Identifying the Role of Primary and Secondary Interactions on the Mechanical Properties and Healing of Densely Branched Polyimides

We present a systematic study of the role of the aromatic dianhydride structure on the self-healing behavior of dimer diamine-based polyimides. By means of solid-state NMR and rheology, we studied the molecular and microscale dynamics of four polyimides comprising the same aliphatic branched diamine yet with variable dianhydride rigidities...