, B. (author), Macchione, M. (author), Mendes, E. (author), Eelkema, R. (author)
Signal transduction in living systems is the conversion of information into a chemical change, and is the principal process by which cells communicate. In nature, these functions are encoded in non-equilibrium (bio)chemical reaction networks (CRNs) controlled by enzymes. However, man-made catalytically controlled networks are rare. We...
journal article 2020
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Wang, Yiming (author), Xu, Zhi (author), Lovrak, M. (author), le Sage, V.A.A. (author), Zhang, K. (author), Guo, Xuhong (author), Eelkema, R. (author), Mendes, E. (author), van Esch, J.H. (author)
Supramolecular structures with strain-stiffening properties are ubiquitous in nature but remain rare in the lab. Herein, we report on strain-stiffening supramolecular hydrogels that are entirely produced through the self-assembly of synthetic molecular gelators. The involved gelators self-assemble into semi-flexible fibers, which thereby...
journal article 2020
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Bernardo, Gabriel (author), Melle-Franco, Manuel (author), Washington, Adam L. (author), Dalgliesh, Robert M. (author), Li, Fankang (author), Mendes, Adélio (author), Parnell, S.R. (author)
Fullerene derivatives are used in a wide range of applications including as electron acceptors in solution-processable organic photovoltaics. We report agglomeration of fullerene derivatives in optically opaque solutions of PC<sub>61</sub>BM and PC<sub>71</sub>BM, with concentrations ranging from 30 mg mL<sup>-1</sup> up to 90 mg mL<sup>-1<...
journal article 2020
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Liu, Q. (author), Zhao, M. (author), Mytnyk, S. (author), Klemm, B. (author), Zhang, K. (author), Wang, Y. (author), Yan, Dadong (author), Mendes, E. (author), van Esch, J.H. (author)
Hydrogel microparticles are important in materials engineering, but their applications remain limited owing to the difficulties associated with their manipulation. Herein, we report the self-orientation of crescent-shaped hydrogel microparticles and elucidate its mechanism. Additionally, the microparticles were used, for the first time, as...
journal article 2019
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Hubbe, H.M.K. (author), Mendes, E. (author), Boukany, P. (author)
Polymer nanowire-related research has shown considerable progress over the last decade. The wide variety of materials and the multitude of well-established chemical modifications have made polymer nanowires interesting as a functional part of a diagnostic biosensing device. This review provides an overview of relevant publications addressing...
review 2019
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Lakshminarayanan, Vasudevan (author), Poltorak, L. (author), Bosma, D. (author), Sudhölter, Ernst J. R. (author), van Esch, J.H. (author), Mendes, E. (author)
Controlled localization of platinum nanoparticles (Pt NPs) at a solid support assisted by a polarized liquid-liquid interface is reported. Electrocatalytic water oxidation resulted in local pH modulation followed by the directed self-assembly of a dibenzoyl-l-cystine hydrogelator forming a structured hydrogel retaining the shape of the Pt NP...
journal article 2019
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Zheng, G. (author), Samkharadze, Nodar (author), Noordam, M.L. (author), Kalhor, N. (author), Brousse, D. (author), Sammak, A. (author), Mendes, U. C. (author), Blais, A. (author), Scappucci, G. (author), Vandersypen, L.M.K. (author)
We demonstrate the strong coupling between a single electron spin in silicon and a single photon in a superconducting microwave cavity. Using the same cavity we perform rapid high-fidelity single-shot readout of two-electron spin states.
conference paper 2019
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El Asjadi, S. (author), Nederpel, Q. A. (author), Cotiuga, I. M. (author), Picken, S.J. (author), Besseling, N.A.M. (author), Mendes, E. (author), Lommerts, B. J. (author)
In this study, we investigated the Stabilization of bitumen emulsions by scleroglucan, a rigid triple-helix forming biopolymer, in combination with a pH-sensitive cationic surfactant. Various aspects of the emulsification process and the final composition influence the Stabilization. We examined two different methods to add scleroglucan to...
journal article 2018
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Samkharadze, Nodar (author), Zheng, G. (author), Kalhor, N. (author), Brousse, D. (author), Sammak, A. (author), Mendes, U. C. (author), Blais, A. (author), Scappucci, G. (author), Vandersypen, L.M.K. (author)
Long coherence times of single spins in silicon quantum dots make these systems highly attractive for quantum computation, but how to scale up spin qubit systems remains an open question. As a first step to address this issue, we demonstrate the strong coupling of a single electron spin and a single microwave photon. The electron spin is...
journal article 2018
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Zhang, K. (author), Gil Arranja, A. (author), Chen, Hongyu (author), Mytnyk, S. (author), Wang, Y. (author), Oldenhof, S. (author), van Esch, J.H. (author), Mendes, E. (author)
The last decade has witnessed great progress in understanding and manipulating self-assembly of block copolymers in solution. A wide variety of micellar structures can be created and many promising applications in bioscience have been reported. In particular, nano-fibrous micelles provide a great platform to mimic the filamentous structure of...
journal article 2018
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Zhang, K. (author), Suratkar, A.P. (author), Vedaraman, S. (author), Lakshminarayanan, V. (author), Jennings, L. (author), Glazer, P.J. (author), van Esch, J.H. (author), Mendes, E. (author)
While the formation of (tri)block copolymer hydrogels has been extensively investigated, such studies mostly focused on equilibrium self-assembling whereas the use of preformed structures as building blocks such as out of equilibrium, quenched, nanofibrillar micelles is still a challenge. Here, we demonstrate that quenched, ultralong...
journal article 2018
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Wedege, Kristina (author), Bae, D. (author), Smith, W.A. (author), Mendes, Adélio (author), Bentien, Anders (author)
In recent years, research in solar energy storage with photoelectrochemical cells (i.e., solar redox flow batteries: SRFBs) has resurged. This development is emerging in parallel with the growing field of research into organic redox couples intended for aqueous redox flow batteries (RFBs) in a range of different pH environments. In a solar...
journal article 2018
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Jennings, Laurence (author), Waton, Gilles (author), Schosseler, François (author), Mendes, E. (author)
Kinetically frozen copolymer micelles are commonly prepared by confining amphiphilic block copolymers in the evaporating dispersed phase of oil-in-water emulsions. We revisit the mechanisms of this process by examining its successive steps separately: the formation of the solvent/water interface, the emulsification, the solvent evaporation and...
journal article 2017
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Mendes, M.F.S. (author), Pool, D.M. (author), van Paassen, M.M. (author)
conference paper 2017
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