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Ding, Z. (author), Brouwer, J.C. (author), Kwakernaak, C. (author), Hermans, M.J.M. (author), Popovich, V. (author), Quadakkers, Willem J. (author), Sloof, W.G. (author)Mo(Al<sub>x</sub>Si<sub>1-x</sub>)<sub>2</sub> alloy with x in the range of 0.35–0.65 were prepared by a one-step spark plasma sintering. To study the exclusive formation of an α-Al<sub>2</sub>O<sub>3</sub> scale, oxidation experiments were conducted in low and high oxygen partial pressure ambient at 1373 K; viz.: 10<sup>−14</sup> and 0.21...journal article 2023
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Kiecana, A. (author), Kwakernaak, C. (author), van Dijk, N.H. (author), Brück, E.H. (author)The effect of the heat treatment on the magnetism, magnetocaloric effect and microstructure formation has been systematically studied in Fe-rich (Mn,Fe)<sub>y</sub>(P,Si) melt-spun ribbons (1.80 ≤ y ≤ 2.00). XRD, SEM and EDS measurements demonstrate that a metal deficiency prompts the stable (Mn,Fe)Si phase, whereas in the metal-rich region...journal article 2023
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Ding, Z. (author), Brouwer, J.C. (author), Kwakernaak, C. (author), Zhu, Jia-Ning (author), Popovich, V. (author), Hermans, M.J.M. (author), Sloof, W.G. (author)To prevent premature triggering of the healing reaction in Mo-Si containing self-healing thermal barrier coating system, an oxygen impenetrable shell (α-Al<sub>2</sub>O<sub>3</sub>) around the sacrificial healing particles (MoSi<sub>2</sub>) is desired. Here an encapsulation method is presented through selective oxidation of Al in Mo(Al<sub>x...journal article 2023
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Kiriinya, L.K. (author), Kwakernaak, M.C. (author), Van den Akker, Simone C.D. (author), Verbist, Guy L.M.M. (author), Picken, S.J. (author), Kelder, E.M. (author)We present a sustainable, inherently safe battery chemistry that is based on widely available and cheap materials, that is, iron and manganese hosted in alginate bio-material known from the food and medical industry. The resulting battery can be recycled to allow circularity. The electrodes were synthesised by the alginate caging the multi...journal article 2023
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You, Y. (author), Kim, Jungki (author), Kwakernaak, C. (author), Brouwer, J.C. (author), Westerwaal, Ruud (author), Sloof, W.G. (author)The surface oxidation and wettability of Mn and Si-alloyed steel after annealing at different conditions are studied with scanning electron microscope (SEM), X-ray photoelectron spectroscopy (XPS), and a so-called de-wetting method. After exposure at 950 °C for 1 hour in an Ar + 5 vol pct H<sub>2</sub> gas atmosphere with dew points (DP)...journal article 2022
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Kiecana, A. (author), Batashev, I. (author), Dugulan, A.I. (author), Kwakernaak, C. (author), Pieter, L. (author), Zhang, F. (author), van Dijk, N.H. (author), Brück, E.H. (author)The effect of Co and Ni doping on the structure, magnetic and magnetocaloric properties of Fe-rich (Mn,Fe)<sub>2</sub>(P,Si) compounds was studied. With increasing Co and Ni content, both the Curie temperature (T<sub>c</sub>) and the thermal hysteresis (ΔT<sub>hys</sub>) decreased, whereas the hexagonal P-62 m crystal structure was maintained...journal article 2022
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Kwakernaak, M.C. (author), Koel, Marijn (author), van den Berg, P.M. (author), Kelder, E.M. (author), Jager, W.F. (author)A novel protocol for the synthesis of perylene diimides (PDIs), by reacting perylene dianhydride (PDA) with aliphatic amines is reported. Full conversions were obtained at temperatures between 20 and 60 °C, using DBU as the base in DMF or DMSO. A "green"synthesis of PDIs, that runs at higher temperatures, was developed using K2CO3 in DMSO....journal article 2022
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Fu, Y. (author), Kwakernaak, C. (author), Sloof, W.G. (author), Tichelaar, F.D. (author), Brück, E.H. (author), van der Zwaag, S. (author), van Dijk, N.H. (author)Autonomous healing of creep-induced grain boundary cavities by Au-rich and W-rich precipitates was studied in a Fe-3Au-4W (wt pct) alloy at a fixed temperature of 823 K (550 °C) with different applied stresses. The ternary alloy, with two supersaturated healing solutes, serves as a model system to study the interplay between two separate...journal article 2020
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Fu, Y. (author), Kwakernaak, C. (author), Brouwer, J.C. (author), Sloof, W.G. (author), Brück, E.H. (author), van der Zwaag, S. (author), van Dijk, N.H. (author)Abstract: The precipitation of supersaturated solutes at free surfaces in ternary Fe–3Au–4W and binary Fe–3Au and Fe–4W alloys (composition in weight percentage) for different ageing times was investigated at a temperature of 700 °C. The time evolution of the surface precipitation is compared among the three alloys to investigate the...journal article 2020
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Janssen, G.C.A.M. (author), van der Pers, N.M. (author), Hendrikx, R.W.A. (author), Bottger, A.J. (author), Kwakernaak, C. (author), Rieger, B. (author), Sluiter, M.H.F. (author)Single-crystal copper films on sapphire have recently been reported upon in relation to graphene growth on these films. In the present paper the kinetics of the formation of single crystal copper films is investigated. We demonstrate the importance of heating the sapphire substrate in 1000 hPa oxygen, followed by a fast cooling prior to...journal article 2020
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Osada, Toshio (author), Watabe, Aiko (author), Yamamoto, Joji (author), Brouwer, J.C. (author), Kwakernaak, C. (author), Ozaki, Shingo (author), van der Zwaag, S. (author), Sloof, W.G. (author)Bones of humans and animals combine two unique features, namely: they are brittle yet have a very high fracture toughness linked to the tortuosity of the crack path and they have the ability to repeatedly heal local fissures such that full recovery of overall mechanical properties is obtained even if the local bone structure is irreversibly...journal article 2020
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Fang, H. (author), Szymanski, N. (author), Versteylen, C.D. (author), Cloetens, P. (author), Kwakernaak, C. (author), Sloof, W.G. (author), Tichelaar, F.D. (author), Balachandran, S. (author), Herbig, M. (author), Brück, E.H. (author), van der Zwaag, S. (author), van Dijk, N.H. (author)When metals are mechanically loaded at elevated temperatures for extended periods of time, creep damage will occur in the form of cavities at grain boundaries. In the present experiments it is demonstrated that in binary iron-tungsten alloys creep damage can be self healed by selective precipitation of a W-rich phase inside these cavities. Using...journal article 2019
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Gavel, D.J. (author), Adema, A.T. (author), van der Stel, Jan (author), Kwakernaak, C. (author), Sietsma, J. (author), Boom, R. (author), Yang, Y. (author)The melting and dripping behaviour of an iron ore pellet bed mixed with nut coke are investigated through a series of quenching, melting and dripping experiments. In the melting bed of iron ore pellets, nut coke acts as a frame to maintain the passage for the gas flow. The iron carburisation level of the pellet shell is found to control the...journal article 2019
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Celada-Casero, Carola (author), Kwakernaak, C. (author), Sietsma, J. (author), Santofimia, Maria Jesus (author)The influence of the prior austenite grain size (PAGS), varying between 6 and 185 μm, on the microstructural development of a low carbon steel during quenching and partitioning (Q&P) processing is investigated. The effect on the size and morphological aspects of the microconstituents is discussed based on the kinetics of carbon...journal article 2019
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Nozahic, F. (author), Carabat, A.L. (author), Mao, W. (author), Monceau, D. (author), Estournes, C. (author), Kwakernaak, C. (author), van der Zwaag, S. (author), Sloof, W.G. (author)Recently MoSi<sub>2</sub> sacrificial particles embedded in yttria partially stabilized zirconia (YPSZ)have been proposed as attractive healing agents to realize significant extension of the lifetime of the thermally loaded structures. Upon local fracture of the YPSZ, the embedded healing particles in the path and in the vicinity of the crack...journal article 2019
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Farle, A.M. (author), Krishnasamy, J. (author), Turteltaub, S.R. (author), Kwakernaak, C. (author), van der Zwaag, S. (author), Sloof, W.G. (author)A wedge loaded testing methodology to determine the fracture energy and strength of (semi-) brittle (metallo-)ceramics is presented. The methodology combines a tailored specimen geometry and a comprehensive finite element analysis based on cohesive zone modelling. The use of a simulation-based approach to extract both fracture strength and...journal article 2018
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Kwakernaak, C. (author), Sloof, W.G. (author)A fast and generic scheme is proposed to calculate the work of adhesion between two different materials or the cohesive energy between two crystal planes in a material. These calculations make use of the regular solution theory. This theory is extended to describe chemical interactions between atoms at either side of an interface. The so...journal article 2018
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Medici, R. (author), Stammes, J.K. (author), Otten, L.G. (author), Hanefeld, U. (author), Kwakernaak, Stender (author)α-Hydroxy ketones and vicinal diols constitute well-known building blocks in organic synthesis. Here we describe one enzyme that enables the enantioselective synthesis of both building blocks starting from diketones. The enzyme 2,3-butanediol dehydrogenase (BudC) from S. marcescens CECT 977 belongs to the NADH-dependent metal-independent short...journal article 2017
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Zhang, S. (author), Fang, H. (author), Gramsma, M. E. (author), Kwakernaak, C. (author), Sloof, W.G. (author), Tichelaar, F.D. (author), Brück, E.H. (author), van der Zwaag, S. (author), van Dijk, N.H. (author)We have investigated the autonomous repair of creep damage by site-selective precipitation in a binary Fe-Mo alloy (6.2 wt pct Mo) during constant-stress creep tests at temperatures of 813 K, 823 K, and 838 K (540 °C, 550 °C, and 565 °C). Scanning electron microscopy studies on the morphology of the creep-failed samples reveal irregularly...journal article 2016
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Zhang, S. (author), Kwakernaak, C. (author), Tichelaar, F.D. (author), Sloof, W.G. (author), Kuzmina, M. (author), Herbig, M. (author), Raabe, D. (author), Brück, E. (author), Van der Zwaag, S. (author), Van Dijk, N.H. (author)The autonomous repair mechanism of creep cavitation during high-temperature deformation has been investigated in Fe-Au and Fe-Au-B-N alloys. Combined electron-microscopy techniques and atom probe tomography reveal how the improved creep properties result from Au precipitation within the creep cavities, preferentially formed on grain boundaries...journal article 2015
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