Asymmetric α-benzylation of cyclic ketones enabled by concurrent chemical aldol condensation and biocatalytic reduction

Chemoenzymatic cascade catalysis has emerged as a revolutionary tool for streamlining traditional retrosynthetic disconnections, creating new possibilities for the asymmetric synthesis of valuable chiral compounds. Here we construct a one-pot concurrent chemoenzymatic cascade by integrating organobismuth-catalyzed aldol condensation with ene...

An inter-city energy migration framework for regional energy balance through daily commuting fuel-cell vehicles

Spatiotemporal energy interaction and sharing are promising solutions to penetrate renewable energy, enhance grid power stability, and improve regional energy flexibility. However, the current literature is restrained in a small-scale neighborhood level, without considering inter-city energy migration through spatiotemporal complementarity...

Artificial intelligence powered large-scale renewable integrations in multi-energy systems for carbon neutrality transition: Challenges and future perspectives

The vigorous expansion of renewable energy as a substitute for fossil energy is the predominant route of action to achieve worldwide carbon neutrality. However, clean energy supplies in multi-energy building districts are still at the preliminary stages for energy paradigm transitions. In particular, technologies and methodologies for large...

Quantification on fuel cell degradation and techno-economic analysis of a hydrogen-based grid-interactive residential energy sharing network with fuel-cell-powered vehicles

Hydrogen-based (H₂-based) interactive energy networks for buildings and transportations provide novel solutions for carbon-neutrality transition, regional energy flexibility and independence on fossil fuel consumption, where vehicle fuel cells are key components for H₂-electricity conversion and clean power supply....

Effect of ethanol concentration on methane hydrate decomposition: MD simulation insights

The controllability of mining is a key factor affecting the commercial application of methane hydrates, and the addition of chemical additives can significantly accelerate the mining process. However, the effect of additive concentration on hydrate decomposition is not yet well understood. In this study, we systematically investigate the...

Transformation towards a carbon-neutral residential community with hydrogen economy and advanced energy management strategies

Cleaner power production, distributed renewable generation, building-vehicle integration, hydrogen storage and associated infrastructures are promising for transformation towards a carbon–neutral community, whereas the academia provides limited information through integrated solutions, like intermittent renewable integration, hydrogen sharing...

Revealing the Impact of Space-Charge Layers on the Li-Ion Transport in All-Solid-State Batteries

The influence of space-charge layers on the ionic charge transport over cathode-solid electrolyte interfaces in all-solid-state batteries remains unclear because of the difficulty to unravel it from other contributions to the ion transport over the interfaces. Here, we reveal the effect of the space-charge layers by systematically tuning the...

Induction heating-assisted compaction in porous asphalt pavements: A computational study

Low temperature asphalt (LTA) technologies, such as warm-mixed asphalt mixes, are utilized in the paving industry to lower energy demands and greenhouse gas emissions during asphalt mixing and pavement construction. However, the asphalt mixes developed that incorporate LTA additives are more sensitive than hot-mixed asphalts to temperature...