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van Hattem, A. (author), Alders, D.C. (author), Konings, R. (author), Smith, A.L. (author)The thermochemistry of the ternary system CsI-PbI<sub>2</sub>-BiI<sub>3</sub>, of interest for applications in photovoltaics, memory devices, and nuclear applications, among other things, is investigated in this work. The binary phase diagrams CsI-PbI<sub>2</sub> and CsI-BiI<sub>3</sub> were subjected to renewed experimental investigation,...journal article 2023
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van Hattem, A. (author), Vlieland, J. (author), Dankelman, B.J.R. (author), Thijs, M.A. (author), Wallez, Gilles (author), Dardenne, Kathy (author), Rothe, Jörg (author), Konings, R. (author), Smith, A.L. (author)The quaternary compound Cs<sub>2</sub>Pb(MoO<sub>4</sub>)<sub>2</sub> was synthesized and its structure was characterized using X-ray and neutron diffraction from 298 to 773 K, while thermal expansion was studied from 298 to 723 K. The crystal structure of the high-temperature phase β-Cs<sub>2</sub>Pb(MoO<sub>4</sub>)<sub>2</sub> was...journal article 2023
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van Hattem, A. (author), Griveau, Jean Christophe (author), Colineau, Eric (author), Lefering, A.J.E. (author), Konings, R. (author), Smith, A.L. (author)The heat capacities of CsPbI<sub>3</sub>, Cs<sub>4</sub>PbI<sub>6</sub>, and Cs<sub>3</sub>Bi<sub>2</sub>I<sub>9</sub> were studied using low-temperature thermal relaxation calorimetry in the temperature range of 1.9-300 K. The three compounds are insulators, with no electronic contribution to the heat capacity. None of them show detectable...journal article 2023