Aqueous chemoenzymatic one-pot enantioselective synthesis of tertiary α-aryl cycloketonesviaPd-catalyzed C-C formation and enzymatic C=C asymmetric hydrogenation

An aqueous chemoenzymatic cascade reaction combining Pd-catalyzed C-C formation and enzymatic C=C asymmetric hydrogenation (AH) was developed for enantioselective synthesis of tertiary α-aryl cycloketones in good yields and excellent enantioselectivities. The stereopreference of the enzyme in AH of α-aryl cyclohexenones was studied. An...

Effect of coarse aggregate size on non-uniform stress/strain and drying-induced microcracking in concrete

Non-uniform stresses, strains and microcracking of the concretes with three coarse aggregate sizes (5–10 mm, 10–16 mm, 16–20 mm) dried under 40% relative humidity (RH) for 60 days were quantified using digital image correlation and lattice fracture modelling. The influencing mechanism of coarse aggregate size on the drying-induced...

Investigation of drying-induced non-uniform deformation, stress, and micro-crack propagation in concrete

Concrete generally deforms and cracks in a non-uniform manner under drying-induced stress. This study used the lattice fracture model to simulate the drying-induced non-uniform deformations, stresses, and micro-crack propagation in concrete. Experiments were designed to validate the lattice fracture model, wherein the drying-induced non...

Effect of relative humidity on drying-induced damage in concrete: A comparative study of digital image correlation and lattice modelling

To assess the effect of relative humidity (RH) on drying-induced damage in concrete, the non-uniform strains and microcracks in concrete under different RH conditions were obtained using the digital image correlation (DIC) technique and lattice fracture model. The simulated non-uniform displacements were consistent with those captured using...

Luminescence of Ce3+ at two different sites in ?-Sr2P2O7 under vacuum ultraviolet-UV and x-ray excitation

A series of Ce3+ doped ?-Sr2?2xCexNaxP2O7 phosphor compounds has been prepared using a high-temperature solid-state reaction technique. The luminescence properties under vacuum ultraviolet-UV and x-ray excitation were studied. Luminescence spectra reveal three UV-emitting peaks at about 310, 330, and 350 nm from which we conclude that Ce3+...