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Guest-induced structural deformation in Cu-based metal-organic framework upon hydrocarbon adsorptionLuna-Triguero, Azahara (author), Andres Garcia, E. (author), Leo LLorente, P. (author), Rook, W. (author), Kapteijn, F. (author)In a world where capture and separation processes represent above 10% of global energy consumption, novel porous materials, such as Metal-Organic Frameworks (MOFs) used in adsorption-based processes are a promising alternative to dethrone the high-energy-demanding distillation. Shape and size tailor-made pores in combination with Lewis acidic...journal article 2023
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Sun, X. (author), Wang, R. (author), Ould-Chikh, Samy (author), Osadchii, D. (author), Li, G. (author), Aguilar, Antonio (author), Hazemann, Jean louis (author), Kapteijn, F. (author), Gascon, Jorge (author)Mesoporous nitrogen-doped carbon nanoparticles with atomically dispersed iron sites (named mesoNC-Fe) are synthesized via high-temperature pyrolysis of an Fe containing ZIF-8 MOF. Hydrolysis of tetramethyl orthosilicate (TMOS) in the MOF framework prior to pyrolysis plays an essential role in maintaining a high surface area during the...journal article 2019