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Vasileiadis, A. (author), Zhou, Q. (author), Lu, Yaxiang (author), Li, Y. (author), Ombrini, P. (author), Chen, Z. (author), van der Jagt, R. (author), Ganapathy, S. (author), Wagemaker, M. (author)Correction to: Nature Energy, published online 3 January 2024. In the version of this article initially published, lithium (green, “Li”) and sodium (purple, “Na”) color key labels in Fig. 3a,d,e were interchanged and are now amended in the HTML and PDF versions of the article.journal article 2024
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Zhang, S. (author), Li, Yuhang (author), Bannenberg, L.J. (author), Liu, Ming (author), Ganapathy, S. (author), Wagemaker, M. (author)Formation cycling is a critical process aimed at improving the performance of lithium ion (Li-ion) batteries during subsequent use. Achieving highly reversible Li-metal anodes, which would boost battery energy density, is a formidable challenge. Here, formation cycling and its impact on the subsequent cycling are largely unexplored. Through...journal article 2024
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Wang, C. (author), Liu, M. (author), Bannenberg, L.J. (author), Zhao, C. (author), Thijs, M.A. (author), Boshuizen, B. (author), Ganapathy, S. (author), Wagemaker, M. (author)Lithium metal with its high theoretical capacity and low negative potential is considered one of the most important candidates to raise the energy density of all-solid-state batteries. However, lithium filament growth and its induced solid electrolyte decomposition pose severe challenges to realize a long cycle life. Here, dendrite growth in...journal article 2024
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Vasileiadis, A. (author), Zhou, Quan (author), Lu, Yaxiang (author), Li, Yu (author), Ombrini, P. (author), Chen, Zhao (author), van der Jagt, R. (author), Ganapathy, S. (author), Wagemaker, M. (author)Transport electrification and grid storage hinge largely on fast-charging capabilities of Li- and Na-ion batteries, but anodes such as graphite with plating issues drive the scientific focus towards anodes with slopped storage potentials. Here we report fast charging of ampere-hour-level full Na-ion batteries within about 9 minutes for...journal article 2024
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Schwietert, T.K. (author), Gautam, A. (author), Lavrinenko, A.K. (author), Drost, David (author), Famprikis, T. (author), Wagemaker, M. (author), Vasileiadis, A. (author)Due to their high ionic conductivity, lithium-ion conducting argyrodites show promise as solid electrolytes for solid-state batteries. Aliovalent substitution is an effective technique to enhance the transport properties of Li<sub>6</sub>PS<sub>5</sub>Br, where aliovalent Si substitution triples ionic conductivity. However, the origin of this...journal article 2024
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Wang, Q. (author), Zhou, Dong (author), Zhao, C. (author), Wang, Jianlin (author), Guo, Hao (author), Wang, Liguang (author), Yao, Zhenpeng (author), Lu, Jun (author), Wagemaker, M. (author)Sodium-ion batteries have not only garnered substantial attention for grid-scale energy storage owing to the higher abundance of sodium compared with lithium, but also present the possibility of fast charging because of the inherently higher sodium-ion mobility. However, it remains a phenomenal challenge to achieve a combination of these...journal article 2024
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Gao, Ziyao (author), Zhao, C. (author), Zhou, Kai (author), Wu, Junru (author), Tian, Yao (author), Deng, Xianming (author), Zhang, Lihan (author), Lin, Kui (author), Wagemaker, M. (author)Nickel-rich layered oxide cathodes promise ultrahigh energy density but is plagued by the mechanical failure of the secondary particle upon (de)lithiation. Existing approaches for alleviating the structural degradation could retard pulverization, yet fail to tune the stress distribution and root out the formation of cracks. Herein, we report...journal article 2024
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Wang, Q. (author), Zhou, Yunan (author), Wang, Xuelong (author), Guo, Hao (author), Gong, Shuiping (author), Yao, Zhenpeng (author), Ganapathy, S. (author), Zhao, C. (author), Wagemaker, M. (author)All-solid-state lithium batteries have attracted widespread attention for next-generation energy storage, potentially providing enhanced safety and cycling stability. The performance of such batteries relies on solid electrolyte materials; hence many structures/phases are being investigated with increasing compositional complexity. Among the...journal article 2024
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Wang, Q. (author), Zhao, C. (author), Yao, Zhenpeng (author), Wang, Jianlin (author), Wu, Fangting (author), Kumar, Sai Govind Hari (author), Ganapathy, S. (author), Eustace, S.J. (author), Wagemaker, M. (author)Developing liquid electrolytes with higher kinetics and enhanced interphase stability is one of the key challenges for lithium batteries. However, the poor solubility of lithium salts in solvents sets constraints that compromises the electrolyte properties. Here, it is shown that introducing multiple salts to form a high-entropy solution,...journal article 2023
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Liu, M. (author), Wang, C. (author), Zhao, C. (author), van der Maas, E.L. (author), Lin, Kui (author), Arszelewska, Violetta (author), Li, Baohua (author), Ganapathy, S. (author), Wagemaker, M. (author)The original version of this article contained errors in Figure 3a and Figure 3f. In Figure 3a, the activation energies (Ea) were calculated using a log scale instead of a logarithm ln scale. In Figure 3f, the y-axis interval was not properly selected. The correct y-axis interval in Figure 3f and the numerical values of the activation energy...journal article 2023
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Ombrini, P. (author), Bazant, Martin Z. (author), Wagemaker, M. (author), Vasileiadis, A. (author)Phase separation during the lithiation of redox-active materials is a critical factor affecting battery performance, including energy density, charging rates, and cycle life. Accurate physical descriptions of these materials are necessary for understanding underlying lithiation mechanisms, performance limitations, and optimizing energy...journal article 2023
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Gautam, A. (author), Al-Kutubi, H.A.A. (author), Famprikis, T. (author), Ganapathy, S. (author), Wagemaker, M. (author)Lithium argyrodite superionic conductors have recently gained significant attention as potential solid electrolytes for all-solid-state batteries because of their high ionic conductivity and ease of processing. Promising aspects of these materials are the ability to introduce halides (Li<sub>6-x</sub>PS<sub>5-x</sub>Hal<sub>1+x</sub>, Hal =...journal article 2023
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Wang, Zaifa (author), Wang, Zhenyu (author), Xue, Dingchuan (author), Zhao, Jun (author), Zhang, Xuedong (author), Geng, Lin (author), Li, Yanshuai (author), Du, Congcong (author), Wagemaker, M. (author)The rock-salt phase (RSP) formed on the surface of Ni-rich layered cathodes in liquid-electrolyte lithium-ion batteries is conceived to be electrochemically "dead". Here we show massive RSP forms in the interior of LiNi<sub>x</sub>Mn<sub>y</sub>Co<sub>(1−x-y)</sub>O<sub>2</sub> (NMC) crystals in sulfide based all solid state batteries (ASSBs)...journal article 2023
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Vasileiadis, A. (author), Li, Yuqi (author), Lu, Yaxiang (author), Hu, Yong Sheng (author), Wagemaker, M. (author)There are several questions and controversies regarding the Na storage mechanism in hard carbon. This springs from the difficulty of probing the vast diversity of possible configurational environments for Na storage, including surface and defect sites, edges, pores, and intercalation morphologies. In the effort to explain the observed voltage...journal article 2023
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Wang, Q. (author), Zhao, C. (author), Wang, Jianlin (author), Yao, Zhenpeng (author), Wang, Shuwei (author), Kumar, Sai Govind Hari (author), Ganapathy, S. (author), Eustace, S.J. (author), Wagemaker, M. (author)High-entropy alloys/compounds have large configurational entropy by introducing multiple components, showing improved functional properties that exceed those of conventional materials. However, how increasing entropy impacts the thermodynamic/kinetic properties in liquids that are ambiguous. Here we show this strategy in liquid electrolytes...journal article 2023
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Landgraf, V.R. (author), Famprikis, T. (author), de Leeuw, Joris (author), Bannenberg, L.J. (author), Ganapathy, S. (author), Wagemaker, M. (author)Most highly Li-conducting solid electrolytes (σ<sub>RT</sub> > 10<sup>-3</sup> S cm<sup>-1</sup>) are unstable against lithium-metal and suffer from detrimental solid-electrolyte decomposition at the lithium-metal/solid-electrolyte interface. Solid electrolytes that are stable against lithium metal thus offer a direct route to stabilize...journal article 2023
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van der Maas, E.L. (author), Famprikis, Theodosios (author), Pieters, S. (author), Dijkstra, Jonas P. (author), Li, Z. (author), Parnell, S.R. (author), Smith, Ronald I. (author), van Eck, Ernst R.H. (author), Ganapathy, S. (author), Wagemaker, M. (author)Chloride-based solid electrolytes are considered interesting candidates for catholytes in all-solid-state batteries due to their high electrochemical stability, which allows the use of high-voltage cathodes without protective coatings. Aliovalent Zr(iv) substitution is a widely applicable strategy to increase the ionic conductivity of Li<sub...journal article 2023
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Liu, M. (author), Zhang, S. (author), van Eck, Ernst R.H. (author), Wang, C. (author), Ganapathy, S. (author), Wagemaker, M. (author)The development of commercial solid-state batteries has to date been hindered by the individual limitations of inorganic and organic solid electrolytes, motivating hybrid concepts. However, the room-temperature conductivity of hybrid solid electrolytes is still insufficient to support the required battery performance. A key challenge is to...journal article 2022
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Liang, Jianwen (author), van der Maas, E.L. (author), Luo, Jing (author), Li, Xiaona (author), Chen, Ning (author), Adair, Keegan R. (author), Li, Weihan (author), Li, Junjie (author), Hu, Yongfeng (author), Liu, Jue (author), Zhang, Li (author), Zhao, W. (author), Parnell, S.R. (author), Ganapathy, S. (author), Wagemaker, M. (author)Understanding the relationship between structure, ionic conductivity, and synthesis is the key to the development of superionic conductors. Here, a series of Li<sub>3-3</sub><sub>x</sub>M<sub>1+</sub><sub>x</sub>Cl<sub>6</sub> (−0.14 < x ≤ 0.5, M = Tb, Dy, Ho, Y, Er, Tm) solid electrolytes with orthorhombic and trigonal structures are...journal article 2022
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van der Maas, E.L. (author), Zhao, W. (author), Cheng, Z. (author), Famprikis, T. (author), Thijs, M.A. (author), Parnell, S.R. (author), Ganapathy, S. (author), Wagemaker, M. (author)Li<sub>3</sub>YX<sub>6</sub>(X = Cl, Br) materials are Li-ion conductors that can be used as solid electrolytes in all solid-state batteries. Solid electrolytes ideally have high ionic conductivity and (electro)chemical compatibility with the electrodes. It was proven that introducing Br to Li<sub>3</sub>YCl<sub>6</sub>increases ionic...journal article 2022