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Zhang, F. (author), Wu, Z. (author), Wang, Jianlin (author), Wu, Zhenduo (author), Zhao, C. (author), Eijt, S.W.H. (author), Schut, H. (author), van Dijk, N.H. (author), Brück, E.H. (author)Recently, the all-d-metal Ni(Co)MnTi based Heusler compounds are found to have a giant magnetocaloric effect (GMCE) near room temperature and manifest different functionalities like multicaloric effects, which can be employed for solid-state refrigeration. However, in comparison to other traditional Heusler compounds, the relatively large...journal article 2024
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Lai, J. (author), Huang, B. (author), You, X. (author), Maschek, M. (author), Zhou, Guofu (author), van Dijk, N.H. (author), Brück, E.H. (author)The Fe<sub>2</sub>P type Mn–Fe–P–Si alloys exhibit a giant magneto-elastic first-order transition, but the large hysteresis limits their performance. Crystal structure evolution and magnetocaloric performance were investigated by varying the Mn and Fe contents at a constant V substitution of 0.02 in Fe<sub>2</sub>P-type (Mn<sub>1.17-x</sub>Fe...journal article 2024
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Ojiyed, Hamutu (author), van den Berg, Maarten (author), Batashev, I. (author), Shen, Q. (author), van Dijk, N.H. (author), Brück, E.H. (author)The magnetocaloric properties of Mn<sub>5</sub>Si<sub>1-x</sub>P<sub>x</sub>B<sub>2</sub> (0 ≤ x ≤ 1) compounds were studied for energy harvesting applications. The crystal structure and the magnetic structure were characterized by powder X-Ray Diffraction and powder Neutron Diffraction. The results indicate that these magnetocaloric...journal article 2024
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Belloni, C. (author), Korving, L. (author), Witkamp, G.J. (author), Brück, E.H. (author), Dugulan, A.I. (author)Iron oxide-based adsorbents showed potential to reach ultra-low phosphorus (P) concentrations to prevent eutrophication and recover P. High affinity, high capacity at low P concentrations (<1 mg L<sup>−1</sup>), good stability, and reusability of the adsorbent are key factors for economic viability. In this study, nanoparticles of goethite...journal article 2024
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Gai, H. (author), van Dijk, N.H. (author), Brück, E.H. (author)The transition-metal based alloy system YNi <sub>4-x</sub>Co <sub>x</sub>Si shows a second-order ferromagnetic-to-paramagnetic transition near room temperature. Here, the magnetic structure, the magnetocaloric properties and the magnetic anisotropy of YNi <sub>4-x</sub>Co <sub>x</sub>Si (x = 0–4) are investigated. For x = 3.5, 3.75 and 4.0 a...journal article 2024
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Zhang, F. (author), Miao, Xuefei (author), van Dijk, N.H. (author), Brück, E.H. (author), Ren, Yang (author)Solid-state caloric effects as intrinsic thermal responses to different physical external stimuli (magnetic-, uniaxial stress-, pressure-, and electric-fields) can achieve a higher energy efficiency compared with traditional gas compression techniques. Among these effects, magnetocaloric energy conversion is regarded as the best available...review 2024
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Wu, Z. (author), De Wit, Lidwin (author), Beek, Melanie (author), Colombi, G. (author), Chaykina, D. (author), Schreuders, H. (author), Schut, H. (author), Butterling, Maik (author), Brück, E.H. (author), Dam, B. (author), Eijt, S.W.H. (author)Cycling stability of the photochromic effect in rare-earth oxyhydride thin films is of great importance for long-term applications such as smart windows. However, an increasingly slower bleaching rate upon photochromic cycling was found in yttrium oxyhydride thin films; the origin of this memory effect is yet unclear. In this work, the...journal article 2024
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Zhang, F. (author), Smits, Sebastian (author), Kiecana, A. (author), Batashev, I. (author), Shen, Q. (author), van Dijk, N.H. (author), Brück, E.H. (author)The influence of doping with the 5d transition metal W has been studied in the quaternary (Mn,Fe)<sub>2</sub>(P,Si) based giant magnetocaloric compounds, which is one of the most promising systems for magnetic refrigeration. It is found that W substitution can separately decrease the Curie temperature T<sub>C</sub> and retain the thermal...journal article 2023
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Shen, Q. (author), Zhang, F. (author), Dugulan, A.I. (author), van Dijk, N.H. (author), Brück, E.H. (author)In this work, the magnetocaloric effect and negative thermal expansion in melt-spun Fe<sub>2</sub>Hf<sub>0.83</sub>Ta<sub>0.17</sub> Laves phase alloys were studied. Compared to arc-melted alloys, which undergo a first-order magnetoelastic transition from the ferromagnetic to the antiferromagnetic phase, melt-spun alloys exhibit a second...journal article 2023
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Kiecana, A. (author), Schaefers, W. (author), Thijs, M. (author), Dankelman, B.J.R. (author), Ojiyed, H. (author), Batashev, I. (author), Zhang, F. (author), van Dijk, N.H. (author), Brück, E.H. (author)Structural, magnetic and magnetocaloric properties of Mn<sub>3</sub>Sn<sub>1-</sub><sub>x</sub>Zn<sub>x</sub>C antiperovskite carbides have been studied. With increasing Zn content the first-order magnetic transition (FOMT) is weakened. The Curie temperature (T<sub>C</sub>) reduces first from 273 to 197 K and when x > 0.3, T<sub>C</sub>...journal article 2023
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Pineda Quijano, D.F. (author), Infante Ferreira, C.A. (author), Brück, E.H. (author)The development of affordable magnetocaloric materials (MCM) with a giant magnetocaloric effect (MCE) has brought magnetocaloric heat pumps a step closer to commercialization. The narrow temperature range in which these materials exhibit a large MCE demands the use of several materials with Curie temperatures covering the temperature span of...journal article 2023
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Zhang, F. (author), Bykov, Eduard (author), Gottschall, Tino (author), van Dijk, N.H. (author), Brück, E.H. (author)The orthorhombic MnCoSi compounds have been found to present a large magnetoelastic coupling, which is regarded as the source for the magnetocaloric effect (MCE) and the magnetostrictive effect. As a result, these compounds are potential materials for caloric applications such as solid-state refrigeration. In the present study, we offer...journal article 2023
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Belloni, C. (author), Korving, L. (author), Witkamp, G.J. (author), Brück, E.H. (author), Dugulan, A.I. (author)Phosphorus (P) removal from freshwater bodies to ultra-low concentrations is fundamental to prevent eutrophication, while its recovery is necessary to close the P usage cycle. Iron oxide-based adsorbents seem promising candidates, being abundant, cheap, and easy to synthesize compounds, with good affinity for P. Affinity is the key parameter...journal article 2023
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Belloni, C. (author), Korving, L. (author), Witkamp, G. J. (author), Brück, E.H. (author), de Jager, P. (author), Dugulan, A.I. (author)Hybrid anion exchange adsorbents (HAIX) seem promising to prevent eutrophication and recover phosphate (P). HAIX consist of an anion exchange resin (AIX) backbone, promoting anion physisorption (outer-sphere complex), impregnated with iron (hydr)oxide nanoparticles (NPs), for selective P chemisorption (inner-sphere complex). In this work, for...journal article 2023
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Shen, Q. (author), Batashev, I. (author), Zhang, F. (author), Ojiyed, Hamutu (author), Dugulan, A.I. (author), van Dijk, N.H. (author), Brück, E.H. (author)The transition-metal based Laves phase materials represent an extended family of alloys with rich and fascinating physical properties. In this work, we have investigated the negative thermal expansion and magnetocaloric effect in arc-melted and melt-spun Fe<sub>2</sub>Hf<sub>1-</sub><sub>x</sub>Ti<sub>x</sub> (x = 0.15, 0.27, 0.30, 0.33, 0.36...journal article 2023
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Kiecana, A. (author), Kwakernaak, C. (author), van Dijk, N.H. (author), Brück, E.H. (author)The effect of the heat treatment on the magnetism, magnetocaloric effect and microstructure formation has been systematically studied in Fe-rich (Mn,Fe)<sub>y</sub>(P,Si) melt-spun ribbons (1.80 ≤ y ≤ 2.00). XRD, SEM and EDS measurements demonstrate that a metal deficiency prompts the stable (Mn,Fe)Si phase, whereas in the metal-rich region...journal article 2023
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Zhang, F. (author), Batashev, I. (author), van Dijk, N.H. (author), Brück, E.H. (author)The influence of off-stoichiometry and of doping with the 5d transition metal Ta has been studied in the quaternary (Mn,Fe)<sub>2</sub>(P,Si)-based compound, which is one of the most promising materials systems for magnetic refrigeration. It is found that Ta substitution can decrease the transition temperature T<sub>tr</sub>, while the...journal article 2023
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Wu, Z. (author), De Krom, Tom (author), Colombi, G. (author), Chaykina, D. (author), Van Hattem, Gijs (author), Schut, H. (author), Dickmann, Marcel (author), Brück, E.H. (author), Dam, B. (author), Eijt, S.W.H. (author)Rare-earth (RE) oxyhydride thin films show a color-neutral, reversible photochromic effect at ambient conditions. The origin of the photochromism is the topic of current investigations. Here, we investigated the lattice defects, electronic structure, and crystal structure of photochromic YHxOy and GdHxOy thin films deposited by magnetron...journal article 2022
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Zhang, F. (author), Taake, Chris (author), Huang, B. (author), You, X. (author), Ojiyed, Hamutu (author), Shen, Q. (author), Dugulan, A.I. (author), Caron, Luana (author), van Dijk, N.H. (author), Brück, E.H. (author)In the field of nanoscale magnetocaloric materials, novel concepts like micro-refrigerators, thermal switches, microfluidic pumps, energy harvesting devices and biomedical applications have been proposed. However, reports on nanoscale (Mn,Fe)<sub>2</sub>(P,Si)-based materials, which are one of the most promising bulk materials for solid-state...journal article 2022
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Bao, L. L. (author), Yibole, H. (author), Xu, J. (author), Ou, Z. Q. (author), Haschuluu, O. (author), Tegus, O. (author), van Dijk, N.H. (author), Brück, E.H. (author), Guillou, F. (author)In view of the interest that (Fe,Co)<sub>2</sub>(P,Si) compounds have as potential permanent magnets, their structural and magnetic phase diagrams are explored focusing on establishing the range where the hexagonal Fe<sub>2</sub>P-type structure is observed. In Fe<sub>1.93-x</sub>Co<sub>x</sub>P<sub>1-y</sub>Si<sub>y</sub>, the highest Si...journal article 2022