The effect of processing parameters on the formation of epoxy/UF resin microcapsules

Epoxy E-51/UF resin microcapsules were prepared by traditional two-stepped in situ polymerization method and processing parameters affecting the final microcapsules’ shape and size were carefully studied in the aim to obtain microcapsule with ideally spherical shape and uniform size. It’s found the polycarboxylate surfactant of SMA (styrene...

Preparation of mono-sized epoxy/MF microcapsulesin the appearance of polyvinyl alcohol as co-emulsifier

For epoxy microcapsules embedded in concrete as mechanic-triggered self-healing adhesive, globular shape with uniform size is the basic requirement to ensure the solid shell broken and the liquid core released at a designed stress. In this paper, monodispersed melamine–formaldehyde (MF) resin-walled epoxy E-51 microcapsules were successfully...

Preparation and characterization of poly (urea-formaldehyde) walled dicyclopentadiene microcapsules

Poly (urea-formaldehyde) (PUF) shelled dicyclopentadiene (DCPD) microcapsules were prepared by in-situ polymerization technology for self-healing concrete applications. It’s found, during the process, sodium dodecyl benzene sulfonate (SDBS) behaves better in emulsification of DCPD than other surfactant of sodium lauryl sulfate (SLS) and styrene...

Preparation and characterization of poly (urea-formaldehyde) walled dicyclopentadiene microcapsules

Poly (urea-formaldehyde) (PUF) shelled dicyclopentadiene (DCPD) microcapsules were prepared by in-situ polymerization technology for self-healing concrete applications. It’s found, during the process, sodium dodecyl benzene sulfonate (SDBS) behaves better in emulsification of DCPD than other surfactant of sodium lauryl sulfate (SLS) and styrene...

Self-encapsulation of epoxy resin by a controlled interface curing process in epoxy/water emulsion

The microcapsules of epoxy E-51 resin encapsulated by cured itself were prepared by interfacial curing reaction, in which ethylenediamine (EDA) was employed as curing agent and sulfonated copolymer of styrene and maleic anhydride (SMA) as emulsifying agent. It’s found the morphology of microcapsules strongly depend on reaction time and EDA...

A novel capsule-based selfrecovery system with a chloride ion trigger

Steel is prone to corrosion induced by chloride ions, which is a serious threat to reinforced concrete structures, especially in marine environments. In this work, we report a novel capsule-based selfrecovery system that utilizes chloride ions as a trigger. These capsules, which are functionalized via a smart response to chloride ions, are...

SlimML: Removing Non- critical Input Data in Large-scale Iterative Machine Learning

The core of many large-scale machine learning (ML) applications, such as neural networks (NN), support vector machine (SVM), and convolutional neural network (CNN), is the training algorithm that iteratively updates model parameters by processing massive datasets. From a plethora of studies aiming at accelerating ML, being data...

Highly dispersed Cd cluster supported on TiO2 as an efficient catalyst for CO2 hydrogenation to methanol

The conversion of CO2 with high activity and high selectivity to methanol remains challenging because of both the kinetics and thermodynamics difficulties associated with the chemical reactivity of CO2. Herein, we report a new catalyst of Cd/TiO2 enabling 81% methanol selectivity at 15.8% CO2 conversion with the CH4 selectivity below 0.7%. The...

Surface Redox Pseudocapacitance of Partially Oxidized Titanium Carbide MXene in Water-in-Salt Electrolyte

Achieving pseudocapacitive intercalation in MXenes with neutral aqueous electrolytes and driving reversible redox reactions is scientifically appealing and practically useful. Here, we report that the partial oxidation of MXene intensifies pseudocapacitive Li+ intercalation into Ti3C2Tx MXene from neutral water-in-salt electrolytes. An in...