Fabrication of graphene oxide-modified self-healing microcapsules for Cardanol-based epoxy anti-corrosion coatings

In this paper, graphene oxide (GO) modified microcapsules have been developed for use in self-healing Cardanol-based epoxy anti-corrosion coatings on steel substrates. The microcapsules had a polymethyl methacrylate (PMMA) shell, covered with aminated GO flakes and contained either of the two complementary healing agents mixed with nanosized...

Small concentrations of NaCl help building stable inhibiting layers from 2,5-dimercapto-1,3,4-thiadiazole (DMTD) on AA2024-T3

The interaction of 2,5-dimercapto-1,3,4-thiadiazole (DMTD) with the AA2024-T3 local microstructure (S-phase, secondary phases and matrix) as function of the NaCl concentration is studied. The inhibiting power and the local interaction of DMTD with the metal were studied by in–situ opto-electrochemistry, XPS and Raman spectroscopy. The...

The compartmented alginate fibres optimisation for bitumen rejuvenator encapsulation

This article presents development of a novel self-healing technology for asphalt pavements, where asphalt binder rejuvenator is encapsulated within the compartmented alginate fibres. The key objective of the study was to optimise the compartmented alginate fibre design, i.e., maximising amount of rejuvenator encapsulated within the fibre. The...

Non-destructive monitoring of delamination healing of a CFRP composite with a thermoplastic ionomer interlayer

A comparative study is performed on the monitoring of delamination healing in CFRP-ionomer sandwich composites by non-destructive techniques and destructive compression testing. Artificial delaminations of various areal dimensions and nature were introduced during production of the composites. The extent of the delamination and the healing...

Effect of the polymer structure on the viscoelastic and interfacial healing behaviour of poly(urea-urethane) networks containing aromatic disulphides

The macroscopic interfacial healing behaviour in a series of urea-urethane networks as function of the hydrogen bonds and disulphides content is presented. The polymers were prepared with different crosslinking densities but with the same amount of dynamic covalent bonds (disulphide linkages). Tensile and fracture measurements were adopted to...

Healing of a glass fibre reinforced composite with a disulphide containing organic-inorganic epoxy matrix

We report the development of an intrinsic healing glass fibre reinforced polymer (GFRP) composite based on a disulphide-containing organic-inorganic thermoset matrix. Thermomechanical experiments showed that the newly developed matrix has a combination of a Young's modulus value in the range of (800–1200 MPa), the ability to multiple...

Superabsorbent polymer additives for repeated barrier restoration of damaged powder coatings under wet-dry cycles: A proof-of-concept

Superabsorbent polymers (SAPs) are well known for their ability to absorb and hold high water amounts accompanied by a high volume expansion. In this work we show the benefits of this underlying property of SAPs to induce underwater crack closure with subsequent barrier restoration in damaged protective coatings. For the proof of concept,...