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Gorczak, N. (author), Renaud, N. (author), Galan, E. (author), Eelkema, R. (author), Siebbeles, L.D.A. (author), Grozema, F.C. (author)Quantum interference is a well-known phenomenon that dictates charge transport properties of single molecule junctions. However, reports on quantum interference in donor-bridge-acceptor molecules are scarce. This might be due to the difficulties in meeting the conditions for the presence of quantum interference in a donor-bridge-acceptor system....journal article 2016
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Gorczak, N. (author), Renaud, N. (author), Tarkuç, S. (author), Houtepen, A.J. (author), Eelkema, R. (author), Siebbeles, L.D.A. (author), Grozema, F.A. (author)Destructive quantum interference has been shown to strongly reduce charge tunneling rates across molecular bridges. The current consensus is that destructive quantum interference occurs in cross-conjugated molecules, while linearly conjugated molecules exhibit constructive interference. Our experimental results on photoinduced charge transfer in...journal article 2015
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Günba?, D.D. (author), Xue, C. (author), Patwardhan, S. (author), Fravventura, M.C. (author), Zhang, H. (author), Jager, W.F. (author), Sudhölter, E.J.R. (author), Laurens, D.A. (author), Siebbeles, L.D.A. (author), Savenije, T.J. (author), Jin, S. (author), Grozema, F.C. (author)In this communication we report on the synthesis and charge mobility of highly soluble perylenebisimid derivatives.We show that introduction of alkylester side chains results in compounds combining a high solubility with charge mobilities up to 0.22 cm2 V_1 s_1. These materials are therefore interesting as an electron acceptor for solution...journal article 2014
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Petrus, M.L. (author), Bouwer, R.K.M. (author), Lafont, U. (author), Murthy, D.H.K. (author), Kist, R.J.P. (author), Böhm, M.L. (author), Olivier, Y. (author), Savenije, T.J. (author), Siebbeles, L.D.A. (author), Greenham, N.C. (author), Dingemans, T.J. (author)Three conjugated triphenylamine-based poly(azomethine)s were prepared via well-known polycondensation chemistry using cheap and readily available starting materials and the results were contrasted with rrP3HT. Three functionalized diaminetriphenylamines (TPA(X), X ¼ –H, –OMe, –CN) were polymerized in a simple one-step process with 2,3...journal article 2013