Solid-State Infrared Upconversion in Perylene Diimides Followed by Direct Electron Injection

In this contribution we demonstrate a solid-state approach to triplet-triplet annihilation upconversion for application in a solar cell device in which absorption of near-infrared light is followed by direct electron injection into an inorganic substrate. We use time-resolved microwave photoconductivity experiments to study the injection of...

Interplay between Charge Carrier Mobility, Exciton Diffusion, Crystal Packing, and Charge Separation in Perylene Diimide-Based Heterojunctions

Two of the key parameters that characterize the usefulness of organic semiconductors for organic or hybrid organic/inorganic solar cells are the mobility of charges and the diffusion length of excitons. Both parameters are strongly related to the supramolecular organization in the material. In this work we have investigated the relation...