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Garcia Santaclara, J. (author), Olivos Suarez, A.I. (author), du Fossé, Indy (author), Houtepen, A.J. (author), Hunger, J (author), Kapteijn, F. (author), Gascon, Jorge (author), van der Veen, M.A. (author)
The highly porous titanium based metal–organic framework NH2-MIL-125(Ti) has recently attracted significant attention in the field of photocatalysis as a promising material for H+ reduction. This work reveals charge transfer upon visible light illumination from this MOF to two different charge acceptors, as an alternative to sacrificial electron...
journal article 2017
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Nasalevich, M. (author), Hendon, Christopher H. (author), Garcia Santaclara, J. (author), Svane, Katrine (author), van der Linden, B. (author), Veber, Sergey L. (author), Fedin, Matvey V. (author), Houtepen, A.J. (author), van der Veen, M.A. (author), Kapteijn, F. (author), Walsh, Aron (author), Gascon, Jorge (author)
Metal-organic frameworks (MOFs) containing d<sup>0</sup> metals such as NH<sub>2</sub>-MIL-125(Ti), NH<sub>2</sub>-UiO-66(Zr) and NH<sub>2</sub>-UiO-66(Hf) are among the most studied MOFs for photocatalytic applications. Despite structural similarities, we demonstrate that the electronic properties of these MOFs are markedly different. As...
journal article 2016