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Assi, H. (author), Pardo Pérez, Laura C. (author), Mouchaham, Georges (author), Ragon, Florence (author), Nasalevich, M. (author), Guillou, Nathalie (author), Martineau, Charlotte (author), Chevreau, Hubert (author), Kapteijn, F. (author), Gascon, Jorge (author), Fertey, Pierre (author), Elkaim, Erik (author), Serre, Christian (author), Devic, Thomas (author)The reactivity of 2,5-dihydroxyterephthalic acid (H<sub>4</sub>DOBDC) with titanium(IV) precursors was thoroughly investigated for the synthesis of metal-organic frameworks under solvothermal conditions. Four crystalline phases were isolated whose structures were studied by a combination of single-crystal or powder X-ray diffraction and solid...journal article 2016
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Nasalevich, M. (author), Hendon, Christopher H. (author), Garcia Santaclara, J. (author), Svane, Katrine (author), van der Linden, B. (author), Veber, Sergey L. (author), Fedin, Matvey V. (author), Houtepen, A.J. (author), van der Veen, M.A. (author), Kapteijn, F. (author), Walsh, Aron (author), Gascon, Jorge (author)Metal-organic frameworks (MOFs) containing d<sup>0</sup> metals such as NH<sub>2</sub>-MIL-125(Ti), NH<sub>2</sub>-UiO-66(Zr) and NH<sub>2</sub>-UiO-66(Hf) are among the most studied MOFs for photocatalytic applications. Despite structural similarities, we demonstrate that the electronic properties of these MOFs are markedly different. As...journal article 2016
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Nasalevich, M.A. (author), Van der Veen, M. (author), Kapteijn, F. (author), Gascon, J. (author)The use of metal organic frameworks (MOFs) as heterogeneous photocatalysts is critically reviewed. First we revisit the general assumption of MOFs behaving truly as semiconductors, demonstrating that such semiconducting behaviour only occurs in a very limited subset of materials. Further, the main approaches for efficient light harvesting and...journal article 2014
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Sartipi, S. (author), Alberts, M. (author), Santos, V.P. (author), Nasalevich, M. (author), Gascon, J. (author), Kapteijn, F. (author)Mesoporous H-ZSM-5 (mesoH-ZSM-5) was used as a carrier for a series of bifunctional Co-based catalysts for Fischer–Tropsch synthesis with ZrO2 and/or Ru added as promoters. The reducibility of the catalysts was studied in detail by using temperature-programmed reduction and X-ray absorption spectroscopy. A comparison of the catalytic performance...journal article 2013
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Nasalevich, M.A. (author), Goesten, M.G. (author), Savenije, T.J. (author), Kapteijn, F. (author), Gascon, J. (author)NH2-MIL-125(Ti) has been post-synthetically functionalized with dye-like molecular fragments. The new material (methyl red-MIL- 125(Ti)) exhibits improved light absorption over a wide range of the visible spectrum, and shows enhanced photocatalytic oxidation activity under visible light illumination. The consequences of functionalization and the...journal article 2013