Erratum: Silica-Supported PdGa Nanoparticles: Metal Synergy for Highly Active and Selective CO₂-to-CH₃OH Hydrogenation (JACS Au (2021) 1:4 (450−458) DOI: 10.1021/jacsau.1c00021)

On page 452, column 1 (lines 12?23) reads: H2 and CO chemisorption show an uptake of 0.91 molH2 molPd?1 and 0.61 molCO molPd ?1, respectively (Table 1, Supporting Information S6). Considering a 1:1 CO/Pd stoichiometry,32 the dispersion from CO chemisorption (D?CO) equals 61%, in a reasonable agreement with the dispersion from TEM (D?TEM 70%;...

Silica-Supported PdGa Nanoparticles: Metal Synergy for Highly Active and Selective CO₂-to-CH₃OH Hydrogenation

The direct conversion of CO₂to CH₃OH represents an appealing strategy for the mitigation of anthropogenic CO₂emissions. Here, we report that small, narrowly distributed alloyed PdGa nanoparticles, prepared via surface organometallic chemistry from silica-supported Ga^IIIisolated sites, selectively...