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van Hattem, A. (author), Vlieland, J. (author), Dankelman, B.J.R. (author), Thijs, M.A. (author), Wallez, Gilles (author), Dardenne, Kathy (author), Rothe, Jörg (author), Konings, R. (author), Smith, A.L. (author)
The quaternary compound Cs<sub>2</sub>Pb(MoO<sub>4</sub>)<sub>2</sub> was synthesized and its structure was characterized using X-ray and neutron diffraction from 298 to 773 K, while thermal expansion was studied from 298 to 723 K. The crystal structure of the high-temperature phase β-Cs<sub>2</sub>Pb(MoO<sub>4</sub>)<sub>2</sub> was...
journal article 2023
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Ocadiz flores, J.A. (author), Gheribi, A. E. (author), Vlieland, J. (author), Dardenne, K. (author), Rothe, J. (author), Konings, R. (author), Smith, A.L. (author)
© 2021 The Authors LiF-UF4 is a key binary system for molten fluoride reactor technology, which has not been scrutinized as thoroughly as the closely related LiF-ThF4 system. The phase diagram equilibria in the system LiF-UF4 are explored in this work with X-ray diffraction (XRD) and differential scanning calorimetry (DSC). The short-range...
journal article 2021
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Ocadiz flores, J.A. (author), Gheribi, A. E. (author), Vlieland, J. (author), de Haas, D.W. (author), Dardenne, K. (author), Rothe, J. (author), Konings, R. (author), Smith, A.L. (author)
The short-range structures of LiF-ThF4, NaF-AnF4, KF-AnF4, and Cs-AnF4 (An = Th, U), were probed using in situ high temperature Extended X-ray Absorption Fine Structure (EXAFS) spectroscopy. Signally, the EXAFS spectra of pure molten ThF4 and UF4 were measured for the first time. The data were interpreted with the aid of Molecular Dynamics ...
journal article 2021