Revealing an Interconnected Interfacial Layer in Solid-State Polymer Sodium Batteries

Replacing the commonly used nonaqueous liquid electrolytes in rechargeable sodium batteries with polymer solid electrolytes is expected to provide new opportunities to develop safer batteries with higher energy densities. However, this poses challenges related to the interface between the Na-metal anode and polymer electrolytes. Driven by...

A Crystal-Less Clock Generation Technique for Battery-Free Wireless Systems

The size of wireless systems is required to be reduced in many applications, such as ultra-low-power sensor nodes and wearable/implantable devices, where battery and crystal are the two main bottlenecks in system miniaturization. In recent years, battery-free radios based on wireless power transfer (WPT) have shown great potential in...

A Series of Ternary Metal Chloride Superionic Conductors for High-Performance All-Solid-State Lithium Batteries

Understanding the relationship between structure, ionic conductivity, and synthesis is the key to the development of superionic conductors. Here, a series of Li_3-3_xM₁₊_xCl₆ (−0.14 < x ≤ 0.5, M = Tb, Dy, Ho, Y, Er, Tm) solid electrolytes with orthorhombic and trigonal structures are...

Template-free preparation of porous Co microfibers from spent lithium-ion batteries as a promising microwave absorber

In order to take full advantage of the secondary resources, in this paper, we reported a template-free process to prepare porous Co microfibers from spent lithium-ion batteries (LIBs). First, the waste LiCoO₂ powders were leached by oxalic acid at a suitable temperature, and rod-like cobalt oxalate powders were obtained. Second,...

Entropy-Driven Liquid Electrolytes for Lithium Batteries

Developing liquid electrolytes with higher kinetics and enhanced interphase stability is one of the key challenges for lithium batteries. However, the poor solubility of lithium salts in solvents sets constraints that compromises the electrolyte properties. Here, it is shown that introducing multiple salts to form a high-entropy solution,...

Reviving the rock-salt phases in Ni-rich layered cathodes by mechano-electrochemistry in all-solid-state batteries

The rock-salt phase (RSP) formed on the surface of Ni-rich layered cathodes in liquid-electrolyte lithium-ion batteries is conceived to be electrochemically "dead". Here we show massive RSP forms in the interior of LiNi_xMn_yCo_(1−x-y)O₂ (NMC) crystals in sulfide based all solid state batteries (ASSBs)...

High dielectric filler for all-solid-state lithium metal battery

Lithium metal with its high theoretical capacity and low negative potential is considered one of the most important candidates to raise the energy density of all-solid-state batteries. However, lithium filament growth and its induced solid electrolyte decomposition pose severe challenges to realize a long cycle life. Here, dendrite growth in...