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Kalikadien, A.V. (author), Mirza, Adrian (author), Hossaini, Aydin Najl (author), Sreenithya, Avadakkam (author), Pidko, E.A. (author)In the past decade, computational tools have become integral to catalyst design. They continue to offer significant support to experimental organic synthesis and catalysis researchers aiming for optimal reaction outcomes. More recently, data-driven approaches utilizing machine learning have garnered considerable attention for their expansive...journal article 2024
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van Putten, R. (author), Uslamin, E. (author), Pidko, E.A. (author)This invention describes an apparatus that enables the automated removal of small samples from fluids such as those encountered in (bio-)chemical reactors. These samples can then be used for, e.g., kinetic analysis and quality control applications. The system was explicitly designed to be compatible with harsh and aggressive reaction conditions...journal article 2021
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Bunea, S. (author), Clemens, Kevin (author), Urakawa, A. (author)The application of a polymer electrolyte membrane (PEM) electrolytic cell for continuous conversion of nitrate, one of the contaminants in water, to ammonia at the cathode was explored in the present work. Among carbon-supported metal (Cu, Ru, Rh and Pd) electrocatalysts, the Ru-based catalyst showed the best performance. By suppressing the...journal article 2021
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Breve, T. (author), Filius, M. (author), Araman, Can (author), van der Helm, M. (author), Hagedoorn, P.L. (author), Joo, C. (author), van Kasteren, Sander I. (author), Eelkema, R. (author)Supramolecular encapsulation is known to alter chemical properties of guest molecules. We have applied this strategy of molecular encapsulation to temporally control the catalytic activity of a stable copper(I)–carbene catalyst. Encapsulation of the copper(I)–carbene catalyst by the supramolecular host cucurbit[7]uril (CB[7]) resulted in the...journal article 2020
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Puspitasari, I. (author)The objectives of this PhD project are to address the challenges of in-situ TEM and introduce a new generation of in-situ TEM equipment. In Chapter 2 the in-situ TEM facilities are introduced, focusing on the nanoreactor that has gone through quite some development stages during this project. Several types of in-situ TEM nanoreactors were...doctoral thesis 2016
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Standing, A. (author), Assali, S. (author), Gao, L. (author), Verheijen, M.A. (author), Van Dam, D. (author), Cui, Y. (author), Notten, P.H.L. (author), Haverkort, J.E.M. (author), Bakkers, E.P.A.M. (author)Photoelectrochemical hydrogen production from solar energy and water offers a clean and sustainable fuel option for the future. Planar III/V material systems have shown the highest efficiencies, but are expensive. By moving to the nanowire regime the demand on material quantity is reduced, and new materials can be uncovered, such as wurtzite...journal article 2015
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Van Ommen, J.R. (author), Kooijman, D. (author), De Niet, M. (author), Talebi, M. (author), Goulas, A. (author)In this paper, the authors demonstrate a novel spatial atomic layer deposition (ALD) process based on pneumatic transport of nanoparticle agglomerates. Nanoclusters of platinum (Pt) of ?1?nm diameter are deposited onto titania (TiO2) P25 nanoparticles resulting to a continuous production of an active photocatalyst (0.12–0.31?wt. % of Pt) at a...journal article 2015
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Ng, N.H.Y. (author), Mančinska, L. (author), Cirstoiu, C. (author), Eisert, J. (author), Wehner, S.D.C. (author)Quantum thermodynamics is a research field that aims at fleshing out the ultimate limits of thermodynamic processes in the deep quantum regime. A complete picture of thermodynamical processes naturally allows for auxiliary systems dubbed 'catalysts', i.e., any physical systems facilitating state transformations while remaining essentially...journal article 2015
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Damsgaard, C.D. (author), Zandbergen, H.W. (author), Hansen, T.W. (author), Chorkendorff, I. (author), Wagner, J.B. (author)Specimen transfer under controlled environment conditions, such as temperature, pressure, and gas composition, is necessary to conduct successive complementary in situ characterization of materials sensitive to ambient conditions. The in situ transfer concept is introduced by linking an environmental transmission electron microscope to an in...journal article 2014
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Skupien, E. (author), Berger, R.J. (author), Santos, V.P. (author), Gascon, J. (author), Makkee, M. (author), Kreutzer, M.T. (author), Kooyman, P.J. (author), Moulijn, J.A. (author), Kapteijn, F. (author)Benzyl alcohol oxidation was carried out in toluene as solvent, in the presence of the potentially inhibiting oxidation products benzaldehyde and benzoic acid. Benzoic acid, or a product of benzoic acid, is identified to be the inhibiting species. The presence of a basic potassium salt (K2CO3 or KF) suppresses this inhibition, but promotes the...journal article 2014
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Everitt, D.T. (author), Coope, T.S. (author), Bond, I.P. (author), Trask, R.S. (author), Wass, D.F. (author)Self-healing polymers typically feature monomer and catalyst either dispersed within a host matrix, or encapsulated within hollow vessels. Unprotected highly active catalysts, sensitive to air and moisture, can readily react with amine cross-linking agents during the cure of reactive prepolymers e.g. epoxy resins. Therefore, catalysts stable to...conference paper 2013
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Durka, T. (author)Due to the quest for more efficient production processes both from the energy and selectivity point of view, microwave irradiation has attracted significant scientific attention over the last three decades, as an alternative means of chemical activation. Over this period, striking process benefits, such as higher conversions and selectivities...doctoral thesis 2013
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Nederlof, C. (author)This research work on the catalytic dehydrogenation of ethylbenzene (EB) to styrene (ST) had a primary goal of developing improved catalysts for dehydrogenation processes both in CO2 as well as with O2 that can compete with the conventional dehydrogenation process in steam. In order to achieve this goal, all these processes need to be properly...doctoral thesis 2012
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Tromp, S.A. (author)This work discusses the use of ATR-FTIR in catalysis. Besides development and critical analysis of the method, several catalytic systems have been studied.doctoral thesis 2011
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Yáng, Z. (author), Harvey, A.S. (author), Infortuna, A. (author), Schoonman, J. (author), Gauckler, L.J. (author)Bulk BaxSr1 - xCoyFe1 - yO3 - dBaxSr1?xCoyFe1?yO3? compositions (BSCF) were synthesized by the solid-state reaction method. The electrical conductivity of ceramic bars was measured using a dc four-probe method as a function of temperature in air up to 970 °C. All compositions showed thermally activated p-type semi-conductivity up to ~450 °C and...journal article 2010
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Van Paassen, L.A. (author)Biogrout is a new ground improvement method based on microbially induced precipitation of calcium carbonate (MICP). When supplied with suitable substrates, micro-organisms can catalyze biochemical conversions in the subsurface resulting in precipitation of inorganic minerals, which change the mechanical soil properties. This study focuses on one...doctoral thesis 2009
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Pereira, S.R.M. (author)The main topic of this thesis is the investigation of the synergies between High-Throughput Experimentation (HTE) and Chemometric Optimization methodologies in Catalysis research and of the use of such methodologies to maximize the advantages of using HTE methods. Several case studies were analysed including: 1) the exploration of a terpene...doctoral thesis 2008
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- Wang, J. (author) doctoral thesis 2008
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De Wael, K. (author), Buschop, H. (author), Heering, H.A. (author), De Smet, L. (author), Van Beeumen, J. (author), Devreese, B. (author), Adriaens, A. (author)We describe the redox behaviour of horse heart cytochrome c (HHC) and Rhodobacter capsulatus cytochrome c peroxidase (RcCCP) at a gold electrode modified with 4,4?-bipyridyl. RcCCP shows no additional oxidation or reduction peaks compared to the electrochemistry of only HHC, which indicates that it most likely binds to HHC and results in a...journal article 2007
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Groen, J.C. (author)Zeolites are crystalline microporous materials consisting of silicon, aluminium and oxygen atoms. A unique combination of properties such as high surface area, high (hydro)thermal stability, and strong acidity, makes that zeolites are frequently used as catalysts in various (petro)chemical processes. The pores of molecular dimensions are...doctoral thesis 2007
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