Non-linear high Tg polyimide-based membranes for separating CO₂/CH₄ gas mixtures

A novel series membranes based on non-linear all-aromatic polyimides (PIs) was investigated with the aim to understand how the PI backbone geometry and local electrostatics govern gas transport and the ability to separate CO₂/CH₄ mixtures. Non-linear 3-ring aromatic diamines, with exocyclic bond angles varying between...