Synergistic Toughening of Epoxy through Layered Poly(ether imide) with Dual-Scale Morphologies

Toughness of epoxies is commonly improved by adding thermoplastic phases, which is achieved through dissolution and phase separation at the microscale. However, little is known about the synergistic effects of toughening phases on multiple scales. Therefore, here, we study the toughening of epoxies with layered poly(ether imide) (PEI) structures...

Debonding-on-demand Fe₃O₄-epoxy adhesively bonded dissimilar joints via electromagnetic induction heating

We investigated the debonding on-demand (DoD) of adhesively bonded hybrid dissimilar joints by applying electromagnetic induction heating to the joint overlap section, wherein the epoxy resin is reinforced with iron oxide (Fe₃O₄) particles. Ti-6Al-4 V adherends were bonded with CFRP or GFRP adherends using neat/modified...

Effect of a Dwell Stage in the Cure Cycle on the Interphase Formation in a Poly(ether imide)/High T_gEpoxy System

Epoxies are inherently brittle materials and to overcome this brittleness, a second microphase (i.e., thermoplastic) is typically added. This modification of epoxy resin using thermoplastics results in reaction-induced phase separating morphologies in the micrometer range. In this study, the influence of the curing history, beyond phase...

Oxidative aging of epoxy asphalt

Oxidative aging is responsible for the irreversible asphalt stiffening and embrittlement leading to asphalt pavements of increased susceptibility to fatigue and thermal cracking. In recent years, various flexible binders have been introduced in asphalt industry to produce long-life pavements and the epoxy asphalt binders are among them....

Adhesive bonding and corrosion performance investigated as a function of auminum oide chemistry and adhesives

The long-term strength and durability of an adhesive bond is dependent on the stability of the oxide-adhesive interface. As such, changes in the chemistry of the oxide and/or the adhesive are expected to modify the interfacial properties and affect the joint performance in practice. The upcoming transition to Cr(VI)-free surface pretreatments...

On the nonlinear thermomechanical behavior and delamination of conductive adhesives

Adhesives based on thermoset polymers are used as thermal and electrical interfaces. These adhesives are filled with different particles in order to meet the requirements of heat transfer and electrical properties. Due to the reliability requirements of automotive applications, they are required to have excellent bulk and interface properties....

Preparation of mono-sized epoxy/MF microcapsulesin the appearance of polyvinyl alcohol as co-emulsifier

For epoxy microcapsules embedded in concrete as mechanic-triggered self-healing adhesive, globular shape with uniform size is the basic requirement to ensure the solid shell broken and the liquid core released at a designed stress. In this paper, monodispersed melamine–formaldehyde (MF) resin-walled epoxy E-51 microcapsules were successfully...

Capsule-based self-healing epoxy systems using Diels-Alder reactions

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Thiol-maleimide chemistry for autonomous self-healing of epoxy resins

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Thiol-isocyanate chemistry for autonomous self-healing of epoxy resins

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Self-encapsulation of epoxy resin by a controlled interface curing process in epoxy/water emulsion

The microcapsules of epoxy E-51 resin encapsulated by cured itself were prepared by interfacial curing reaction, in which ethylenediamine (EDA) was employed as curing agent and sulfonated copolymer of styrene and maleic anhydride (SMA) as emulsifying agent. It’s found the morphology of microcapsules strongly depend on reaction time and EDA...

Encapsulation of an amine using microfluidics

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Polymer composite layer with damage indication ability

Bio-inspired “bruisable” polymer composite layer is the solution in structural health monitoring processes which will allow minimise time of inspection and simplify the process of monitoring. The aim of the study was to develop polymer composite layer with damage indication ability. Visualization of damaged place is provided by colour changing...

Self-healing chemistries for epoxy resins: Has the limit been reached?

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Thermal conductivity of microPCMs-filled epoxy matrix composites

Microencapsulated phase change materials (microPCMs) have been widely applied in solid matrix as thermal-storage or temperature-controlling functional composites. The thermal conductivity of these microPCMs/matrix composites is an important property need to be considered. In this study, a series of microPCMs have been fabricated using the in...

Mechanical characterization and modeling of curing thermosets

Chemical shrinkage and simultaneous build-up of mechanical properties in curing thermosets leads to the build-up of residual stresses and strains. Depending on the constraints these may cause interface failure, dimensional inaccuracy or failure in the thermoset or its surrounding structure. The present work aims at both an improved methodology...