Effect of H₂S and HCl contaminants on nickel and ceria pattern anode solid oxide fuel cells

In this study, with the motivation of elucidating the effect of H₂S and HCl on solid oxide fuel cell anodes, nickel and ceria pattern anodes are prepared on yttrium-stabilized zirconia electrolyte, and the effect of H₂S and HCl on their performance is tested using electrochemical impedance spectroscopy. However, it has...

A detailed look into hydrogen electrochemical oxidation on ceria anodes

Using the Nernst-Planck-Poisson model and a detailed reaction mechanism, we studied the hydrogen electrochemical oxidation on a ceria anode. Resistances caused by surface kinetics, and bulk transport of oxide-ion vacancies and electrons are computed individually to identify the dominant resistive process. The effect of operating conditions...

Publisher's Note: Diffusion Impedance on Nickel/Gadolinia-Doped Ceria Anodes for Solid Oxide Fuel Cells [J. Electrochem. Soc., 156, B1417 (2009)]

Diffusion Impedance on Nickel/Gadolinia-Doped Ceria Anodes for Solid Oxide Fuel Cells

Electrochemical impedance measurements were carried out on symmetrical nickel/gadolinia-doped ceria test cells. For H2, N2, and H2O mixtures, the diffusion length obtained based on the impedance measurements is on the order of centimeters. This high value of the diffusion length is attributed to the flow field in the reactor. It is suggested...