- document
-
Vasileiadis, A. (author), Zhou, Q. (author), Lu, Yaxiang (author), Li, Y. (author), Ombrini, P. (author), Chen, Z. (author), van der Jagt, R. (author), Ganapathy, S. (author), Wagemaker, M. (author)Correction to: Nature Energyhttps://doi.org/10.1038/s41560-023-01414-5, published online 3 January 2024. In the version of this article initially published, lithium (green, “Li”) and sodium (purple, “Na”) color key labels in Fig. 3a,d,e were interchanged and are now amended in the HTML and PDF versions of the article.journal article 2024
- document
-
Vasileiadis, A. (author), Zhou, Quan (author), Lu, Yaxiang (author), Li, Yu (author), Ombrini, P. (author), Chen, Zhao (author), van der Jagt, R. (author), Ganapathy, S. (author), Wagemaker, M. (author)Transport electrification and grid storage hinge largely on fast-charging capabilities of Li- and Na-ion batteries, but anodes such as graphite with plating issues drive the scientific focus towards anodes with slopped storage potentials. Here we report fast charging of ampere-hour-level full Na-ion batteries within about 9 minutes for...journal article 2024
- document
-
Wang, Q. (author), Zhou, Yunan (author), Wang, Xuelong (author), Guo, Hao (author), Gong, Shuiping (author), Yao, Zhenpeng (author), Ganapathy, S. (author), Zhao, C. (author), Wagemaker, M. (author)All-solid-state lithium batteries have attracted widespread attention for next-generation energy storage, potentially providing enhanced safety and cycling stability. The performance of such batteries relies on solid electrolyte materials; hence many structures/phases are being investigated with increasing compositional complexity. Among the...journal article 2024
- document
-
Zhang, S. (author), Li, Yuhang (author), Bannenberg, L.J. (author), Liu, Ming (author), Ganapathy, S. (author), Wagemaker, M. (author)Formation cycling is a critical process aimed at improving the performance of lithium ion (Li-ion) batteries during subsequent use. Achieving highly reversible Li-metal anodes, which would boost battery energy density, is a formidable challenge. Here, formation cycling and its impact on the subsequent cycling are largely unexplored. Through...journal article 2024
- document
-
Wang, C. (author), Liu, M. (author), Bannenberg, L.J. (author), Zhao, C. (author), Thijs, M.A. (author), Boshuizen, B. (author), Ganapathy, S. (author), Wagemaker, M. (author)Lithium metal with its high theoretical capacity and low negative potential is considered one of the most important candidates to raise the energy density of all-solid-state batteries. However, lithium filament growth and its induced solid electrolyte decomposition pose severe challenges to realize a long cycle life. Here, dendrite growth in...journal article 2024
- document
-
Voltage Imaging with Engineered Proton-Pumping Rhodopsins: Insights from the Proton Transfer PathwayMeng, X. (author), Ganapathy, S. (author), van Roemburg, Lars (author), Post, M.G. (author), Brinks, D. (author)Voltage imaging using genetically encoded voltage indicators (GEVIs) has taken the field of neuroscience by storm in the past decade. Its ability to create subcellular and network level readouts of electrical dynamics depends critically on the kinetics of the response to voltage of the indicator used. Engineered microbial rhodopsins form a...review 2023
- document
-
Ganapathy, S. (author), Meng, X. (author), Mossel, D.D.M. (author), Jagt, Mels (author), Brinks, D. (author)Genetically encoded voltage indicators, particularly those based on microbial rhodopsins, are gaining traction in neuroscience as fluorescent sensors for imaging voltage dynamics with high-spatiotemporal precision. Here we establish a novel genetically encoded voltage indicator candidate based on the recently discovered subfamily of the...journal article 2023
- document
-
Liu, M. (author), Wang, C. (author), Zhao, C. (author), van der Maas, E.L. (author), Lin, Kui (author), Arszelewska, Violetta (author), Li, Baohua (author), Ganapathy, S. (author), Wagemaker, M. (author)The original version of this article contained errors in Figure 3a and Figure 3f. In Figure 3a, the activation energies (Ea) were calculated using a log scale instead of a logarithm ln scale. In Figure 3f, the y-axis interval was not properly selected. The correct y-axis interval in Figure 3f and the numerical values of the activation energy...journal article 2023
- document
-
Gautam, A. (author), Al-Kutubi, H.A.A. (author), Famprikis, T. (author), Ganapathy, S. (author), Wagemaker, M. (author)Lithium argyrodite superionic conductors have recently gained significant attention as potential solid electrolytes for all-solid-state batteries because of their high ionic conductivity and ease of processing. Promising aspects of these materials are the ability to introduce halides (Li<sub>6-x</sub>PS<sub>5-x</sub>Hal<sub>1+x</sub>, Hal =...journal article 2023
- document
-
Wang, Q. (author), Zhao, C. (author), Wang, Jianlin (author), Yao, Zhenpeng (author), Wang, Shuwei (author), Kumar, Sai Govind Hari (author), Ganapathy, S. (author), Eustace, S.J. (author), Wagemaker, M. (author)High-entropy alloys/compounds have large configurational entropy by introducing multiple components, showing improved functional properties that exceed those of conventional materials. However, how increasing entropy impacts the thermodynamic/kinetic properties in liquids that are ambiguous. Here we show this strategy in liquid electrolytes...journal article 2023
- document
-
Landgraf, V.R. (author), Famprikis, T. (author), de Leeuw, Joris (author), Bannenberg, L.J. (author), Ganapathy, S. (author), Wagemaker, M. (author)Most highly Li-conducting solid electrolytes (σ<sub>RT</sub> > 10<sup>-3</sup> S cm<sup>-1</sup>) are unstable against lithium-metal and suffer from detrimental solid-electrolyte decomposition at the lithium-metal/solid-electrolyte interface. Solid electrolytes that are stable against lithium metal thus offer a direct route to stabilize...journal article 2023
- document
-
van der Maas, E.L. (author), Famprikis, Theodosios (author), Pieters, S. (author), Dijkstra, Jonas P. (author), Li, Z. (author), Parnell, S.R. (author), Smith, Ronald I. (author), van Eck, Ernst R.H. (author), Ganapathy, S. (author), Wagemaker, M. (author)Chloride-based solid electrolytes are considered interesting candidates for catholytes in all-solid-state batteries due to their high electrochemical stability, which allows the use of high-voltage cathodes without protective coatings. Aliovalent Zr(iv) substitution is a widely applicable strategy to increase the ionic conductivity of Li<sub...journal article 2023
- document
-
Wang, Q. (author), Zhao, C. (author), Yao, Zhenpeng (author), Wang, Jianlin (author), Wu, Fangting (author), Kumar, Sai Govind Hari (author), Ganapathy, S. (author), Eustace, S.J. (author), Wagemaker, M. (author)Developing liquid electrolytes with higher kinetics and enhanced interphase stability is one of the key challenges for lithium batteries. However, the poor solubility of lithium salts in solvents sets constraints that compromises the electrolyte properties. Here, it is shown that introducing multiple salts to form a high-entropy solution,...journal article 2023
- document
-
Liu, C. (author), Uslamin, E. (author), Khramenkova, E. (author), Sireci, Enrico (author), Ouwehand, Lucas T.L.J. (author), Ganapathy, S. (author), Kapteijn, F. (author), Pidko, E.A. (author)The production of valuable aromatics and the rapid catalyst deactivation due to coking are intimately related in the zeolite-catalyzed aromatization reactions. Here, we demonstrate that these two processes can be decoupled by promoting the Ga/HZSM-5 aromatization catalyst with Ca. The resulting bimetallic catalysts combine high selectivity to...journal article 2022
- document
-
van der Maas, E.L. (author), Zhao, W. (author), Cheng, Z. (author), Famprikis, T. (author), Thijs, M.A. (author), Parnell, S.R. (author), Ganapathy, S. (author), Wagemaker, M. (author)Li<sub>3</sub>YX<sub>6</sub>(X = Cl, Br) materials are Li-ion conductors that can be used as solid electrolytes in all solid-state batteries. Solid electrolytes ideally have high ionic conductivity and (electro)chemical compatibility with the electrodes. It was proven that introducing Br to Li<sub>3</sub>YCl<sub>6</sub>increases ionic...journal article 2022
- document
-
Wang, Q. (author), Zhao, C. (author), Wang, Shuwei (author), Wang, Jianlin (author), Liu, M. (author), Ganapathy, S. (author), Bai, Xuedong (author), Li, Baohua (author), Wagemaker, M. (author)Improving the reversibility of lithium metal batteries is one of the challenges in current battery research. This requires better fundamental understanding of the evolution of the lithium deposition morphology, which is very complex due to the various parameters involved in different systems. Here, we clarify the fundamental origins of...journal article 2022
- document
-
Weijers, M.J. (author), Karanth, P. (author), Ganapathy, S. (author), Mulder, F.M. (author)Nanostructured solid composite electrolyte or nano-SCE, which is composed of an ionic liquid, nanoporous silica, and residuals of immobilized precursor components, shows promising synergistic properties. The ionic conductivity of nano-SCE is in the range of 2–5 mS cm<sup>−1</sup>, which exceeds the bulk ionic liquid conductivity at ambient...journal article 2022
- document
-
Liang, Jianwen (author), van der Maas, E.L. (author), Luo, Jing (author), Li, Xiaona (author), Chen, Ning (author), Adair, Keegan R. (author), Li, Weihan (author), Li, Junjie (author), Hu, Yongfeng (author), Liu, Jue (author), Zhang, Li (author), Zhao, W. (author), Parnell, S.R. (author), Ganapathy, S. (author), Wagemaker, M. (author)Understanding the relationship between structure, ionic conductivity, and synthesis is the key to the development of superionic conductors. Here, a series of Li<sub>3-3</sub><sub>x</sub>M<sub>1+</sub><sub>x</sub>Cl<sub>6</sub> (−0.14 < x ≤ 0.5, M = Tb, Dy, Ho, Y, Er, Tm) solid electrolytes with orthorhombic and trigonal structures are...journal article 2022
- document
-
Ubbink, R.F. (author), Gonçalves Pereira Fonseca DeAl, G.P.F. (author), Iziyi, Hodayfa (author), du Fossé, I. (author), Verkleij, Ruud (author), Ganapathy, S. (author), Van Eck, Ernst R.H. (author), Houtepen, A.J. (author)Indium phosphide quantum dots are the main alternative for toxic and restricted Cd-based quantum dots for lighting and display applications, but in the absence of protecting ZnSe and/or ZnS shells, InP quantum dots suffer from low photoluminescence quantum yields. Traditionally, HF treatments have been used to improve the quantum yield of InP...journal article 2022
- document
-
Liu, C. (author), Uslamin, E. (author), van Vreeswijk, Sophie H. (author), Yarulina, Irina (author), Ganapathy, S. (author), Weckhuysen, Bert M. (author), Kapteijn, F. (author), Pidko, E.A. (author)Identification of the catalyst characteristics correlating with the key performance parameters including selectivity and stability is key to the rational catalyst design. Herein we focused on the identification of property-performance relationships in the methanol-to-olefin (MTO) process by studying in detail the catalytic behaviour of MFI,...journal article 2022