- document
-
Li, Z. (author)Over many decades, intensive studies have been performed towards safe and sustainable substitutes for chromate corrosion inhibitors in active corrosion protection coatings for aerospace aluminium alloys. The proposed candidates must provide similar corrosion protection as compared to that of chromate-based compounds and be cost-effective for...doctoral thesis 2024
- document
-
Li, Z. (author), Visser, Peter (author), Hughes, Anthony E. (author), Homborg, A.M. (author), Gonzalez Garcia, Y. (author), Mol, J.M.C. (author)The quest for novel alternatives to hexavalent-chromium-based corrosion inhibitors is of utmost significance and urgency. Strict international health and safety regulations, due to growing concerns regarding the impact of hexavalent chromium on human health and the environment, have pushed the commercial introduction of many alternative...journal article 2024
- document
-
Mopon, M. (author), Mol, J.M.C. (author), Garcia, Santiago J. (author)Understanding how late an inhibitor can be released once corrosion initiated without compromising corrosion protection may help in developing more efficient anticorrosion coatings. We explored this idea through time-controlled Ce(NO<sub>3</sub>)<sub>3</sub> availability to AA2024-T3 immersed in 0.05 M NaCl. Ce(NO<sub>3</sub>)<sub>3</sub> was...journal article 2024
- document
-
Li, Z. (author), Homborg, A.M. (author), Visser, Peter (author), Gonzalez Garcia, Y. (author), Mol, J.M.C. (author)In this work, the corrosion mechanism of AA2024-T3 covered by a lithium-based conversion layer is studied with high spatial and temporal resolution. Although the aluminium alloy surface is protected by a multi-layered conversion layer, areas around intermetallic phases (IMPs) represent weak spots due to an insufficient generation of a...journal article 2024
- document
-
Zhao, J. (author), van Ommen, J.R. (author), Garcia, Santiago J. (author)The most common way to protect metallic structures from corrosion is through the use of passive and active corrosion protection with coatings containing dispersed corrosion inhibitor particles. Current approaches use inorganic microparticles containing mostly toxic and/or critical elements (e.g. CrVI, Li-salts). Organic inhibitors have been...journal article 2024
- document
-
Lubelli, B. (author), des Bouvrie, Ernst (author), Nijland, Timo G. (author), Kamat, Ameya (author)Salt crystallization is a major cause of weathering of mortars, including plasters and renders. In the last decade, the use of mixed-in salt crystallization inhibitors in mortars has been proposed as a solution to improve the durability of this material with respect to salt decay. Laboratory characterization and accelerated weathering tests have...journal article 2023
- document
-
Pillado, B. (author), Mingo, B. (author), del Olmo, R. (author), Matykina, E. (author), Kooijman, A.M. (author), Gonzalez Garcia, Y. (author), Arrabal, R. (author), Mohedano, M. (author)Zinc aluminium (Zn-Al) and lithium aluminium (Li-Al) – layered double hydroxides (LDH) coatings with incorporated inhibitors (Li−, Mo− and W−based) were successfully synthesized on AZ31 Mg alloy. Zn−Al LDH W and Li−Al LDH Li showed the highest corrosion resistance and were selected for further evaluation. SEM cross−section examination...journal article 2023
- document
-
del Olmo, R. (author), López, E. (author), Matykina, E. (author), Tiringer, U. (author), Mol, J.M.C. (author), Mohedano, M. (author), Arrabal, R. (author)Plasma electrolytic oxidation (PEO) has been targeted as an eco-friendly alternative technology to conventional chromic acid anodizing (CAA) for corrosion protection of aluminium alloys in the aircraft industry. However, conventional PEO technology implies high energy consumption. Flash-PEO coatings (≤10 μm) produced in short treatment times ...journal article 2023
- document
-
Kortram, J. (author), Barnhoorn, A. (author), Pluymakers, Anne (author)Geothermal energy production often involves use of corrosion inhibitors. We performed rock mechanical experiments (room temperature; confining pressure of 10/20/30 MPa) on typical reservoir rocks (Bentheim sandstone and Treuchtlinger limestone) in contact with two different inhibitor solutions or with demineralized water. The sandstone...journal article 2023
- document
-
Kamat, Ameya (author), Lubelli, B. (author), Schlangen, E. (author)This paper investigates the leaching behaviour of sodium ferrocyanide, a known crystallisation inhibitor of sodium chloride, which is added to mortars for mitigation of salt decay. Leaching and depletion of the inhibitor is a practical performance related issue that might over time, make the inhibitor less effective against salt decay. In...journal article 2023
- document
-
Zhao, J. (author), Santoso, A. (author), Garcia, Santiago J. (author)The interaction of 2,5-dimercapto-1,3,4-thiadiazole (DMTD) with the AA2024-T3 local microstructure (S-phase, secondary phases and matrix) as function of the NaCl concentration is studied. The inhibiting power and the local interaction of DMTD with the metal were studied by in–situ opto-electrochemistry, XPS and Raman spectroscopy. The...journal article 2023
- document
-
Li, Z. (author), Li, G. (author), Visser, Peter (author), Homborg, A.M. (author), Gonzalez Garcia, Y. (author), Mol, J.M.C. (author)Scanning electrochemical microscopy (SECM) is employed to characterize the evolution of local electrochemical surface activity during lithium-based conversion layer formation on legacy aerospace aluminium alloy AA2024-T3. Initially, three types of studied intermetallic particles - S-, θ- and constituent phases - act as active cathodic areas....journal article 2023
- document
-
Chang, Xiwen (author), Long, Yongshuang (author), Yi, Mingwei (author), Wang, C. (author), Xiao, Yue (author)Due to the complex organic properties of asphalt materials, the heating process during asphalt pavement construction will lead to the release of asphalt VOCs‧ Asphalt VOCs volatilization will cause irreversible harm to both the environment and health of construction workers‧ Researchers in the field of road construction have carried out...review 2023
- document
-
Vidojkovic, S. (author), Mijajlovic, Miroslav (author), Lindeboom, R.E.F. (author), Jovicic, Vojislav (author)Film forming amines (FFA) are corrosion inhibitors added to power plant water. The major concern associated with their application is the thermal stability in the high temperature power plant water medium, along with the risk of decomposition into low molecular weight organic acids that can cause corrosive damages in the water/steam cycle....review 2023
- document
-
Kamat, Ameya (author), Lubelli, B. (author), Schlangen, E. (author)Sodium chloride (NaCl) is one of the most commonly occurring weathering agents, responsible for a progressive damage in mortar. Current solutions to mitigate salt damage in mortar, such as the use of mixed-in water repellent additives, have often exhibited low compatibility with the existing building fabric. In the last years, research has...book chapter 2023
- document
-
Potang, Baikaow (author)Pretreatment has become a necessary process to enhance the surface chemistry and morphology of aluminium alloys before implementing subsequent corrosion protection measures, especially organic coating application. Traditionally, hexavalent-chromium-based pretreatment processes were frequently used in many industries, but hexavalent-chromium...master thesis 2022
- document
-
Sewlikar, Parth (author)For the past few decades, the aerospace industry has been actively looking for measures to tackle the problem of localized corrosion of aluminium alloy 2024-T3. One such measure was the use of hexavalent chromium salts as corrosion inhibitors. However, recent studies have reflected the environmental concerns and health impacts associated with...master thesis 2022
- document
-
Denissen, P.J. (author), Homborg, A.M. (author), Garcia, Santiago J. (author)In this work a diffusion-driven inhibitor transport model is used to help in the design of inhibitor-loaded carriers for anticorrosive primers. The work focuses on inhibitor release at damaged locations of different dimensions exposed to electrolyte and is validated experimentally. The damage dimensions are first simulated to determine the...journal article 2022
- document
-
Kamat, Ameya (author), Lubelli, B. (author), Schlangen, E. (author)Porous building materials are often subjected to damage due to salt crystallization. In recent years, the addition of crystallization inhibitors in lime-based mortar, has shown promising results in improving durability of this material against salt decay. Lime-based mortars have low mechanical properties and slow setting. They are often replaced...journal article 2022
- document
-
Dai, Jiaxin (author), Fu, Dongmei (author), Song, Guangxuan (author), Ma, Lingwei (author), Guo, Xin (author), Mol, J.M.C. (author), Cole, Ivan (author), Zhang, Dawei (author)Current experimental verification, computational modeling, and machine learning methods for predicting corrosion inhibition efficiency (IE) are limited to specific inhibitor categories with high cost and poor generalization. In this study, a cross-category corrosion inhibitor dataset is constructed and a three-level direct message passing...journal article 2022