Metabolic Fate of Metallothionein in Copper and Zinc Interaction in Cultured Liver Cells

Zeolite catalyzed nucleophilic aromatic substitution reactions

Atomistic simulation of Cu-Ta thin film deposition and other phenomena

Tantalum (Ta) is a metal with good properties to act as a diffusion barrier material in computer chips, where it should prevent the mixing of Cu into Si and SiO. The deposition of thin Cu films onto various Ta substrates has been studied through molecular dynamics simulations, using either empirical EAM potentials or Density Functional Theory ...

Bias-dependent contact resistance in rubrene single-crystal field-effect transistors

The authors report a systematic study of the bias-dependent contact resistance in rubrene single-crystal field-effect transistors with Ni, Co, Cu, Au, and Pt electrodes. They show that the reproducibility in the values of contact resistance strongly depends on the metal, ranging from a factor of 2 for Ni to more than three orders of magnitude...

Effects of heavy metals on microbial diversity and bacterial resistance in marine sediments

In North-Western Europe alone more than 200 million cubic meters of contaminated sludge is dredged on an annual basis. Deposition of dredged harbour sediments in relatively undisturbed ecosystems is often considered a viable option, under the assumption that metals are not released into the environment. This research initially focused on the...

Quantitative analysis of electronic transport through weakly coupled metal/organic interfaces

Using single-crystal transistors, we have performed a systematic experimental study of electronic transport through oxidized copper/rubrene interfaces as a function of temperature and bias. We find that the measurements can be quantitatively reproduced in terms of the thermionic emission theory for Schottky diodes, if the effect of the bias...

Josephson squelch filter for quantum nanocircuits

We fabricated and tested a squelch circuit consisting of a copper powder filter with an embedded Josephson junction connected to ground. For small signals (squelch ON), the small junction inductance attenuates strongly from dc to at least 1 GHz, while for higher frequencies dissipation in the copper powder increases the attenuation exponentially...

Substrate-dependent quasiparticle recombination time in superconducting resonators

We demonstrate an increased quasiparticle recombination time in superconducting resonators on a SiNx membrane, compared to identical resonators on a SiNx/Si wafer. An interpretation is given using a thermal model of the membrane. Using an array of tunnel junctions to cool or heat the membrane, we show that the resonators on the membranes are...

Oxidation kinetics of nanoscale copper films studied by terahertz transmission spectroscopy

Terahertz (THz) transmission spectroscopy is used to measure the oxidation kinetics of copper thin films evaporated on silicon substrates. The transmission of broadband THz pulses from 1 to 7 THz through the copper film is measured while it gets oxidized at an elevated temperature in ambient air. The change in the transmitted THz electric field...

The Amyloid Precursor Protein (APP) Does Not Have a Ferroxidase Site in Its E2 Domain

The ubiquitous 24-meric iron-storage protein ferritin and multicopper oxidases such as ceruloplasmin or hephaestin catalyze oxidation of Fe(II) to Fe(III), using molecular oxygen as oxidant. The ferroxidase activity of these proteins is essential for cellular iron homeostasis. It has been reported that the amyloid precursor protein (APP) also...