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Li, Yongru (author), Ma, Yunjian (author), Li, Peilin (author), Zhang, Xizhen (author), Ribitsch, Doris (author), Alcalde, Miguel (author), Hollmann, F. (author), Wang, Yonghua (author)A bienzymatic cascade for selective sulfoxidation is presented. The evolved recombinant peroxygenase from Agrocybe aegeritra catalyses the enantioselective sulfoxidation of thioanisole whereas the choline oxidase from Arthrobacter nicotianae provides the H2 O2 necessary via reductive activation of ambient oxygen. The reactions are performed...journal article 2020
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Ma, Yunjian (author), Li, Yongru (author), Ali, Shahid (author), Li, Peilin (author), Zhang, W. (author), Rauch, M.C.R. (author), Willot, S.J. (author), Ribitsch, Doris (author), Hollmann, F. (author)Natural deep eutectic solvents (NADES) are proposed as alternative solvents for peroxygenase-catalysed oxyfunctionalization reactions. Choline chloride-based NADES are of particular interest as they can serve as solvent, enzyme-stabiliser and sacrificial electron donor for the in situ H<sub>2</sub>O<sub>2</sub> generation. This report...journal article 2019
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Ma, Yunjian (author), Li, Peilin (author), Li, Yongru (author), Willot, S.J. (author), Zhang, W. (author), Ribitsch, Doris (author), Choi, Young Hae (author), Verpoorte, Robert (author), Hollmann, F. (author)The use of natural deep eutectic solvents (NADES) as multifunctional solvents for limonene bioprocessing was reported. NADES were used for the extraction of limonene from orange peel wastes, as solvent for the chemoenzymatic epoxidation of limonene, and as sacrificial electron donor for the in situ generation of H <sub>2</sub> O <sub>2</sub>...journal article 2019