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Kapteijn, S. (author), Kim, Wansoo (author), Marchal Crespo, L. (author), Peternel, L. (author)
Walking is an essential part of almost all activities of daily living. We use different gait patterns in different situations, e.g., moving around the house, performing various sports, or when compensating for an injury. However, how humans perform this gait tailoring remains a partially unknown process. To this end, the influence of various...
conference paper 2022
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Kapteijn, J. (author)
doctoral thesis 1980
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Jacobs, A. (author), Vangrunderbeek, J. (author), Beckers, H. (author), De Schutter, F. (author), Luyten, J. (author), Van Landschoot, R. (author), Schoonman, J. (author), Kapteijn, F. (author), Moulijn, J. (author), Nater, K. (author), Prins, W. (author)
journal article 1993
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Van Miltenburg, A. (author), Gascon, J. (author), Zhu, W. (author), Kapteijn, F. (author), Moulijn, J.A. (author)
The adsorption of propylene and propane on zeolite NaX with and without a saturated (36 wt%) amount of CuCl have been investigated. The single component adsorption isotherms could be well described with a Dual-Site Langmuir model. The dispersion of CuCl results in a decrease of the maximum adsorption capacity of the zeolite for both components....
journal article 2008
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Sachdeva, S. (author), Pustovarenko, A. (author), Sudhölter, E.J.R. (author), Kapteijn, F. (author), De Smet, L.C.P.M. (author), Gascon, J. (author)
A study of a copper-based metal–organic framework (MOF) synthesized by an electrochemical route is presented. Morphological and adsorption properties of the MOF synthesized as bulk powder and on supported copper surfaces were investigated. Differences in these properties and structural refinement studies indicate that when 4,4?,4??-s-triazine-2...
journal article 2016
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Rodenas, T. (author), Van Dalen, M. (author), Garcia-Perez, E. (author), Serra-Crespo, P. (author), Zornoza, B. (author), Kapteijn, F. (author), Gascon, J. (author)
Mixed matrix membranes (MMMs) composed of metal organic framework (MOF) fi llers embedded in a polymeric matrix represent a promising alternative for CO 2 removal from natural gas and biogas. Here, MMMs based on NH 2 -MIL-53(Al) MOF and polyimide are successfully synthesized with MOF loadings up to 25 wt% and different thicknesses. At 308 K and ...
journal article 2013
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Zornoza, B. (author), Rodenas, T. (author), Tellez, C. (author), Coronas, J. (author), Gascon, J. (author), Kapteijn, F. (author)
journal article 2012
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Sartipi, S. (author), Jansma, H. (author), Bosma, D. (author), Boshuizen, B. (author), Makkee, M. (author), Gascon, J. (author), Kapteijn, F. (author)
Design and operation of a “six-flow fixed-bed microreactor” setup for Fischer-Tropsch synthesis (FTS) is described. The unit consists of feed and mixing, flow division, reaction, separation, and analysis sections. The reactor system is made of five heating blocks with individual temperature controllers, assuring an identical isothermal zone of...
journal article 2013
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Yarulina, I. (author), Goetze, J. (author), Gücüyener, C. (author), Van Thiel, L. (author), Dikhtiarenko, A. (author), Ruiz-Martinez, J. (author), Weckhuysen, B.M. (author), Gascon, J. (author), Kapteijn, F. (author)
A systematic study of the effect of physicochemical properties affecting catalyst deactivation, overall olefin selectivity and ethylene/propylene ratio during the methanol-to-olefins (MTO) reaction is presented for two zeolites with the DDR topology, namely Sigma-1 and ZSM-58. Both catalysts show high selectivity towards light olefins and...
journal article 2016
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De Lathouder, K.M. (author), Smeltink, M.W. (author), Straathof, A.J.J. (author), Paasman, M.A. (author), Van de Sandt, E.J.A.X. (author), Kapteijn, F. (author), Moulijn, J.A. (author)
The objective of this work was to develop a hydrogel-coated monolith for the entrapment of penicillin G acylase (E. coli, PGA). After screening of different hydrogels, chitosan was chosen as the carrier material for the preparation of monolithic biocatalysts. This protocol leads to active immobilized biocatalysts for the enzymatic hydrolysis of...
journal article 2008
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Goesten, M.G. (author), Kapteijn, F. (author), Gascon, J. (author)
Reticular design is a highly attractive concept, but coordination chemistry around the tectonic units of metal– organic frameworks (MOFs) and additional interplay with anionic and solvent species provide for dazzling complexity that effectively rules out structure prediction. We can however study the chemistry around pre-existing clusters, and...
journal article 2013
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Skupien, E. (author), Berger, R.J. (author), Santos, V.P. (author), Gascon, J. (author), Makkee, M. (author), Kreutzer, M.T. (author), Kooyman, P.J. (author), Moulijn, J.A. (author), Kapteijn, F. (author)
Benzyl alcohol oxidation was carried out in toluene as solvent, in the presence of the potentially inhibiting oxidation products benzaldehyde and benzoic acid. Benzoic acid, or a product of benzoic acid, is identified to be the inhibiting species. The presence of a basic potassium salt (K2CO3 or KF) suppresses this inhibition, but promotes the...
journal article 2014
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Moulijn, J.A. (author), Perez-Ramirez, J. (author), Van Diepen, A. (author), Kreutzer, M.T. (author), Kapteijn, F. (author)
The relevance of levels in space and time for chemical engineering are discussed. Catalysis Engineering is introduced as an emerging new discipline. In Catalysis Engineering three levels can be distinguished: the microlevel focusing on molecules and catalytic sites, the mesolevel focusing on the catalyst particle and the catalytic reactor, and...
journal article 2003
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García-Pérez, E. (author), Serra-Crespo, P. (author), Hamad, S. (author), Kapteijn, F. (author), Gascon, J. (author)
Simulation of gas adsorption in flexible porous materials is still limited by the slow progress in the development of flexible force fields. Moreover, the high computational cost of such flexible force fields may be a drawback even when they are fully developed. In this work, molecular simulations of gas adsorption and diffusion of carbon...
journal article 2014
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Valero-Romero, M.J. (author), Sartipi, S. (author), Sun, X. (author), Rodríguez-Mirasol, J. (author), Cordero, T. (author), Kapteijn, F. (author), Gascon, J. (author)
Mesoporous H-ZSM-5–carbon composites, prepared via tetrapropylammonium hydroxide (TPAOH) post treatment of H-ZSM-5 followed by deposition of pyrolytic carbon, have been used as the support for the preparation of Co-based Fischer–Tropsch catalysts. The resulting catalysts display an improved performance during Fischer–Tropsch synthesis (FTS),...
journal article 2016
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Binder, T. (author), Hibbe, F. (author), Chmelik, C. (author), Kärger, J. (author), Martinez-Joaristi, A. (author), Gascon, J. (author), Kapteijn, F. (author), Ruthven, D. (author)
Nanoporous host materials giving rise to transient guest profiles of cylindrical symmetry during molecular uptake and release are shown to provide particularly advantageous conditions for the study of guest diffusion by micro-imaging. Considering zeolites of structure type DDR (Deca-dodecasil 3R) as a host system and short-chain length...
journal article 2012
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Gora, L. (author), Kuhn, J. (author), Baimpos, T. (author), Nikolakis, V. (author), Kapteijn, F. (author), Serwicka, E.M. (author)
This report presents the development of new selective gas sensors utilizing a b-oriented silicalite-1 layer–magneto-elastic ribbon assembly. The key principle for the operation of these sensors is monitoring the changes in the resonance frequency of the Metglas® strip in relation to the concentration of a component in the gas phase. This...
journal article 2009
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Puspitasari, I. (author), Saputra, P. (author), Morana, B. (author), Mele, L. (author), Santagata, F. (author), Creemer, J.F. (author), Kapteijn, F. (author), Kooyman, P.J. (author)
journal article 2012
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Nasalevich, M.A. (author), Goesten, M.G. (author), Savenije, T.J. (author), Kapteijn, F. (author), Gascon, J. (author)
NH2-MIL-125(Ti) has been post-synthetically functionalized with dye-like molecular fragments. The new material (methyl red-MIL- 125(Ti)) exhibits improved light absorption over a wide range of the visible spectrum, and shows enhanced photocatalytic oxidation activity under visible light illumination. The consequences of functionalization and the...
journal article 2013
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Bakker, J.J.W. (author), Zieverink, M.M.P. (author), Kapteijn, F. (author), Moulijn, J.A. (author), Kreutzer, M.T. (author)
Segmented flow in standard GC capillary columns, with a heterogeneous Pd catalyst on the walls, gave rapid information about catalytic processes in them. The residence time and conversion was monitored visually, greatly simplifying bench-scale optimization. Examples show the benefits of the elimination of pore diffusion and axial dispersion....
journal article 2011
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