Asymmetric α-benzylation of cyclic ketones enabled by concurrent chemical aldol condensation and biocatalytic reduction

Chemoenzymatic cascade catalysis has emerged as a revolutionary tool for streamlining traditional retrosynthetic disconnections, creating new possibilities for the asymmetric synthesis of valuable chiral compounds. Here we construct a one-pot concurrent chemoenzymatic cascade by integrating organobismuth-catalyzed aldol condensation with ene...

Continuous Fatty Acid Decarboxylation using an Immobilized Photodecarboxylase in a Membrane Reactor

The realm of photobiocatalytic alkane biofuel synthesis has burgeoned recently; however, the current dearth of well-established and scalable production methodologies in this domain remains conspicuous. In this investigation, we engineered a modified form of membrane-associated fatty acid photodecarboxylase sourced from Micractinium conductrix...

A data-driven high spatial resolution model of biomass accumulation and crop yield: Application to a fragmented desert-oasis agroecosystem

Information on crop yield is important for food security, in particular under the conditions of climate change and growing population worldwide. We developed a new fully distributed, high spatial resolution, model of biomass accumulation and crop yield applicable to a highly heterogeneous desert-oasis agroecosystem. The bulk of required input...

Contour Moments Based Manipulation of Composite Rigid-Deformable Objects With Finite Time Model Estimation and Shape/Position Control

The robotic manipulation of composite rigid-deformable objects (i.e., those with mixed nonhomogeneous stiffness properties) is a challenging problem with clear practical applications that, despite the recent progress in the field, it has not been sufficiently studied in the literature. To deal with this issue, in this article, we propose a...

Lanthanide-Doped Nanoprobes as Orthogonal NIR-II Fluorescence Channels for In Vivo Information Storage

Information storage in vivo will lead to next-generation identification and security authentication. Here, an information storage method was proposed for in vivo application by using a pair of lanthanide-doped nanoprobes (NdNPs and ErNPs) with orthogonal emissions in the second near-infrared window. The information is stored in different...

The aging effect in evolving scientific citation networks

The study of citation networks is of interest to the scientific community. However, the underlying mechanism driving individual citation behavior remains imperfectly understood, despite the recent proliferation of quantitative research methods. Traditional network models normally use graph theory to consider articles as nodes and citations as...

Degradation behaviors and in-vivo biocompatibility of a rare earth- and aluminum-free magnesium-based stent

Biodegradable stents can provide scaffolding and anti-restenosis benefits in the short term and then gradually disappear over time to free the vessel, among which the Mg-based biodegradable metal stents have been prosperously developed. In the present study, a Mg-8.5Li (wt.%) alloy (RE- and Al-free) with high ductility (> 40%) was...

Site Occupancies, VUV-UV-vis Photoluminescence, and X-ray Radioluminescence of Eu²⁺-Doped RbBaPO₄

RbBaPO4:Eu2+ phosphors have been prepared by a high-temperature solid-state reaction method, and the structure was determined by Rietveld refinement based on powder X-ray diffraction (P-XRD) data. Their VUV-UV-vis photoluminescence properties are systematically investigated with three objectives: (1) based on low-temperature spectra, we...

Study of Lateral Flow in a Stratified Tidal Channel-Shoal System: The Importance of Intratidal Salinity Variation

Lateral flow significantly contributes to the near-bottom mass transport of salinity in a channel-shoal system. In this study, an integrated tripod system was deployed in the transition zone of a channel-shoal system of the Changjiang Estuary (CE), China, to observe the near-bottom physics with high temporal/spatial resolution, particularly...

Identifying Spreading Sources and Influential Nodes of Hot Events on Social Networks

The rapid development of World Wide Web accelerates information spreading in various ways. Thanks to the emergence of multiple social platforms, some events which are not much attractive in the past can become social hot spots nowadays. In this paper, we study the information diffusion process of “IP MAN3 box office fraud”, which is widely...

A Concealed Car Extraction Method Based on Full-Waveform LiDAR Data

Concealed cars extraction from point clouds data acquired by airborne laser scanning has gained its popularity in recent years. However, due to the occlusion effect, the number of laser points for concealed cars under trees is not enough. Thus, the concealed cars extraction is difficult and unreliable. In this paper, 3D point cloud...

Controlling of merging electric field and IMF magnitude on storm-time changes in thermospheric mass density

The controls of merging electrical field, Em, and IMF (interplanetary magnetic field) magnitude, B, on the storm-time changes in upper thermospheric mass density are statistically investigated using GRACE accelerometer observations and the OMNI data of solar wind and IMF for 35 great storms during 2002–2006. It reveals the following: (1) The...