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Wu, Bin (author), Wang, Xiangyun (author), Yang, Bo (author), Ma, Yunjian (author), Hollmann, F. (author), Wang, Yonghua (author)
In the present work we propose a bienzymatic cascade for the oxyfunctionalisation of cycloalkanes to cyclic alcohols/cyclic ketones. By combining a H<sub>2</sub>O<sub>2</sub>-dependent peroxygenase with a O<sub>2</sub>-consuming and H<sub>2</sub>O<sub>2</sub>-producing alcohol oxidase an overall aerobic oxidation system was established. A...
journal article 2023
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van Schie, M.M.C.H. (author), Pedroso de Almeida, T. (author), Laudadio, Gabriele (author), Tieves, F. (author), Fernandez Fueyo, E. (author), Noël, Timothy (author), Arends, I.W.C.E. (author), Hollmann, F. (author)
The biocatalytic preparation of trans-hex-2-enal from trans-hex-2-enol using a novel aryl alcohol oxidase from Pleurotus eryngii (PeAAOx) is reported. As O<sub>2</sub>-dependent enzyme PeAAOx-dependent reactions are generally plagued by the poor solubility of O<sub>2</sub> in aqueous media and mass transfer limitations resulting in poor...
journal article 2018