Vacuum-Referred Binding Energies of Bismuth and Lanthanide Levels in LiTaO₃ Perovskite: Toward Designing Energy Storage Phosphor for Anti-Counterfeiting, X-Ray Imaging, and Mechanoluminescence

Discovering UV-light or X-ray charged afterglow and storage phosphors with high charge carrier storage capacity remains challenging. Herein, a method is proposed by combining vacuum referred binding energy (VRBE) diagram construction and optimization of dopants’ concentration and compound synthesis. The refined chemical shift model, optical...

Thermal quenching of Eu2+ emission in Ca- and Sr-Ga2S4 in relation with VRBE schemes

Structural and optical properties of MGa2S4 (M = Mg, Zn, Ca, Sr, Ba) compounds have been compared, and the vacuum referred binding energy (VRBE) schemes were constructed for the lanthanide ions in the iso-structural compounds CaGa2S4 and SrGa2S4 employing literature data. The VRBE of an electron in the 5d excited state of Eu2+ was found at 0.75...