Competitive Healing of Creep-Induced Damage in a Ternary Fe-3Au-4W Alloy

Autonomous healing of creep-induced grain boundary cavities by Au-rich and W-rich precipitates was studied in a Fe-3Au-4W (wt pct) alloy at a fixed temperature of 823 K (550 °C) with different applied stresses. The ternary alloy, with two supersaturated healing solutes, serves as a model system to study the interplay between two separate...

Surface precipitation of supersaturated solutes in a ternary Fe–Au–W alloy and its binary counterparts

Abstract: The precipitation of supersaturated solutes at free surfaces in ternary Fe–3Au–4W and binary Fe–3Au and Fe–4W alloys (composition in weight percentage) for different ageing times was investigated at a temperature of 700 °C. The time evolution of the surface precipitation is compared among the three alloys to investigate the...

Full strength and toughness recovery after repeated cracking and healing in bone-like high temperature ceramics

Bones of humans and animals combine two unique features, namely: they are brittle yet have a very high fracture toughness linked to the tortuosity of the crack path and they have the ability to repeatedly heal local fissures such that full recovery of overall mechanical properties is obtained even if the local bone structure is irreversibly...

Self healing of creep damage in iron-based alloys by supersaturated tungsten

When metals are mechanically loaded at elevated temperatures for extended periods of time, creep damage will occur in the form of cavities at grain boundaries. In the present experiments it is demonstrated that in binary iron-tungsten alloys creep damage can be self healed by selective precipitation of a W-rich phase inside these cavities. Using...

Kinetics of zircon formation in yttria partially stabilized zirconia as a result of oxidation of embedded molybdenum disilicide

Recently MoSi₂ sacrificial particles embedded in yttria partially stabilized zirconia (YPSZ)have been proposed as attractive healing agents to realize significant extension of the lifetime of the thermally loaded structures. Upon local fracture of the YPSZ, the embedded healing particles in the path and in the vicinity of the crack...

Determination of fracture strength and fracture energy of (metallo-) ceramics by a wedge loading methodology and corresponding cohesive zone-based finite element analysis

A wedge loaded testing methodology to determine the fracture energy and strength of (semi-) brittle (metallo-)ceramics is presented. The methodology combines a tailored specimen geometry and a comprehensive finite element analysis based on cohesive zone modelling. The use of a simulation-based approach to extract both fracture strength and...

Autonomous filling of grain-boundary cavities during creep loading in Fe-Mo alloys

We have investigated the autonomous repair of creep damage by site-selective precipitation in a binary Fe-Mo alloy (6.2 wt pct Mo) during constant-stress creep tests at temperatures of 813 K, 823 K, and 838 K (540 °C, 550 °C, and 565 °C). Scanning electron microscopy studies on the morphology of the creep-failed samples reveal irregularly...