Charge transport in a zinc-porphyrin single-molecule junction

We have investigated charge transport in ZnTPPdT-Pyr (TPPdT: 5,15-di(p-thiolphenyl)-10,20-di(p-tolyl)porphyrin) molecular junctions using the lithographic mechanically controllable break-junction (MCBJ) technique at room temperature and cryogenic temperature (6 K). We combined low-bias statistical measurements with spectroscopy of the molecular...

Q-factor control of a microcantilever by mechanical sideband excitation

We demonstrate the coupling between the fundamental and second flexural modes of a microcantilever. A mechanical analogue of cavity-optomechanics is then employed, where the mechanical cavity is formed by the second vibrational mode of the same cantilever, coupled to the fundamental mode via the geometric nonlinearity. By exciting the cantilever...

Discrete-time quadrature feedback cooling of a radio-frequency mechanical resonator

We have employed a feedback cooling scheme, which combines high-frequency mixing with digital signal processing. The frequency and damping rate of a 2 MHz micromechanical resonator embedded in a dc SQUID are adjusted with the feedback, and active cooling to a temperature of 14.3 mK is demonstrated. This technique can be applied to GHz resonators...

Electrical control over the Fe(II) spin crossover in a single molecule: Theory and experiment

We report on theoretical and experimental work involving a particular molecular switch, an [FeII(L)2]2+ complex, that utilizes a spin transition (“crossover”). The hallmark of this transition is a change of the spin of the metal ion, SFe=0 to SFe=2, at fixed oxidation state of the Fe ion. Combining density functional theory and first principles...

A versatile low-temperature setup for the electrical characterization of single-molecule junctions

We present a modular high-vacuum setup for the electrical characterization of single molecules down to liquid helium temperatures. The experimental design is based on microfabricated mechanically controllable break junctions, which offer control over the distance of two electrodes via the bending of a flexible substrate. The actuator part of the...

Mechanical stiffening, bistability, and bit operations in a microcantilever

We investigate the nonlinear dynamics of microcantilevers. We demonstrate mechanical stiffening of the frequency response at large amplitudes, originating from the geometric nonlinearity. At strong driving the cantilever amplitude is bistable. We map the bistable regime as a function of drive frequency and amplitude, and suggest several...