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Putra, N.E. (author), Leeflang, M.A. (author), Minneboo, M.B. (author), Taheri, P. (author), Fratila-Apachitei, E.L. (author), Mol, J.M.C. (author), Zhou, J. (author), Zadpoor, A.A. (author)Extrusion-based 3D printing followed by debinding and sintering is a powerful approach that allows for the fabrication of porous scaffolds from materials (or material combinations) that are otherwise very challenging to process using other additive manufacturing techniques. Iron is one of the materials that have been recently shown to be...journal article 2021
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Kokalj, Anton (author), Lozinšek, Matic (author), Kapun, Barbara (author), Taheri, P. (author), Neupane, Shova (author), Losada-Pérez, Patricia (author), Xie, Chenyang (author), Stavber, Stojan (author), Crespo, Daniel (author), Renner, Frank U. (author), Mol, J.M.C. (author), Milošev, Ingrid (author)The often used simplistic correlations between molecular electronic parameters and experimentally determined corrosion inhibition efficiencies are critically evaluated for a set of 24 heterocyclic organic compounds, tested as corrosion inhibitors for copper in 3 wt.% NaCl aqueous solution. Twelve different molecular electronic descriptors...journal article 2021
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Dong, J. (author), Tümer, N. (author), Leeflang, M.A. (author), Taheri, P. (author), Fratila-Apachitei, E.L. (author), Mol, J.M.C. (author), Zadpoor, A.A. (author), Zhou, J. (author)Porous biodegradable Mg and its alloys are considered to have a great potential to serve as ideal bone substitutes. The recent progress in additive manufacturing (AM) has prompted its application to fabricate Mg scaffolds with geometrically ordered porous structures. Extrusion-based AM, followed by debinding and sintering, has been recently...journal article 2022
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Taheri, P. (author), Milošev, Ingrid (author), Meeusen, M. (author), Kapun, Barbara (author), White, Paul (author), Kokalj, Anton (author), Mol, J.M.C. (author)Efficiency of corrosion inhibitors in aqueous solutions depends on several interfacial parameters, which may vary over time. Therefore, reliable electrochemical techniques are demanded for screening the efficiency of corrosion inhibitors and monitoring their performance over time. Here, we evaluate corrosion inhibition efficiency of imidazole...journal article 2020
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Putra, N.E. (author), Tigrine, A. (author), Aksakal, S. (author), de la Rosa, V. R. (author), Taheri, P. (author), Fratila-Apachitei, E.L. (author), Mol, J.M.C. (author), Zhou, J. (author), Zadpoor, A.A. (author)Additively manufacturing of porous iron offers a unique opportunity to increase its biodegradation rate by taking advantage of arbitrarily complex porous structures. Nevertheless, achieving the required biodegradation profile remains challenging due to the natural passivation of iron that decrease the biodegradation rate. Moreover, the...journal article 2022
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Huang, Luyao (author), Chang, Weiwei (author), Zhang, Dawei (author), Huang, Ye (author), Li, Z. (author), Lou, Yuntian (author), Qian, Hongchang (author), Jiang, Chengying (author), Li, Xiaogang (author), Mol, J.M.C. (author)The influence of outward extracellular electron transfer (EET) of Pseudomonas aeruginosa in accelerating corrosion of 304 stainless steel was investigated. With less NO<sub>3</sub><sup>−</sup> available as electron acceptor, P. aeruginosa biofilm accelerated the pitting corrosion. The ICP-MS and XPS results indicated that P. aeruginosa...journal article 2022
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Kosari, A. (author), Tichelaar, F.D. (author), Visser, P. (author), Taheri, P. (author), Zandbergen, H.W. (author), Terryn, H.A. (author), Mol, J.M.C. (author)Lithium salts have been proposed as promising environmentally friendly alternatives to carcinogenic hexavalent chromium-based inhibitors for the corrosion protection of aerospace aluminium alloys (AAs). Incorporated into organic coatings, lithium salts are released at damaged locations to establish a conversion layer in which distinct...journal article 2021
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Kosari, A. (author), Tichelaar, F.D. (author), Visser, P. (author), Zandbergen, H.W. (author), Terryn, H.A. (author), Mol, J.M.C. (author)Lithium leaching coatings have recently been developed as eco-friendly active corrosion protection technology for aerospace aluminium alloys (AAs) by the formation of a conversion layer at coating defects. While general conversion layer formation characteristics were studied and reported before, here we study the local layer formation process...journal article 2021
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Putra, N.E. (author), Leeflang, M.A. (author), Taheri, P. (author), Fratila-Apachitei, E.L. (author), Mol, J.M.C. (author), Zhou, J. (author), Zadpoor, A.A. (author)Additively manufactured biodegradable porous iron has been only very recently demonstrated. Two major limitations of such a biomaterial are very low biodegradability and incompatibility with magnetic resonance imaging (MRI). Here, we present a novel biomaterial that resolves both of those limitations. We used extrusion-based 3D printing to...journal article 2021
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Chen, Guangmeng (author), Wen, Shifeng (author), Ma, Jiacheng (author), Sun, Zhiyong (author), Lin, Cunguo (author), Yue, Zhufeng (author), Mol, J.M.C. (author), Liu, M. (author)Multifunctional intrinsic self-healing polymers (ISP) are gaining increasing attention these days, and many studies have been devoted to solving the conflict between achieving high mechanical polymer strength and active polymer chain diffusion. In this research, we developed an optimized self-healing composite coating by adding Benzotriazole ...journal article 2021
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Pyurbeeva, Eugenia (author), Hsu, C. (author), Vogel, David (author), Wegeberg, Christina (author), Mayor, Marcel (author), van der Zant, H.S.J. (author), Mol, Jan A. (author), Gehring, P. (author)Single molecules are nanoscale thermodynamic systems with few degrees of freedom. Thus, the knowledge of their entropy can reveal the presence of microscopic electron transfer dynamics that are difficult to observe otherwise. Here, we apply thermocurrent spectroscopy to directly measure the entropy of a single free radical molecule in a...journal article 2021
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Suresh Babu, Diwakar (author), Mol, J.M.C. (author), Buijnsters, J.G. (author)GenX is the trade name of the ammonium salt of hexafluoropropylene oxide dimer acid (HFPO-DA) and is used as a replacement for the banned perfluorooctanoic acid (PFOA). However, recent studies have found GenX to be more toxic than PFOA. This work deals with the electrochemical degradation of HFPO-DA using boron-doped diamond anodes. For the...journal article 2022
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Kosari, A. (author), Zandbergen, H.W. (author), Tichelaar, F.D. (author), Visser, P. (author), Terryn, H.A. (author), Mol, J.M.C. (author)Liquid-phase transmission electron microscopy (LP-TEM) has provided corrosion scientists with a unique opportunity to directly correlate nanoscopic morphological and compositional evolutions to the corresponding electrochemical response of corroding thin TEM specimens. Electrochemical liquid cell designs are key components of a LP-TEM study...journal article 2021
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Zhou, Enze (author), Li, Feng (author), Zhang, Dawei (author), Xu, Dake (author), Li, Zhong (author), Jia, Ru (author), Song, Hao (author), Gu, Tingyue (author), Homborg, A.M. (author), Mol, J.M.C. (author)Shewanella oneidensis MR-1 is an attractive model microbe for elucidating the biofilm-metal interactions that contribute to the billions of dollars in corrosion damage to industrial applications each year. Multiple mechanisms for S. oneidensis-enhanced corrosion have been proposed, but none of these mechanisms have previously been rigorously...journal article 2022
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Willemsen, Koen (author), Magré, Joëll (author), Mol, Jeroen (author), Noordmans, Herke Jan (author), Weinans, Harrie (author), Hekman, Edsko E.G. (author), Kruyt, Moyo C. (author)For decades, the advantages of rapid prototyping for clinical use have been recognized. However, demonstrations of potential solutions to treat spinal problems that cannot be solved otherwise are scarce. In this paper, we describe the development, regulatory process, and clinical application of two types of patient specific 3D-printed devices...journal article 2022
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Li, Z. (author), Homborg, A.M. (author), Gonzalez Garcia, Y. (author), Kosari, A. (author), Visser, Peter (author), Mol, J.M.C. (author)The formation process of a lithium-based conversion layer on AA2024-T3 and its corrosion protective behavior are studied using electrochemical noise (EN). Wavelet transform, as well as noise resistance analysis, have been employed to interpret the EN data. The EN data confirmed five different stages during the conversion layer growth,...journal article 2022
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Chang, Weiwei (author), Li, Yangyang (author), Li, Z. (author), Lou, Yuntian (author), Cui, Tianyu (author), Qian, Hongchang (author), Mol, J.M.C. (author), Zhang, Dawei (author)The microbiologically influenced corrosion of pure iron was investigated in the presence of Shewanella oneidensis MR-1 with various levels of exogenous riboflavin (RF) serving as electron shuttles for extracellular electron transfer (EET). With more RF available, a larger and denser phosphate layer was formed on the surface of pure iron by...journal article 2022
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Mol, Merel O. (author), van der Lee, S.J. (author), Hulsman, M. (author), Pijnenburg, Yolande A.L. (author), Scheltens, Phillip (author), Seelaar, Harro (author), van Swieten, John C. (author), Kaat, Laura Donker (author), Holstege, H. (author), van Rooij, Jeroen G.J. (author)Background: Many families with clinical early-onset Alzheimer’s disease (EOAD) remain genetically unexplained. A combination of genetic factors is not standardly investigated. In addition to monogenic causes, we evaluated the possible polygenic architecture in a large series of families, to assess if genetic testing of familial EOAD could be...journal article 2022
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Dai, Jiaxin (author), Fu, Dongmei (author), Song, Guangxuan (author), Ma, Lingwei (author), Guo, Xin (author), Mol, J.M.C. (author), Cole, Ivan (author), Zhang, Dawei (author)Current experimental verification, computational modeling, and machine learning methods for predicting corrosion inhibition efficiency (IE) are limited to specific inhibitor categories with high cost and poor generalization. In this study, a cross-category corrosion inhibitor dataset is constructed and a three-level direct message passing...journal article 2022
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Liu, M. (author), Zhu, Jia-Ning (author), Popovich, V. (author), Borisov, E. (author), Mol, J.M.C. (author), Gonzalez Garcia, Y. (author)Electrochemical tests and surface analysis measurements were performed to study the corrosion behavior in a 0.9 wt.% NaCl solution at 37 °C of three NiTi shape memory alloys fabricated by laser-powder bed fusion (L-PBF). The passive film characteristics and corrosion resistance of L-PBF NiTi showed different features as a function of their...journal article 2023