Highly efficient carbon assimilation and nitrogen/phosphorus removal facilitated by photosynthetic O₂ from algal-bacterial aerobic granular sludge under controlled DO/pH operation

Reducing CO₂ emission and energy consumption is crucial for the sustainable management of wastewater treatment plants (WWTPs). In this study, an algal-bacterial aerobic granular sludge (AGS) system was developed for efficient carbon (C) assimilation and nitrogen (N)/phosphorus (P) removal without the need for mechanical aeration....

2D Dion–Jacobson CsPbI₃ with Enhanced Interlayer Coupling for Stable and Efficient Photovoltaics

Inorganic 2D layered CsPbI₃ is awaiting to overcome the phase instability of traditional 3D components. However, the most reported Ruddlesden–Popper (RP) phase 2D CsPbI₃ leads to larger interlayer distance and weaker interlayer coupling since the existence of the van der Waals gap, which deteriorates the performance of...

Manipulate energy transport via fluorinated spacers towards record-efficiency 2D Dion-Jacobson CsPbI₃ solar cells

Two-dimensional (2D) Dion-Jacobson (D-J)-type cesium lead iodide CsPbI ₃ perform remarkably in terms of stability. However, the complex interactions between spacer and inorganic layers limit its excellent progress in perovskite solar cells (PSCs). Herein, starting from the considerable structural diversity of organic spacers, we...

A Novel Multiple-Ring Aromatic Spacer Based 2D Ruddlesden–Popper CsPbI₃ Solar Cell with Record Efficiency Beyond 16%

Two-dimensional (2D) Ruddlesden–Popper (RP) CsPbI₃ perovskite possesses superior phase stability by introducing steric hindrance. However, due to the quantum and dielectric confinement effect, 2D structures usually exhibit large exciton binding energy, and the charge tunneling barrier across the organic interlayer is difficult to...

An Interface Co-modification Strategy for Improving the Efficiency and Stability of CsPbI₃Perovskite Solar Cells

Interface engineering is a simple and effective strategy for improving the photovoltaic performance and stability of perovskite solar cells (PSCs). Herein, an interface co-modification strategy is proposed, using [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) and 2-fluoro-1,4-phenylenediammonium iodide (2FPPD) to modify the electron...

Guanidium-assisted crystallization engineering for highly efficient CsPbI₃ solar cells

Iodine vacancies and uncoordinated iodide ions of CsPbI₃ films are mainly responsible for nonradiative recombination. Here, we report a composition-engineering passivation method that through guanidium (GA⁺) and I⁻ forms strong hydrogen bonds to passivate iodine vacancies and reduce defects. Both experimental...

Solvent Engineering for High-Performance Two-Dimensional Ruddlesden-Popper CsPbI₃Solar Cells

Two-dimensional (2D) Ruddlesden-Popper (RP) CsPbI3 exhibits enhanced phase stability compared with 3D CsPbI3. However, the issue of the uncontrollable crystallization process limits its photovoltaic performance. Here, the influence of a binary mixed solvent on the film quality and photovoltaic properties of (PEA)2Cs4Pb5I16 (n = 5) is studied...