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Ocadiz flores, J.A. (author), Capelli, E. (author), Raison, P. E. (author), Konings, R. (author), Smith, A.L. (author)Using the modified quasi-chemical model in the quadruplet approximation, three new thermodynamic assessments of binary systems useful for the detailed operational design of the Molten Salt Reactor are presented: AF-NiF<sub>2</sub> (A = Li, Na, K). These systems are particularly relevant for the study of the molten salt-structural materials...journal article 2018
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Smith, A.L. (author), Martin, Philippe M. (author), Prieur, Damien (author), Scheinost, Andreas C. (author), Raison, Philippe E. (author), Cheetham, Anthony K. (author), Konings, R. (author)The charge distributions in α-Na<sub>2</sub>UO<sub>4</sub>, Na<sub>3</sub>NpO<sub>4</sub>, α-Na<sub>2</sub>NpO<sub>4</sub>, Na<sub>4</sub>NpO<sub>5</sub>, Na<sub>5</sub>NpO<sub>6</sub>, Na<sub>2</sub>PuO<sub>3</sub>, Na<sub>4</sub>PuO<sub>5</sub>, and Na<sub>5</sub>PuO<sub>6</sub> are investigated in this work using X-ray absorption near-edge...journal article 2016
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Smith, A.L. (author), Hen, Amir (author), Magnani, Nicola (author), Sanchez, Jean Pierre (author), Colineau, Eric (author), Griveau, Jean Christophe (author), Raison, Philippe E. (author), Caciuffo, Roberto (author), Konings, R. (author), Cheetham, Anthony K. (author)The physical and chemical properties at low temperatures of hexavalent disodium neptunate α-Na<sub>2</sub>NpO<sub>4</sub> are investigated for the first time in this work using Mössbauer spectroscopy, magnetization, magnetic susceptibility, and heat capacity measurements. The Np(VI) valence state is confirmed by the isomer shift value of the...journal article 2016