Gas bubble removal from a zero-gap alkaline electrolyser with a pressure swing and why foam electrodes might not be suitable at high current densities

To make green hydrogen more economically attractive, the energy losses in alkaline electrolysis need to be minimized while operating at high current densities (1 A cm⁻²). At these current densities the ohmic resistance and gas bubbles effects contribute largely to the energy losses. To mitigate the gas bubbles losses, we...

Direct Imaging of Local pH Reveals Bubble-Induced Mixing in a CO₂ Electrolyzer

Electrochemical CO₂ reduction poses a promising pathway to produce hydrocarbon chemicals and fuels without relying on fossil fuels. Gas diffusion electrodes allow high selectivity for desired carbon products at high current density by ensuring a sufficient CO₂ mass transfer rate to the catalyst layer. In addition to CO...

Quinolinium-Based Fluorescent Probes for Dynamic pH Monitoring in Aqueous Media at High pH Using Fluorescence Lifetime Imaging

Spatiotemporal pH imaging using fluorescence lifetime imaging microscopy (FLIM) is an excellent technique for investigating dynamic (electro)chemical processes. However, probes that are responsive at high pH values are not available. Here, we describe the development and application of dedicated pH probes based on the 1-methyl-7-amino...

Substitution Effects on the Photoinduced Charge-Transfer Properties of Novel Perylene-3,4,9,10-tetracarboxylic Acid Derivatives

We report here the synthesis and photophysical study of a series of electron donor–acceptor molecules, in which electron-donating 4-methoxyphenoxy groups are attached to the 1,7-bay positions of four different perylene tetracarboxylic acid derivatives, namely, perylene tetraesters 1, perylene monoimide diesters 2, perylene bisimides 3, and...