Effects of mixing conditions and activator anionic species on the rheology of silicate-activated slag concrete

The proper control of the rheological performance of silicate-based alkali-activated slag (AAS) mixtures is problematic, as the conventional superplasticizers become less effective in alkaline media. Nevertheless, several methods have been proposed to improve the workability of silicate-activated AAS, such as by extending the mixing time, and...

Effect of High-Range Water-Reducing Admixtures on Alkali-Activated Slag Concrete

The rapid workability loss of alkali-activated materials (AAM) has been a major obstacle limiting its onsite application. In this study, two conventional SPs (made of polynaphthalene sulfonate (PNS) and lignosulfonate (LS) salts), which have been reported to be effective in some specific AAM mixtures were separately applied in alkali...

Utilizing Design of Experiments Approach to Assess Kinetic Parameters for a Mn Homogeneous Hydrogenation Catalyst

Homogeneous hydrogenation catalysts based on metal complexes provide a diverse and highly tunable tool for the fine chemical industry. To fully unleash their potential, fast and effective methods for the evaluation of catalytic properties are needed. In turn, this requires changes in the experimental approaches to test and evaluate the...

Characterization of epoxy-asphalt binders by differential scanning calorimetry

Asphalt binders incorporating different modifiers is a common practice but empirically driven in most of the cases. Therefore, the fundamental understanding of modification mechanisms in asphalt binders is needed to design polymer modified binders in a controllable manner, especially today in which new modification technologies are proposed....

Coupled thermodynamic modelling and experimental study of sodium hydroxide activated slag

In previous researches, the thermodynamic modelling of alkali-activated slag was conducted as a function of the degree of reaction of slag, which makes it difficult to compare the modelling results with the experimental results in a time scale. In this study, the reaction kinetics of sodium hydroxide activated slag was studied using...

Reaction Kinetics and Thermodynamic Modeling of Sodium Hydroxide Activated Slag Paste

The technology of alkaline activation of calcium aluminosilicate materials, as an alternative to Portland cement to produce a clinker-free material, can address the energy and environmental concerns associated with Portland cement production. As this technology attracts more and more attention in recent years, there are increasing researches...