Design principles for efficient photoelectrodes in solar rechargeable redox flow cell applications

Recent advances in photoelectrochemical redox flow cells, such as solar redox flow batteries, have received much attention as an alternative integrated technology for simultaneous conversion and storage of solar energy. Theoretically, it has been reported that even single- photon devices can demonstrate unbiased photo-charging with high solar-to...

Hidden Figures of Photo-charging: a thermo-electrochemical approach for a solar-rechargeable redox flow cell system

Achieving high current densities without thermal performance degradation at high temperatures is one of the main challenges for enhancing the competitiveness of photo-electrochemical energy storage systems. We describe a system that overcomes this challenge by incorporating an integrated photoelectrode with a redox flow cell, which functions...

Tailored energy level alignment at MoOX/GaP interface for solar-driven redox flow battery application

MoOX is commonly considered to be a high work-function semiconductor. From x-ray photoelectron spectroscopy and photoelectrochemical analysis, it is shown that MoOX can be considered as an effective hole transfer layer for the GaP-based device. Specifically, in the absence of carbon contamination using an ion beam cleaning step, the oxygen...

Bias-Free in Situ H₂O₂ Generation in a Photovoltaic-Photoelectrochemical Tandem Cell for Biocatalytic Oxyfunctionalization

Peroxygenases catalyze selective oxyfunctionalization of hydrocarbons with high conversion efficiencies using H₂O₂ as a key cosubstrate. Here, we report an unbiased photoelectrochemical (PEC) tandem structure consisting of a FeOOH/BiVO₄ photoanode, a Cu(In,Ga)Se₂ solar absorber, and a graphitic...

Carbon Nanotube-Graphitic Carbon Nitride Hybrid Films for Flavoenzyme-Catalyzed Photoelectrochemical Cells

In green plants, solar-powered electrons are transferred through sophistically arranged photosystems and are subsequently channelled into the Calvin cycle to generate chemical energy. Inspired by the natural photosynthetic scheme, a photoelectrochemical cell (PEC) is constructed configured with protonated graphitic carbon nitride (p-g-C<sub>3...

Conceptual Design of an industrial-scale artificial leaf device: PDEng - Chemical Product Design; Individual Design Project - Final Report

Hydrogen, if produced from clean and abundant sources, has the potential for solving the concerns on energy supply security, climate change and local air pollution. Photoelectrochemical (PEC) water-splitting is a promising technology under development for the production of hydrogen from water by using sunlight. This design project aims to...