Near-infrared light-driven asymmetric photolytic reduction of ketone using inorganic-enzyme hybrid biocatalyst

Effective photolytic regeneration of the NAD(P)H cofactor in enzymatic reductions is an important and elusive goal in biocatalysis. It can, in principle, be achieved using a near-infrared light (NIR) driven artificial photosynthesis system employing H₂O as the sacrificial reductant. To this end we utilized TiO₂/reduced...

Size effect on compressive strength of foamed concrete: Experimental and numerical studies

This study investigates the size effect on the compressive strength of foamed concrete at the mesoscale level combining X-ray computed tomography (X-CT) and a discrete lattice model. Image segmentation techniques and X-CT were employed to obtain virtual specimens comprising hydrated cement paste and air voids. The lineal-path function and...

A theoretical study of atmospheric pollutant NO₂ on as-doped monolayer WS₂ based on DFT method

For the relevant properties of pristine and doped (Si, P, Se, Te, As) monolayer WS₂ before and after the adsorption of CO, CO₂, N₂, NO, NO₂ and O₂, density functional theory (DFT) calculations are made. Calculation results reveal that the monolayer WS₂ doped with P and As atoms...

Aqueous chemoenzymatic one-pot enantioselective synthesis of tertiary α-aryl cycloketonesviaPd-catalyzed C-C formation and enzymatic C=C asymmetric hydrogenation

An aqueous chemoenzymatic cascade reaction combining Pd-catalyzed C-C formation and enzymatic C=C asymmetric hydrogenation (AH) was developed for enantioselective synthesis of tertiary α-aryl cycloketones in good yields and excellent enantioselectivities. The stereopreference of the enzyme in AH of α-aryl cyclohexenones was studied. An...

Effects of a passive tuned mass damper on blade root impacts during the offshore mating process

Single-blade installation is a conventional method for installing blades on monopile-type offshore wind turbines. A jack-up crane vessel is commonly used, and individual blades are lifted to the tower top height and mated with the hub. The relative motions between the hub and blade root during the mating phase, partly due to wind-induced...

Effects of Wind-Wave Misalignment on a Wind Turbine Blade Mating Process: Impact Velocities, Blade Root Damages and Structural SafetyAssessment

Most wind turbine blades are assembled piece-by-piece onto the hub of a monopile-type offshore wind turbine using jack-up crane vessels. Despite the stable foundation of the lifting cranes, the mating process exhibits substantial relative responses amidst blade root and hub. These relative motions are combined effects of wave-induced monopile...