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Li, Z. (author), Homborg, A.M. (author), Gonzalez Garcia, Y. (author), Visser, Peter (author), Soleimani, M. (author), Mol, J.M.C. (author)
The influence of ageing under ambient conditions on the corrosion protective behaviour of a lithium-based conversion layer on AA2024-T3 is studied in this work. Conversion layers aged at ambient conditions for relatively short times (0 h and 4 h), show an initial high degree of corrosion inhibition but a much lower protectiveness after the...
journal article 2023
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Homborg, A.M. (author), Mol, J.M.C. (author), Tinga, Tiedo (author)
This paper for the first time treats the interpretation of electrochemical noise time-frequency spectra as an image classification problem. It investigates the application of a convolutional neural network (CNN) for deep learning image classification of electrochemical noise time-frequency transient information. Representative slices of these...
journal article 2024
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Li, Z. (author), Chang, Weiwei (author), Cui, Tianyu (author), Xu, Dake (author), Zhang, Dawei (author), Lou, Yuntian (author), Qian, Hongchang (author), Song, Hao (author), Mol, J.M.C. (author), Cao, Fahe (author), Gu, Tingyue (author), Li, Xiaogang (author)
Microbiologically influenced corrosion of metals is prevalent in both natural and industrial environments, causing enormous structural damage and economic loss. Exactly how microbes influence corrosion remains controversial. Here, we show that the pitting corrosion of stainless steel is accelerated in the presence of Shewanella oneidensis MR...
journal article 2021
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Naddaf Dezfuli, S. (author), Brouwer, J.C. (author), Mol, J.M.C. (author), van der Helm, F.C.T. (author), Zhou, J. (author)
Recent studies have shown great potential of Mg matrix composites for biodegradable orthopedic devices. However, the poor structural integrity of these composites, which results in excessive localized corrosion and premature mechanical failure, has hindered their widespread applications. In this research, an in-situ Powder Metallurgy (PM)...
journal article 2018
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Harzheim, Achim (author), Spiece, Jean (author), Evangeli, Charalambos (author), McCann, Edward (author), Falko, Vladimir (author), Sheng, Yuewen (author), Warner, Jamie H. (author), Briggs, G. Andrew D. (author), Mol, Jan A. (author), Gehring, P. (author), Kolosov, Oleg V. (author)
The influence of nanostructuring and quantum confinement on the thermoelectric properties of materials has been extensively studied. While this has made possible multiple breakthroughs in the achievable figure of merit, classical confinement, and its effect on the local Seebeck coefficient has mostly been neglected, as has the Peltier effect...
journal article 2018
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Imani, Amin (author), Rahimi, E. (author), Lekka, Maria (author), Andreatta, Francesco (author), Magnan, Michele (author), Gonzalez Garcia, Y. (author), Mol, J.M.C. (author), Raman, R. K. Singh (author), Fedrizzi, Lorenzo (author), Asselin, Edouard (author)
Mg and its alloys are promising biodegradable materials for orthopedic implants and cardiovascular stents. The first interactions of protein molecules with Mg alloy surfaces have a substantial impact on their biocompatibility and biodegradation. We investigate the early-stage electrochemical, chemical, morphological, and electrical surface...
journal article 2024
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Dong, J. (author), Tümer, N. (author), Putra, N.E. (author), Zhu, Jia-Ning (author), Li, Y. (author), Leeflang, M.A. (author), Taheri, P. (author), Fratila-Apachitei, E.L. (author), Mol, J.M.C. (author), Zadpoor, A.A. (author), Zhou, J. (author)
Additively manufactured (AM) biodegradable magnesium (Mg) scaffolds with precisely controlled and fully interconnected porous structures offer unprecedented potential as temporary bone substitutes and for bone regeneration in critical-sized bone defects. However, current attempts to apply AM techniques, mainly powder bed fusion AM, for the...
journal article 2021
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Li, Y. (author), Jahr, H. (author), Lietaert, K. (author), Pavanram, P. (author), Yilmaz, A. (author), Fockaert, L.I. (author), Leeflang, M.A. (author), Pouran, B. (author), Gonzalez Garcia, Y. (author), Weinans, Harrie (author), Mol, J.M.C. (author), Zhou, J. (author), Zadpoor, A.A. (author)
Additively manufactured (AM) topologically ordered porous metallic biomaterials with the proper biodegradation profile offer a unique combination of properties ideal for bone regeneration. These include a fully interconnected porous structure, bone-mimicking mechanical properties, and the possibility of fully regenerating bony defects. Most...
journal article 2018
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Visser, P. (author), Terryn, H.A. (author), Mol, J.M.C. (author)
Inhibitor leaching, fast, effective and irreversible passivation are essential for active protective coatings to protect aluminium alloys. This study presents the comparison of the active protective properties of lithium carbonate and two organic corrosion inhibitors, benzotriazole and 2-mercaptobenzothiazole, on aluminium alloy 2024-T3 with...
journal article 2018
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Li, Z. (author), Visser, Peter (author), Hughes, Anthony E. (author), Homborg, A.M. (author), Gonzalez Garcia, Y. (author), Mol, J.M.C. (author)
The quest for novel alternatives to hexavalent-chromium-based corrosion inhibitors is of utmost significance and urgency. Strict international health and safety regulations, due to growing concerns regarding the impact of hexavalent chromium on human health and the environment, have pushed the commercial introduction of many alternative...
journal article 2024
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Cornet, A.J. (author), Homborg, A.M. (author), Ravi Anusuyadevi, P. (author), 't Hoen-Velterop, L. (author), Mol, J.M.C. (author)
Despite extensive research, eliminating hexavalent chromium-based inhibitors from aerospace coatings remains challenging due to a lack of understanding of coating degradation during aircraft service. This study addresses the issue by investigating the protective mechanisms and aging processes of chromate-containing coatings on aircraft...
journal article 2024
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Liu, Tong (author), Chen, Zhuoyao (author), Yang, Jingzhi (author), Ma, Lingwei (author), Mol, J.M.C. (author), Zhang, Dawei (author)
Machine learning is a powerful means for the rapid development of high-performance functional materials. In this study, we presented a machine learning workflow for predicting the corrosion resistance of a self-healing epoxy coating containing ZIF-8@Ca microfillers. The orthogonal Latin square method was used to investigate the effects of the...
journal article 2024
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Mopon, M. (author), Mol, J.M.C. (author), Garcia, Santiago J. (author)
Understanding how late an inhibitor can be released once corrosion initiated without compromising corrosion protection may help in developing more efficient anticorrosion coatings. We explored this idea through time-controlled Ce(NO<sub>3</sub>)<sub>3</sub> availability to AA2024-T3 immersed in 0.05 M NaCl. Ce(NO<sub>3</sub>)<sub>3</sub> was...
journal article 2024
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Cutz, L. (author), Tiringer, U. (author), de Jong, W. (author), Mol, J.M.C. (author)
Long transport distances and extended storage of biomass pellets especially in humid environments provide a suitable setting for enhanced degradation in the form of moisture sorption, cracking and attrition. We developed an optically transparent, low-cost and environmentally friendly coating to reduce moisture sorption and storage degradation...
journal article 2023
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Ma, Lingwei (author), Wang, Jinke (author), Zhang, D. (author), Huang, Yao (author), Huang, Luyao (author), Wang, Panjun (author), Qian, Hongchang (author), Li, Xiaogang (author), Terryn, H.A. (author), Mol, J.M.C. (author)
This work introduces a novel nanocomposite coating with dual-action self-healing corrosion protection activated by the photothermal response of plasmonic titanium nitride nanoparticles (TiN NPs). TiN@mesoporous SiO<sub>2</sub> core–shell nanocontainers were developed as reservoirs for benzotriazole (BTA) corrosion inhibitors and incorporated...
journal article 2021
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del Olmo, R. (author), Tiringer, U. (author), Milošev, I. (author), Visser, P. (author), Arrabal, R. (author), Matykina, E. (author), Mol, J.M.C. (author)
The effect of the presence of an anodic film and hybrid sol-gel coating loaded with corrosion inhibitors was evaluated as a strategy for enhanced barrier and active corrosion protection of aluminium alloy 2024-T3. In this study, AA2024-T3 specimens were anodized in a modified sulphuric-citric acid bath (SCA) as the first layer of a corrosion...
journal article 2021
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Putra, N.E. (author), Leeflang, M.A. (author), Klimopoulou, M. (author), Dong, J. (author), Taheri, P. (author), Huan, Z. (author), Fratila-Apachitei, E.L. (author), Mol, J.M.C. (author), Chang, J. (author), Zhou, J. (author), Zadpoor, A.A. (author)
The development of biodegradable Fe-based bone implants has rapidly progressed in recent years. Most of the challenges encountered in developing such implants have been tackled individually or in combination using additive manufacturing technologies. Yet not all the challenges have been overcome. Herein, we present porous FeMn-akermanite...
journal article 2023
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Gao, Yu (author), Zhang, Jingru (author), Wang, Donglei (author), Fan, Jiaxin (author), Mol, J.M.C. (author), Wang, Fuhui (author), Zhang, Danni (author), Xu, Dake (author)
Microbially influenced corrosion (MIC) of metals exerts a negative effect on the marine environment and causes a great loss of marine facilities. Corrosion prevention in an eco-friendly and sustainable way is a difficult problem to address, especially in the marine environment. In this work, Nocardiopsis dassonville, a corrosive bacteria...
journal article 2024
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Liu, M. (author), Zhu, Jia-Ning (author), Popovich, V. (author), Borisov, E. (author), Mol, J.M.C. (author), Gonzalez Garcia, Y. (author)
Electrochemical tests and surface analysis were applied to study the corrosion behavior and passive film characteristics of three-dimensional-printed NiTi shape memory alloys fabricated by laser-powder bed fusion (L-PBF) in artificial saliva at 37 °C. The passivity of L-PBF NiTi shows to be influenced by the process parameters and resulting...
journal article 2023
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Aghaeian, S. (author), Norouzi, F. (author), Sloof, W.G. (author), Mol, J.M.C. (author), Bottger, A.J. (author)
The parabolic growth rate constant (k<sub>p</sub>) of high-temperature oxidation of steels is predicted via a data analytics approach. Four machine learning models including Artificial Neural Networks, Random Forest, k-Nearest Neighbors, and Support Vector Regression are trained to establish the relations between the input features ...
journal article 2023
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