2D Dion–Jacobson CsPbI₃ with Enhanced Interlayer Coupling for Stable and Efficient Photovoltaics

Inorganic 2D layered CsPbI₃ is awaiting to overcome the phase instability of traditional 3D components. However, the most reported Ruddlesden–Popper (RP) phase 2D CsPbI₃ leads to larger interlayer distance and weaker interlayer coupling since the existence of the van der Waals gap, which deteriorates the performance of...

Manipulate energy transport via fluorinated spacers towards record-efficiency 2D Dion-Jacobson CsPbI₃ solar cells

Two-dimensional (2D) Dion-Jacobson (D-J)-type cesium lead iodide CsPbI ₃ perform remarkably in terms of stability. However, the complex interactions between spacer and inorganic layers limit its excellent progress in perovskite solar cells (PSCs). Herein, starting from the considerable structural diversity of organic spacers, we...

An Interface Co-modification Strategy for Improving the Efficiency and Stability of CsPbI₃Perovskite Solar Cells

Interface engineering is a simple and effective strategy for improving the photovoltaic performance and stability of perovskite solar cells (PSCs). Herein, an interface co-modification strategy is proposed, using [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) and 2-fluoro-1,4-phenylenediammonium iodide (2FPPD) to modify the electron...

Multifunctional pressure/temperature/bending sensor made of carbon fibre-multiwall carbon nanotubes for artificial electronic application

A flexible sensor with excellent pressure, temperature, and bending sensitivity is fabricated based on the conductive skeleton material with hierarchical porous structure. The conductive skeleton material is composed of carbon fibres (CFs) and multiwalled carbon nanotubes (MWCNTs), in which lay perpendicular to each other CFs are used as...

Guanidium-assisted crystallization engineering for highly efficient CsPbI₃ solar cells

Iodine vacancies and uncoordinated iodide ions of CsPbI₃ films are mainly responsible for nonradiative recombination. Here, we report a composition-engineering passivation method that through guanidium (GA⁺) and I⁻ forms strong hydrogen bonds to passivate iodine vacancies and reduce defects. Both experimental...

Solvent Engineering for High-Performance Two-Dimensional Ruddlesden-Popper CsPbI₃Solar Cells

Two-dimensional (2D) Ruddlesden-Popper (RP) CsPbI3 exhibits enhanced phase stability compared with 3D CsPbI3. However, the issue of the uncontrollable crystallization process limits its photovoltaic performance. Here, the influence of a binary mixed solvent on the film quality and photovoltaic properties of (PEA)2Cs4Pb5I16 (n = 5) is studied...