Asymmetric α-benzylation of cyclic ketones enabled by concurrent chemical aldol condensation and biocatalytic reduction

Chemoenzymatic cascade catalysis has emerged as a revolutionary tool for streamlining traditional retrosynthetic disconnections, creating new possibilities for the asymmetric synthesis of valuable chiral compounds. Here we construct a one-pot concurrent chemoenzymatic cascade by integrating organobismuth-catalyzed aldol condensation with ene...

Continuous Fatty Acid Decarboxylation using an Immobilized Photodecarboxylase in a Membrane Reactor

The realm of photobiocatalytic alkane biofuel synthesis has burgeoned recently; however, the current dearth of well-established and scalable production methodologies in this domain remains conspicuous. In this investigation, we engineered a modified form of membrane-associated fatty acid photodecarboxylase sourced from Micractinium conductrix...

Contribution of extracellular polymeric substances fractions to the adsorption of silver nanoparticles by activated sludge

The extracellular polymeric substances (EPS) from activated sludge played significant roles in the removal of nanoparticles from wastewater. A series of batch experiments were carried out to determine the adsorption mechanism of three nano-Ag by activated sludge, as well as the contributions of EPS fractions including dissolved EPS (DEPS),...

Comparison of usage regularity and its determinants between docked and dockless bike-sharing systems: A case study in Nanjing, China

Bike-sharing systems have rapidly expanded around the world. Previous studies found that docked and dockless bike-sharing systems are different in terms of user demand and travel characteristics. However, their usage regularity and its determinants have not been fully understood. This research aims to fill this gap by exploring smart card...

Assessment on China's urbanization after the implementation of main functional areas planning

China has implemented main functional areas planning (MFAP) since 2010, which is essential for improving the efficiency of land space utilization and achieving sustainable urban development. Quantitative assessments of the urban development levels (UDLs) at the county level across China after the implementation of MFAP have not been well...

Assessing the global resilience of water quality sensor placement strategies within water distribution systems

Water quality sensors are often spatially distributed in water distribution systems (WDSs) to detect contamination events and monitor quality parameters (e.g., chlorine residual levels), thereby ensuring safety of a WDS. The performance of a water quality sensor placement strategy (WQSPS) is not only affected by sensor spatial deployment that...

Abundant grain boundaries activate highly efficient lithium ion transportation in high rate Li₄Ti₅O₁₂ compact microspheres

It is a huge challenge for high-tap-density electrodes to achieve high volumetric energy density but without compromising the ionic transportation. Herein, we prepared compact Li₄Ti₅O₁₂ (LTO) microspheres consisting of densely packed primary nanoparticles. The real space distribution of lithium ions inside the...